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Synthesis and Catalytic Activity of the Fe(II) and Fe(III) Complexes with a New Polydentate Ligand Containing an Amide Donor

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Abstract

The iron complexes [Fe2+(tpcaH)(MeCN)2](ClO4)2 (I) and [Fe2O(tpca)2(H2O)2](ClO4)2 (II) based on the new potentially tetradentate ligand bis(2-pyridyl)methyl-2-pyridylcarboxamide (tpcaH) with the amide donor group inside the molecule were synthesized. The composition of the complexes was confirmed by elemental and mass spectrometric analyses and various spectral methods. Compounds I and II exhibited good catalytic activity in the stereospecific oxidation of alkanes by hydrogen peroxide.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    E. A. Gutkina, T. B. Rubtsova & A. A. Shteinman

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  1. E. A. Gutkina
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  2. T. B. Rubtsova
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  3. A. A. Shteinman
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Gutkina, E.A., Rubtsova, T.B. & Shteinman, A.A. Synthesis and Catalytic Activity of the Fe(II) and Fe(III) Complexes with a New Polydentate Ligand Containing an Amide Donor. Kinetics and Catalysis 44, 106–111 (2003). https://doi.org/10.1023/A:1022580903767

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