Abstract
In this paper results are presented on the corrosion resistance against SO2-polluted atmospheres of ultrathin Fe layers (<2.5 nm) deposited on SiO2/Si wafers by two methods: vacuum evaporation and Langmuir–Blodgett (LB) technique. It is shown that the corrosion resistance of the evaporated films is similar to that shown by massive iron while the corrosion resistance of the LB films is remarkably higher. We also show that the corrosion resistance of iron evaporated films can be greatly enhanced by using TiN coatings. Results on the influence of the SO2 concentration, the atmospheric relative humidity and the exposure time on the corrosion behaviour of thin (30 nm) TiN layers deposited onto evaporated Fe films on SiO2/Si wafers are discussed.
Similar content being viewed by others
References
Meisel, W., In: G. J. Long and F. Grandjean (eds), Mössbauer Spectroscopy Applied to Magnetism and Material Science, Vol. 2, Plenum, New York, 1996, pp. 1–30.
Meisel, W., Faldum, T., Sprenger, D. and Gütlich, P., Fresenius J. Anal. Chem. 346 (1993), 110.
Faldum, T., Meisel, W. and Gütlich, P., Fresenius J. Anal. Chem. 353 (1995), 723.
Gracia, M., Marco, J. F., Gancedo, J. R., Exel, W. and Meisel, W., Surf. Interface Anal. 29 (2000), 82.
O'Grady, W. E., J. Electrochem. Soc. 127 (1980), 555.
Brett, M. E., Parkin K. M. and Graham, M. J., J. Electrochem. Soc. 133 (1986), 2031.
Choudhury, T., Saied, S. O., Sullivan, J. L. and Abbot, A. M., J. Phys. D 22 (1989), 1185.
Wagner, C. D., Passoja, D. E., Hillery, H. F., Kinisky, T. G., Six, H. A., Jansen, W. T. and Taylor, J. A., J. Vac. Sci. Technol. 21 (1982), 933.
Meisel, W. and Gütlich, P., Surf. Interf. Anal. 19 (1992), 450.
Hamer, F., The Potter's Dictionary of Materials and Techniques, Pitman Publishing, London, 1977, pp. 132–133, 144-146.
Agudelo, A. C., Gancedo, J. R., Marco, J. F. and Hanžel, D., J. Vac. Sci. Technol. A 15 (1997), 3163.
Marco, J. F., Agudelo, A. C., Gancedo, J. R. and Hanžel, D., Surf. Interface Anal. 26 (1998), 667.
Marco, J. F., Agudelo, A. C., Gancedo, J. R. and Hanžel, D., Surf. Interface Anal. 27 (1999), 71.
Marco, J. F., Dávalos, J., Gracia, M. and Gancedo, J. R., Hyp. Interact. 83 (1994), 111.
Marco, J. F., PhD Thesis, Universidad Autónoma de Madrid, 1989.
Hübler, R., Schröer, A., Ensinger, W., Wolf, G., Stedile, F. C., Schreiner, W. H. and Baumvol, I. J. R., J. Vac. Sci. Technol. A11 (1993), 451.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Marco, J.F., Gracia, M., Gancedo, J.R. et al. Corrosion of Ultrathin Iron Layers and Titanium Nitride Coated Iron. Hyperfine Interactions 134, 37–51 (2001). https://doi.org/10.1023/A:1013837425035
Issue Date:
DOI: https://doi.org/10.1023/A:1013837425035