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Etude du Systeme LiPO3-Pr(PO3)3 Donnees sur LiPr(PO3)4

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Abstract

The LiPO3-Pr(PO3)3 system was studied by micro-differential thermal analysis. The only new compound observed in the system was LiPr(PO3)4, melting incongruently at 1246 K. An eutectic appears at 926 K. Crystallographic data and powder diagram of the new compound are given. LiPr(PO3)4 crystallizes in the C2/c monoclinic system with unit cell:

a=16.428(6), b=7.054(3), c=9.747(4) Å, β=126°31′(3), V=910.2 Å3, Z=4.

The IR and Raman spectra of this compound are given.

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Authors and Affiliations

  1. Laboratoire de Physico-Chimie des Interfaces et des Matériaux, Institut National de Recherche Scientifique et Technique, B.P. 95, Hammam-Lif, 2050, Tunisie

    Mokhtar Ferid

  2. Laboratoire de Chimie et Physico-Chimie Moléculaires et Minérales, Ecole Centrale, Paris Grande Voie des Vignes, 92295, Châtenay-Malabry Cedex, France

    B. Piriou

  3. Faculté des Sciences de Bizerte, Zarzouna, Bizerte, Tunisie

    Malika Trabelsi-Ayedi

Authors
  1. Mokhtar Ferid
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  2. B. Piriou
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  3. Malika Trabelsi-Ayedi
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Ferid, M., Piriou, B. & Trabelsi-Ayedi, M. Etude du Systeme LiPO3-Pr(PO3)3 Donnees sur LiPr(PO3)4. Journal of Thermal Analysis and Calorimetry 53, 227–234 (1998). https://doi.org/10.1023/A:1010148527708

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