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Lithium-cation and proton affinities of sulfoxides and sulfones: A fourier transform ion cyclotron resonance study

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Journal of the American Society for Mass Spectrometry

Abstract

The kinetic method was used for the quantitative determination of lithium-cation affinities by Fourier transform ion cyclotron resonance. This method was applied to a series of XYSO and XYSO2 compounds. Proton basicities of the SO and SO2 compounds were also determined. When comparison is made between Li+ basicities and proton basicities, a linear regression encompassing XYSO and XYSO2 families suggests that Li+ may be bonded in a similar way to the SO and SO2 moieties, that is, to only one oxygen on the latter. PM3 calculations support this hypothesis.

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Authors and Affiliations

  1. Department of Chemistry, Queen’s University, Kingston, Ontario, Canada

    Erwin Buncel

  2. Groupe FT-ICR, Laboratoire de Chimie Physique Organique, Université de Nice-Sophia Antipolis, 06108, Nice Cedex 2, France

    Michèle Decouzon, Alessandra Formento, Jean-François Gal, Marta Herreros, Lewyn Li & Pierre-Charles Maria

  3. Institute of Chemical Physics, Tartu University, Tartu, Estonia

    Ilmar Koppel & Riho Kurg

Authors
  1. Erwin Buncel
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  2. Michèle Decouzon
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  3. Alessandra Formento
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  4. Jean-François Gal
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  5. Marta Herreros
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  6. Lewyn Li
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  7. Pierre-Charles Maria
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  8. Ilmar Koppel
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  9. Riho Kurg
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Correspondence to Jean-François Gal.

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Buncel, E., Decouzon, M., Formento, A. et al. Lithium-cation and proton affinities of sulfoxides and sulfones: A fourier transform ion cyclotron resonance study. J Am Soc Mass Spectrom 8, 262–269 (1997). https://doi.org/10.1016/S1044-0305(96)00255-3

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  • DOI: https://doi.org/10.1016/S1044-0305(96)00255-3

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