Skip to main content
Log in

Effect of Cu content on aging precipitation behaviors of Cu-rich phase in Fe-Cr-Ni alloy

  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

The precipitation characteristics and effect on strengthening mechanism of Cu-rich phases during short-time and long-time aging for Super 304H steels with different Cu content were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The results show that the size of Cu-rich phase particles increases, the interspace of Cu-rich phase particles decreases and the density of Cu-rich phases increases with the increase of Cu content during short-time aging (approximately 800 h) at 650 °C for Super 304H steels. During long-time aging (more than 2000 h) at 650 °C, Cu-rich phase precipitates sufficiently and the strengthening effect of Cu-rich phase is preferable in Super 304 H steel containing Cu of 4%. The strengthening effect of Cu-rich phase in Super 304H steels containing Cu of 2.2% or 5% is weaker than that with Cu of 4% during long-time aging (more than 2000 h).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. YANG Yan, CHENG Shi-chang, YANG Gang. Present Situation of Exploiting and Research of Super 304H Steel for Boiler [J]. Special Steel, 2002, 23(1): 27 (in Chinese).

    Google Scholar 

  2. GUO Fu-qiang, CHENG Shi-chang, LIU Zheng-dong, et al. Effect of Carbon and Niobium on Intergranular Corrosion of ASME S30432 Austenitic Heat Resistant Steel [J]. Materials for Mechanical Engineering, 2007, 31(8): 11 (in Chinese).

    Google Scholar 

  3. SUN Yu-mei, ZHOU Xiao-ping. The Comment of Super304H Stainless Steel Boilet Tube [J]. Boiler Technology, 2007, 38 (1): 52 (in Chinese).

    Google Scholar 

  4. Tanaka H, Murata M, Abe F, et al. Microstructural Evolution and Change in Hardness in Type 304H Stainless Steel During Long-Term Creep [J]. Materials Science and Engineering, 2001, 319–321A: 788.

    Article  Google Scholar 

  5. Marián V, Terézia K, Mária D, et al, Evolution of Secondary Phases in Austenitic Stainless Steels During Long-Term Exposures at 600, 650 and 800 °C [J]. Mater Charact, 2008, 59: 1792.

    Article  Google Scholar 

  6. Ryoichi M, Kenichi T, Chihiro W. Coarsening of Spherical Cu Particles in an α-Fe Matrix [J]. ISIJ International, 2004, 44 (2): 442.

    Article  Google Scholar 

  7. Kozeschnik E. Thermodynamic Prediction of the Equilibrium Chemical Composition of Critical Nuclei: bcc Cu Precipitation in α-Fe [J]. Scripta Materials, 2008, 59: 1018.

    Article  Google Scholar 

  8. Dieter I, Semyon V, Morris E, et al. Copper-Precipitation Hardening in a Non-Ferromagnetic Face-Centered Cubic Austenitic Steel [J]. Scripta Materialia, 2008, 59: 1235.

    Article  Google Scholar 

  9. Sawaragi Y. The Development of a New 18-8 Austenitic Stainless Steel With High Elevated Temperature Strength for Fossil Fired Boilers [J]. Mechanical Behavior of Material, 1991, 4: 50.

    Google Scholar 

  10. YANG Yan, CHENG Shi-chang, YANG Gang. Effect of Cu Addition on the Creep Rupture Properties of Super304H Steel [J]. Materials for Mechanical Engineering, 2002, 6(10): 23.

    Google Scholar 

  11. Dieter Isheim, Gagliano Michael S, Fine Morris E, et al. Interfacial Segregation at Cu-Rich Precipitates in a High-Strength Low-Carbon Steel Studied on a Sub-Nanometer Scale [J]. Acta Materialia, 2006, 54(3): 841.

    Article  Google Scholar 

  12. Kozo O, Hiroshi O, Kazuo A, et al. SANS Study of Phase Decomposition in Fe-Cu Alloy With Ni and Mn Addition [J]. ISIJ International, 1994, 34(4): 346.

    Article  Google Scholar 

  13. Zhang C, Enomoto M. Study of the Influence of Alloying Elements on Cu Precipitation in Steel by Non-Classical Nucleation Theory [J]. Acta Materialia, 2006, 54(16): 4183.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shu-ping Tan.

Additional information

Foundation Item: Item Sponsored by National Science and Technology Support Plan of China (2007BAE51B02)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tan, Sp., Wang, Zh., Cheng, Sc. et al. Effect of Cu content on aging precipitation behaviors of Cu-rich phase in Fe-Cr-Ni alloy. J. Iron Steel Res. Int. 17, 63–68 (2010). https://doi.org/10.1016/S1006-706X(10)60101-X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1006-706X(10)60101-X

Key words

Navigation