Skip to main content
Log in

Microstructure of solid phase reduction on manganese oxide ore fines containing coal by microwave heating

  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

Microstructure of solid phase reduction on manganese oxide ore fines containing coal (MOOFCC) is one of important kinetics conditions of influencing microwave heating. On condition that an atomic molar ratio of rO: rC- in MOOFCC is 1 : 1.06 as well as a molecular molar ratio of \({r_{{\rm{Si}}{{\rm{O}}_{\rm{2}}}}}\) : rCaO is 1: 1.28, 1 kg of MOOFCC is heated by microwave to reach 1000–1300 °C and hold different time respectively. Experiments show that the metal phase takes the iron-based metal compounds containing manganese as the main content. The manganese content of metal phase increases with the rise of temperature. The particle size of the metal phase is within the range from 0.01 to 0.05 mm. MO2 phase in the stuff is entirely changed into MnO phase and the slag phase is mainly composed of wollastonite and manganese olivine. The stuff reduced is loose and massive as a whole and its porosity is from 30% to 45%. The low softening-melting property and the low density of the stuff impact, to some degree, the solid phase reduction of powder by microwave heating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. CHEN Jin, PAN Xiao-juan, ZHANG Meng. Heating Characteristics of Manganese Oxide Ore Fines Containing Coal Under Microwave Irradiation [J]. Materials Review, 2007, 21(11): 81.

    Google Scholar 

  2. TANG Hui-qing, ZHANG Shen-bi, GUO Xing-min. Magnetic Concentration of Mn and Fe in Manganese-Containing Low Grade Iron Ore [J]. Journal of University of Science and Technology Beijing, 1999, 21(40): 327 (in Chinese).

    Google Scholar 

  3. Swamy Y V, Bhoi B, Prakash S. Enrichment of the Manganese to Iron Ratio of Ferruginous Low-Grade Manganese Ore Using Solid Reductant [J]. Minerals and Metallurgical Processing, 1998, 15(3): 34.

    Google Scholar 

  4. PENG Meng-long. A Study on the Reduction of Carbon-Bearing Mn-Ore Lump in Solid State [J]. China’s Manganese Industry, 2000, 18(1): 36 (in Chinese).

    Google Scholar 

  5. TANG Hui-qing, ZHANG Shen-bi, GUO Xing-min. Effect of CaO on the Reduction Behavior and the Magnetic Concentration of Fe and Mn of the Manganese Containing Low Grade Iron Ore [J]. Journal of Baotou University of Iron and Steel Technology, 1999, 18(3): 167 (in Chinese).

    Google Scholar 

  6. LIU Shou-chang, GU Xiang-rong. Probe Into Thermodynamics of Blast Furnace FeMn Reduction [J]. Ferro-Alloys, 1999, 30 (6): 15 (in Chinese).

    Google Scholar 

  7. Welham N J. Activation of the Carbothermic Reduction of Manganese Ore [J]. International Journal of Mineral Processing, 2002, 67(1): 187.

    Article  Google Scholar 

  8. LIN Chuan-xian, BAI Zhenghua, ZHANG Zhe-ru. Handbook of Thermodynamic Data on Minerals and Related Compounds [M]. Beijing: Science Press, 1985 (in Chinese).

    Google Scholar 

  9. HUA Yi-xin, YAO Gang, XU Yang-liang. Study on Thermal Decomposition of Pyrolusite by DTA-TG [J]. Journal of Kunming University of Science and Technology, 1998, 23(3): 85 (in Chinese).

    Google Scholar 

  10. JIANG Guo-chang, XU Jiang-lun, XU Kuang-di. Basic Research on Reduction Process of Manganese Ore Agglomerate [J]. Ferro-Alloys, 1989, 20(6): 31 (in Chinese).

    Google Scholar 

  11. YANG Hua-ming, PAN Xiao, QIU Guan-zhou. Study on the Thermal Properties of Carbon-Bearing Manganese Fines Briquette [J]. Shanghai Metals, 1996, 18(6): 20 (in Chinese).

    Google Scholar 

  12. FAN De-lian, YANG Pei-ji. Introduction and Classification of Manganese Deposits of China [J]. Ore Geology Reviews, 1999, 15(1): 1.

    Article  Google Scholar 

  13. HUANG Meng-yang, ZHANG Shi-min, PENG Jin-hui. Study on Microwave-Absorption Property of Titanium Concentrate at Different Particle Sizes in Microwave Field [J]. Metal Mine, 2007(1): 42 (in Chinese).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jin Chen.

Additional information

Foundation Item: Item Sponsored by National Natural Science Foundation of China (50674069)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, J., Tian, Pf., Song, Xa. et al. Microstructure of solid phase reduction on manganese oxide ore fines containing coal by microwave heating. J. Iron Steel Res. Int. 17, 13–20 (2010). https://doi.org/10.1016/S1006-706X(10)60066-0

Download citation

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1006-706X(10)60066-0

Key words

Navigation