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One-pot alkanolamines-assisted synthesis of magnetic mesoporous silica for synthetic dye adsorption

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Abstract

Magnetic mesoporous silica (MMS) was synthesized in a one-pot system using various alkanolamines (triethanolamine, diethanolamine, tris (hydroxymethyl)aminomethane) as a basic catalyst. The characterization of the composites was conducted using scanning electron microscope, transmission electron microscope, X-ray diffractometer, surface area analyzer, and X-ray photoelectros spectroscopy. The MMS synthesized with tris(hydroxymethyl)aminomethane (MMSTRIS) showed the highest specific surface area, pore volume, and average pore diameter. However, when the composites were applied as adsorbents for brilliant green (BG) dye, MMS synthesized with diethanolamine (MMSDEA) showed the highest maximum adsorption capacity of 339.7 mg g−1. The fastest adsorption rate constant of 1.57 × 10−2 g mg−1 min−1 was obtained for MMSTRIS, which has the largest average pore size among all composites. The adsorption kinetic study suggested that the adsorption of BG onto the prepared MMS composites was mainly chemisorption process, which most likely involves electrostatic interaction and hydrogen bonding between BG molecule and the surface of the composites.

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Acknowledgements

This study was partly supported by JSPS Grants-in-Aid for Scientific Research (KAKENHI, Grant Number: 18K05168), Japan. PL would like to thank the Graduate School of Engineering, Gifu University, for the financial support under the Advanced Global Program (AGP).

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Authors and Affiliations

  1. Division of Materials Engineering, Graduate School of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Puji Lestari & Yutaka Ohya

  2. Department of Environmental Engineering, Faculty of Civil Engineering and Planning, Islamic University of Indonesia, Jl. Kaliurang Km. 14.5, Yogyakarta, 55584, Indonesia

    Puji Lestari

  3. Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Lee Wah Lim, Yutaka Ohya & Toyohide Takeuchi

  4. International Joint Department of Materials Science and Engineering between National University of Malaysia and Gifu University, Graduate School of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Lee Wah Lim

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  1. Puji Lestari
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Correspondence to Lee Wah Lim.

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Lestari, P., Lim, L.W., Ohya, Y. et al. One-pot alkanolamines-assisted synthesis of magnetic mesoporous silica for synthetic dye adsorption. ANAL. SCI. 38, 1441–1448 (2022). https://doi.org/10.1007/s44211-022-00183-7

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  • DOI: https://doi.org/10.1007/s44211-022-00183-7

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