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Functional materials for modifying interfaces between solid electrolytes and lithium electrodes of all-solid-state lithium metal batteries

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Abstract

All-solid-state lithium metal batteries have attracted considerable attention as the next-generation energy storage devices with high energy density and safety. This review focuses on the properties of interfaces between solid electrolytes and lithium electrodes, which are important for realizing all-solid-state lithium metal batteries. Various functional materials were used for modifying such interfaces, including amorphous oxide solid electrolytes, LiF, Al2O3, and carbon-based materials. After reviewing literature works related to this topic, we concluded that optimizing the combinations of the various functional materials should be studied more actively. In addition, along with performance optimization of functional materials, the development of mass-production processes should be carried out in parallel.

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Fig. 1
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Fig. 4

Copyright 2017 Elsevier B.V. All rights reserved. c Schematic of the Li dendrite inhibition mechanism in the Li3OCl–LLZTO composite electrolyte. SEM images of the d LLZTO pellet and e Li3OCl–LLZTO composite pellet. f Cycle evaluation data obtained for the symmetric cells. Reprinted with permission from Ref. [42]. Copyright 2018 Elsevier B.V. All rights reserved

Fig. 5

Copyright 2019 Tsinghua University Press and Springer-Verlag GmbH Germany. All rights reserved. c Galvanostatic cycling and electrochemical impedance spectra of the symmetric Li–LLZO cells. d Schematics and SEM images showing the interface state after cycling according to the thickness of the LiPON protective film. Reprinted with permission from Ref. [44]. Copyright 2021 Wiley–VCH GmbH. All rights reserved

Fig. 6

Copyright 2022 Elsevier B.V. All rights reserved

Fig. 7

Copyright 2022 The Authors, some rights reserved; exclusive licensee: American Association for the Advancement of Science

Fig. 8

Copyright 2020 Elsevier Ltd. All rights reserved

Fig. 9
Fig. 10

Copyright 2021 The Authors. All rights reserved

Fig. 11

Copyright 2016 Macmillan Publishers Limited, part of Springer Nature. All rights reserved. e Cycling behavior of the bare LATP/Li and Al2O3 coated LATP/Li symmetric cells. f TEM cross-sectional images of the bare and Al2O3 coated LATP pellets. Reprinted with permission from Ref. [51]. Copyright 2018 American Chemical Society. All rights reserved

Fig. 12

Copyright 2018 American Chemical Society. All rights reserved. c Mechanism of the graphite reaction with lithium. d SEM image of the interface between lithium and LLZTO. e Nyquist plots of the symmetric cells containing bare LLZTO and iGr@LLZTO. f Cycling performance of the Li│iGr@LLZTO│LiFePO4 full cell. Reprinted with permission from Ref. [54]. Copyright 2022 Elsevier B.V. All rights reserved

Fig. 13

Copyright 2021 The Authors, some rights reserved; exclusive licensee: American Association for the Advancement of Science

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Acknowledgements

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2021M1A7A4092589).

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    Jaehwan Ko & Young Soo Yoon

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Ko, J., Yoon, Y.S. Functional materials for modifying interfaces between solid electrolytes and lithium electrodes of all-solid-state lithium metal batteries. J. Korean Ceram. Soc. 60, 591–613 (2023). https://doi.org/10.1007/s43207-023-00293-6

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