Abstract
In the past few decades, numerous studies have been conducted to promote the use of biochar as a soil amendment and most recently, for compacted geo-engineered soils. In general, the definite trends of biochar effects on water retention and fertility of soils have been confirmed. However, the biochar effects on hydraulic conductivity, particularly unsaturated hydraulic conductivity of soil-biochar mix remain unclear, making it difficult to understand water seepage in both agricultural and geo-engineered infrastructures in semi-arid regions. This study examines the unsaturated hydraulic conductivity function derived based on the measurements of soil water characteristic curves of soil with biochar contents of 0%, 5% and 10%. A new parameter “biochar conductivity factor (BCF)” is proposed to evaluate the inconsistency in reported biochar effects on soil hydraulic conductivity and to interpret it from various mechanisms (inter- and intra- pore space filling, cracking, aggregation, bio-film formation and piping/internal erosion). The impact of biochar content on unsaturated hydraulic conductivity appears to reduce as the soil becomes drier with minimal effect in residual zone. Qualitative comparison of near-saturated hydraulic conductivity with test results in the literature showed that the BCF is generally higher for smaller ratio of sand to fine content (clay and silt). Moreover, the particle size of biochar may have significant influence on soil permeability. Future scope of research has been highlighted with respect to biochar production for its applications in agriculture and geo-environmental engineering. Long term effects such as root decay and growth, aggregation and nutrient supply need to be considered.
Graphical Abstract
Highlights
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1.
New biochar conductivity factor (BCF) is defined to explore hydraulic conductivity of biochar amended soils.
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2.
BCF is generally higher for smaller ratio of sand to fine content (clay and silt).
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3.
Pore filling, aggregation, bio-film formation and piping in soils due to biochar is discussed.
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4.
Lack of systematic studies revealing effects of physio-chemical properties of biochar on hydraulic conductivity.
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1 Introduction
Biochar is widely recognized as a sustainable solution to improve soil hydrological properties, retention of nutrients in agriculture fields, and improve crop productivity while preserving the ecosystem health (Gámiz et al. 2017; Garg et al. 2020). Biochar is a biomass-derived carbonaceous material produced via the pyrolysis process in the absence or under a limited amount of oxygen. Production of biochar is dependent on the type of feedstock used and the operating conditions such as residence time, temperature, and flowrate of feedstock in the pyrolysis reactor (Meyer et al. 2011). It is well established that changes in pyrolysis temperature affect the pore structure of biochar (Ganesan et al. 2020). Such changes in porosity may subsequently alter the moisture retention properties of soils (Ganesan et al. 2020; Mei et al. 2020). However, past studies on the influence of pyrolysis temperature on moisture retention characteristics of soils have been hitherto neglected.
There have been numerous studies on the application of biochar in agricultural soils (Laird et al. 2010; Barnes et al. 2014; Edeh et al. 2020) and, more recently, in compacted geo-engineered soils (Bordoloi et al. 2018; Kumar et al. 2019; Ni et al. 2020). For instance, a study conducted by Kumar et al. (2019) showed that compacted biochar-amended soil decreases erosion on landfill cap covers. Bordoloi et al. (2018) found an improvement in crack resistance due to addition of biochar in compacted soil. Furthermore, enhanced water retention and plant growth were also found due to the presence of biochar in compacted soil (Ni et al. 2020). The positive effects of biochar in terms of water retention, plant growth and crack suppression have been confirmed. However, the influence of biochar on soil hydraulic conductivity or permeability is inconclusive (Blanco-Canqui 2017). Hydraulic conductivity is expressed as the average rate of flow of water through soil pores. Near-saturated hydraulic conductivity indicates rate of flow of water in pores, which are assumed to be filled with water (Das 2019). Whereas, unsaturated hydraulic conductivity indicates water flow rate among inter-connected pores containing water (Thorbjørn et al. 2008). As expected, tortuosity increases due to disconnectivity caused by air filled pores and this phenomenon increases the travle path and hence, reduces the flow rate in an unsaturated soil (Faybishenko 1995).
Several studies have been conducted to analyze the near-saturated hydraulic conductivity of soil mixed with biochar at relatively lower compaction effort (less than 90% degree of compaction) for agricultural purposes (Busscher et al. 2010; Ibrahim et al. 2013; Githinji 2014; Prober et al. 2014; Rogovska et al. 2014; Novak et al. 2016). However, these studies on soil mixed with biochar did not reveal any particular trend with regard to the increase or decrease in the hydraulic conductivity values. For example, some studies have shown enhanced hydraulic conductivity in clayey or loamy soils when mixed with biochar (Prober et al. 2014; Novak et al. 2016), while others have observed lower hydraulic conductivity in sandy or silty sandy soils (Ibrahim et al. 2013; Githinji 2014). Given that the previous studies were conducted under varied soil and testing conditions (in the field or laboratory), a direct comparison is difficult. Furthermore, the authors hypothesized different possible mechanisms such as the pore-space filling effect of biochar into soil, the pore-space filling effect of soil into biochar pores and long-term aggregation (Jien and Wang 2013). To date, only a limited number of studies have investigated hydraulic conductivity over a wide range of suction. Unsaturated hydraulic conductivity is essential to analyze seepage of water during rainfall infiltration and to estimate water balance in slopes and green infrastructure (green roof, biofilters, etc.; Kutílek and Nielsen 1994; Hillel 1998). The effect of biochar on unsaturated hydraulic conductivity, hence, needs to be investigated. Both experimental (instantaneous profile method using 1-D column testing; Ng et al. 2011) and theoretical derivation from soil water characteristic curve (SWCC) (Brooks and Corey 1964) can be adopted for deducing unsaturated soil hydraulic conductivity functions. The former approach is time-consuming and costly, and requires long term measurements. By contrast, the latter approach is relatively easy and has proven to be reliable in deducing hydraulic conductivity for unsaturated soils (Huang et al. 1998; Ni et al. 2020).
The overarching aim of this study is to deduce the unsaturated hydraulic conductivity function of soil based on the measured SWCC at different biochar contents. A new parameter “Biochar conductivity factor” (BCF) has been proposed for interpreting near-saturated hydraulic conductivity, which is defined as the ratio of conductivity of soil-biochar mix and bare soil. Comparisons have been made with 148 measured hydraulic conductivity values in the literature. The differences between hydraulic conductivity values have been analyzed with respect to pore-space filling, aggregation and root growth/decay. In addition, the influence of the biochar production process (pyrolysis conditions and feedstock) on the structure of biochar and subsequent hydraulic conductivity has also been discussed.
2 Materials and methodology
2.1 Theoretical framework for estimating unsaturated hydraulic conductivity
Macroscopic models for predicting permeability function are established by assuming fluid-filled pores as bundles of capillary tubes of different sizes. The distribution of the pores that are filled with fluid is determined from SWCC.
In Brooks and Corey (1964), the flow through fluid-filled pores is characterized using Poiseuille equation. Integration across all the pore-water volume expressed by the SWCC can be used to determine hydraulic radius. During the derivation, a tortuosity factor was used to describe the difference between the actual and average pore velocities, and the actual and average pressure gradients. Based on the experimental data obtained by Burdine et al. (1950) and the analytical data of Wyllie and Gardner (1958), the following relationship for tortuosity was put forward.
where Ts represents the tortuosity that is a function of the degree of saturation, and Ts=1 represents the tortuosity at saturation, S is the degree of saturation and Sr is the residual degree of saturation, and \(\frac{s-{s}_{r}}{1-{s}_{r}}\) is the effective degree of saturation which can be expressed in terms of Se.
As proposed by Brooks and Corey (1964), the equation of the relative permeability (kr) can be written as:
where k(ѱ) means the permeability function and ѱ is the soil suction, and ks means the factor of permeability at saturation. Function of Se follows SWCC as:
where \({\psi }_{aev}\) means the suction that is associated with the air-entry value and
where \(\lambda\) is the pore-size distribution index and also implies the slope of SWCC on a log–log diagram (∆log Se/ ∆log ѱ). To obtain a bilinear curve on a log–log plot, Sr must be considered as a fitted parameter. In macroscopic models, the effective degree of saturation is generally used to explain “mobile” water phase in the soil, instead of the degree of saturation (Mualem 1986). The relative permeability is replaced by the effective degree of saturation. The relationship of the function is as follow:
Based on the effective degree of saturation given in Eq. (3), the relative permeability can be further simplified as:
where δ is an empirical index.
The relative permeability in terms of suction can be equivalent to the following expression:
where the pore-size distribution coefficient, η, is equal to (2 + 3λ).
In the present study, the “macroscopic model” represents the permeability function in terms of degree of saturation (Eq. (5)). Equation (6) has a strong analytical basis and experimental background. Mualem (1978) proposed a macroscopic model by considering the solid surface area in Kozeny’s (1927) equation and the hydraulic radius in the Hagen-Poiseuille equation. The equation of the index δ was proposed as follows:
where θ is the volumetric water content.
Many experimental results have shown that the index δ is determined by the pore-size distribution of the porous medium (Huang 1994; Laliberte et al. 1966; Mualem 1978). Consequently, the macroscopic models represented by Brooks and Corey (1964) and Mualem (1978) have found wider applicability than others because the δ index varies due to porous medium pore-size characteristics.
2.2 Experimental programme for determining unsaturated soil water characteristic curve
A series of 1-D column experiments were designed and conducted to measure SWCC for soil modified with biochar. The design and description of the 1-D column (300 mm in diameter and 250 mm in height) can be found in Bordoloi et al. (2018). The particle size distribution of the soils used in the study was 57%, 37% and 6%, for sand, silt and clay, respectively. The soil was classified as sandy loam according to United States Department of Agriculture (USDA) specifications (Soil Survey Staff 2004). The maximum dry density and optimum water content of soil were determined as 1.59 g/c.c. and 16.5%, respectively. The soil was compacted to a bulk density of 1.66 g/c.c. The soil sample was compacted in the 1-D column up to height of 220 mm, and was instrumented with two suction (MPS-6; Decagon devices) and volumetric water content sensors (EC-5, Decagon devices) at a depth of 30 mm from the surface. Both sensors were installed diametrically at opposite ends during compaction. The EC-5 sensors were calibrated for soils at different biochar contents (0%, 5% and 10%). Sensors were calibrated using the approaches proposed by Starr and Paltineanu (2002) and Cobos and Chambers (2010). MPS-6 sensors can be utilized for reliable measurements till 1700 kPa (Saha et al. 2020). The soil sample was prepared in a mold to calibrate the sensors. The sensors were installed in the prepared sample to measure water contents and thereafter, the volumetric water contents were quantified using a small cylinder. The obtained values of volumetric water contents were compared for the calibration. As per study by Kameyama et al. (2014), the effect of biochar type (i.e., pyrolyzed at 400 °C) was found to have almost negligible effect on the calibration results.
The biochar amended soil was subjected to 9 wetting–drying cycles with each cycle consisting of 7 days. Such time period was determined based on negligible change of soil volumetric water content (assuming soil reached residual zone) under drying. The soil suction and volumetric moisture content were simultaneously measured. It should be noted that saturated hydraulic conductivity for soil-biochar mix was determined using mini-disk infiltrometer. Cracks were observed and measured in terms of crack intensity factor (i.e., ratio of total crack area and soil surface area), which is deduced from image processing (Gadi et al. 2017a). It must be noted that minidisk infiltrometer is widely used to measure near saturated hydraulic conductivity. In addition, the theory, working principle and measuring procedure have been explicitly shown in several earlier studies (Bordoloi et al. 2017, 2019a, b; Gadi et al. 2017a, b). Details of testing procedures for SWCC can be found in Bordoloi et al. (2018) and Gopal et al. (2019), respectively. Brooks and Corey (1964) model (Eq. 5) for relative permeability coupled with Mualem (1978) model (Eq. 7) of hydraulic radius was adopted to deduce relative permeability function. Using near-saturated hydraulic conductivity as measured from mini-disk infiltrometer and obtained relative permeability, unsaturated hydraulic conductivity as a function of soil suction was obtained.
3 Results and discussions
3.1 Near-saturated hydraulic conductivity and cracking of biochar amended soils
Average near saturated permeability of biochar was found to be 1.27 ± 0.1 × 10–6 m s−1 (Gopal et al. 2019). Biochar reduced near-saturated hydraulic conductivity by 39 ± 2% and 72 ± 3% at 5% and 10% biochar content (Gopal et al. 2019). Though, it was expected that the presence of biochar may enhance porosity, however, crack suppression phenomenon of biochar also resulted in reduced hydraulic conductivity rate at surface. Peak crack intensity factor in bare soil was found to be 7.1 ± 0.4%. The presence of biochar reduced cracking by 46 ± 1% and 54 ± 2%, for 5% and 10% amendment ratio, respectively (Gopal et al. 2019). It is known that cracks can significantly increase permeability (Li et al., 2009), as described by the following equation:
where k is hydraulic conductivity and CIF is crack intensity factor. For CIF equivalent to 0, soil can be considered fully uncracked. For this case, permeability of cracked soil is same as that of soil matrix (without crack). For CIF equivalent to 1, the permeability of cracked soil is the same as the permeability of crack matrix.
Sun et al. (2020) analyzed the saturated permeability of low liquid limit clay under influence of biochar at different amendment ratios (0%, 10%, 15% and 20%). It was found from their study that the presence of biochar enhanced permeability of clay. Nuclear magnetic response (NMR) tests confirmed that bi-modal distribution of pure clay was observed under the influence of biochar with relatively higher probable pore size in soil-biochar mix. Recently Zhang et al. (2020) also found that biochar enhanced the swelling ability of soil, which was attributed to the binding of H2O molecules with C–O–H and –OH groups (Jačka et al. 2018). The moisture retained by the biochar amended soil could be 5% higher than that of bare soil and therefore the saturated hydraulic conductivity was found to decrease in the biochar amended soil (Jačka et al. 2018).
3.2 Normalized soil water characteristic curve and unsaturated hydraulic conductivity function of biochar amended soils
Figure 1a shows the measured SWCCs of bare soil as well as soil amended with 0%, 5% and 10% biochar. It can be observed that near-saturated volumetric water content is significantly higher for biochar amended soils as compared to the bare soil. The difference in volumetric water content retention between them reduces as soil becomes drier. In order to compare efficiency of biochar at different amendment ratios (i.e., 5% and 10%), it may be more suitable to analyze normalized volumetric water content with respect to soil suction (Fig. 1b). It can be observed that the difference between 5% and 10% biochar content on normalized water content was not significant and may lie within error limits of the EC-5 sensor (Fig. 1b), implying that efficiency of biochar content of 5% is already significant as compared to that of bare soil.
Figure 2 shows the variation in estimated unsaturated hydraulic conductivity function. It can be observed from the figure that unsaturated hydraulic conductivity for soil-biochar mix remains lower than that of bare soil throughout suction range. The difference in hydraulic conductivity between bare soil and biochar amended soil reduced with suction. There is a limitation in Brooks and Corey (1980) model, which does not capture post residual zone of unsaturated soil (Sillers and Fredlund 2001). Nevertheless, there is a clear tendency of reduction in impact of biochar on permeability of soil in residual zone. It should be noted that such observation is only applicable to one particular soil under given compaction. Further studies are required to obtain more comprehensive view of unsaturated permeability function of biochar amended clay. The following discussion would help to shed more light into possible mechanisms that are likely to influence permeability in biochar amended soils.
Higher water retention capacity is likely due to pore space filling effect of biochar in sand dominated mixture (Jien and Wang 2013). These findings reported in the current study (Fig. 2) are generally opposite to those of soils with lower ratio of sand to fine content (Ibrahim et al. 2013; Githinji 2014). A likely explanation could be that biochar filled the pores of sandy soils, while it was opposite (i.e., clayey particles filling pores of biochar) in case of finer-textured soils. Liu et al. (2016) analyzed the effects of relative particle size of biochar and sand grains on hydraulic conductivity and the authors found that the reduction in hydraulic conductivity was much higher when biochar particles were much finer than sand grains. However, the reduction in hydraulic conductivity was minimal, when biochar particles were coarser or comparable to sand grains, respectively. The decrease of hydraulic conductivity under coarser biochar might be due to bi-modal particle size distribution, resulting in compact packing and enhanced tortuosity.
3.3 Newly proposed biochar conductivity factor (BCF)
Though, qualitatively, the results of near-saturated permeability are consistent with those of Prober et al. (2014) and Novak et al. (2016), it may be difficult to compare since their studies seldom report any cracking effects of biochar. Tables 1, 2 and 3 summarize the near-saturated hydraulic conductivities measured in the literature.
In order to assess biochar effect, a new term “Biochar Conductivity Factor (BCF)” is defined. A BCF greater than 1 implies an increase in conductivity due to the influence of biochar, while a BCF less than 1 indicates a reduction in conductivity (see Fig. 3). Studies are categorized based on the reported suction and void ratio/density values (see Table 2) and particle size (see Table 3), which are missing in Table 1. In order to understand soil type effect, a new ratio between sand and fine particles (silt and clay) was defined. The lowerthe ratio, the higheris the fine content and expected lower average pore size. Figure 3a and b shows BCF and its corresponding variation with soil type, respectively and it can be observed that BCF is larger for higher ratio of sand to fine content. BCF factor was enhanced (either less than 1 or greater than 1) under higher biochar content. Glab et al. (2016) investigated the effect of feedstock type (Miscanthus and Winter wheat) and particle size on hydraulic conductivity and the authors found that both biochars enhanced conductivity in general; however, the effect of winter wheat feedstock was more significant than that of the Miscanthus type (see Table 3).
3.4 Aggregation effect
In contrast to the pore filling and bi-modal particle size distribution effects, Jien and Wang (2013) observed another factor (i.e., aggregation effect; Fig. 3) to be more dominant, while analyzing potential of biochar in a highly weathered soil (i.e., Typic Paleudults; Soil Survey Staff (2010)). The authors reported that biochar less than 2 mm in size was able to enhance hydraulic conductivity by almost 1.8 fold in weathered soil containing 43% clay, 40% silt and much lower sand content (i.e., 16%). Biochar could function as a binder, facilitating the connection of microaggregates in the soil to form macroaggregates. It was hypothesized in their study that the oxidized surface of biochar containing hydroxyl (-OH) and carboxylic groups (-COOH) can adsorb soil particles (even clay) to form macroaggregates under low pH environment (i.e., acidic). Jien and Wang (2013) further showed that mucilage produced by microbial activity and hyphae in the interface between soil and biochar particles tended to bind micro-aggregates to form macro-aggregates in biochar amended soils. In their study, porosity tended to decrease due to enhanced macro-aggregate formation at relatively higher biochar addition (i.e., 5%).
As also suggested in Fig. 4, aggregation can also happen due to presence of humus formed (due to root growth and decay) that is more likely to happen in long term. Plant residues naturally are broken down in long term (more than 10 years) to form humus. As compared to natural biomass decomposition, biochar is relatively far more stable (O/C ratio of less than 0.2 can have expected half-life over 1000 years; Wani et al., 2020). Biochar aggregation is more likely to occur in the long term in the field. There is aging effects that could oxidize functional groups at biochar surface, thus leading to higher water retention (Aller et al., 2017; Wang et al., 2019). Further systematic studies are needed to analyse long term effects of biochar on water retention taking aggregation, biomass decomposition and aging of biochar into account.
3.5 Wettability
Wettability is indicated by hydrophilicity (contact angle < 90°) or hydrophobicity (contact angle > 90°). Minimum biochar pore diameter (D) that can retain water is determined as:
where \(\gamma\) refers to surface tension at room temperature (0.072 N m−1) and θ is the contact angle between the biochar surface and water–air interface. A lower contact angle implies a larger D. This indicates that even larger pores of biochar can retain water. There is a dearth of information on the contact angle of biochar and how this can influence the hydraulic properties of soils. Das and Sarmah (2015) reported that hydrophobicity of biochar produced at low pyrolysis temperature is temporary and contact angle tends to reduce under wetting. They hypothesized that under water, aliphatic functional groups that are responsible for hydrophobicity are likely to be displaced, which can further enhance the affinity of the biochar for water. Recent studies (Mei et al. 2020; Ganesan et al. 2020) also showed that pyrolysis temperature could affect porosity as well as hydrophobicity of biochar, which can influence its cracking and water retention property. The authors concluded that biochar from plant waste (water hyacinth/algae) was found to retain more water than that from animal waste (pig manure, poultry litter), which could be attributed to higher porous structure of biochar from plant waste. Therefore, in addition to relative physical structure of biochar and soil, it is important to consider other factors such as feedstock type, pyrolysis temperature, pH and cracking of soil. These factors can affect hydrophilicity, aggregation and water retention phenomenon and hence, hydraulic conductivity of soil-biochar mix. Therefore, suffice it to say that porosity of biochar alone is not the driver that determines the soil hydraulic conductivity values upon biochar addition. The physio-chemical and biological interactions between biochar, soil, and water need to be considered.
3.6 Influence of biochar production process on soil permeability and water retention control
Figure 5 shows the conceptual framework on how biochar production process (feedstock type and pyrolysis temperature) may affect soil water retention. An increase in pyrolysis temperature leads to disappearance of the functional groups on biochar surface, leaving behind highly stable (i.e., due to aromatic structure of Benzene) and porous carbon structure (i.e., Turbidostratic char). Typical biomass constituting of lignin, cellulose and hemi-cellulose is broken down into biochar up on pyrolysis. Since feedstock type (plant type or animal waste) consists of varying compositions of lignin, cellulose and hemi-cellulose, it is obvious that micro-structure and composition of respective biochars (plant type or animal waste) will also vary significantly. Recently, the effect of pyrolysis temperature on water retention and crack suppression was discussed by Ganesan et al. (2020), who found that biochar produced at relatively high temperatures is likely to retain more water due to the formation of highly porous structure and thus reduce cracking, and subsequent suppression can further help in reduction in conductivity. However, studies on the effect of pyrolysis conditions (feedstocktype and temperature) on hydraulic conductivity are limited, which needs to be studied in greater detail.
4 Conclusions
Our study demonstrated that the hydraulic conductivity of biochar amended soil remained lower than that of bare soil throughout the entire suction range (including at 1500 kPa), and the impact of biochar was more pronounced on the unsaturated hydraulic conductivity of sandy soil. The efficiency of biochar at 5% and 10% amendment ratio was found to be similar. Based on the critical review for analyzing ambiguities, it can be concluded that there are five possible mechanisms through which biochar may influence hydraulic conductivity. These include (1) pore filling, (2) cracking, (3) aggregation, (4) root growth and decay and (5) bio-film formation. Extent of these mechanisms may vary with soil and biochar properties during testing. Hence, it is recommended to systematically characterize soil and biochar parameters (pore size distribution, density, void ratio) individually. Biochar production process (i.e., pyrolysis temperature, feedstock type) should be optimized for maximizing the effect on hydraulic conductivity according to the requirements in agriculture and geo-environmental engineering infrastructure. Clay in agricultural field requires higher hydraulic conductivity to avoid waterlogging condition and enhance crop yield, whereas, geo-environmental engineering infrastructure (i.e., landfill cover, slopes) prefers the opposite of it. It is imperative that a transdisciplinary approach need to be considered involving agriculture, geo-environmental engineering, energy and production engineering to put joint efforts in research related to optimization of production process and promote commercial utilization of biochar for large-scale application.
Availability of data and materials
Data is available upon reasonable request.
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Acknowledgements
Authors would like to acknowledge guidance of Prof. S. Sreedeep from IIT Guwahati, India for his expertise in unsaturated soil.
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The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (Grant No. 41907252).
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The first author drafted the manuscript based on idea jointly discussed with the second author. The third author provided feedback from geotechnical engineering point of view while the fourth author (AKS) provided technical guidelines from biochar characterization point of view. The fifth author helped to revise manuscript based on technical advice. The graphs and figures were corrected by the second and fifth authors. All authors read and approved the final manuscript.
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Garg, A., Zhu, HH., Sarmah, A.K. et al. Evaluating mechanism and inconsistencies in hydraulic conductivity of unsaturated soil using newly proposed biochar conductivity factor. Biochar 5, 34 (2023). https://doi.org/10.1007/s42773-023-00233-x
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DOI: https://doi.org/10.1007/s42773-023-00233-x