Abstract
A study of the application of mine tailings as precast construction materials through alkali activation has been carried out, focusing on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. Firstly, the effect of temperature on the alkali activation of mine tailings was studied. Secondly, the impact of additives, i.e., calcium hydroxide and aluminum oxide, on the compressive strength of samples was investigated. Thirdly, the impact of forming pressure on sample strength was studied. Test results showed that unconfined compressive strength (UCS) of 40 MPa was achieved with the geopolymerization products through optimization. Finally, to elucidate the geopolymerization mechanism of mine tailings, microscopic and spectroscopic techniques including SEM/EDX, XRD, and FTIR spectroscopy were used to investigate the microstructure and the elemental and phase composition of the geopolymerization products. The findings of the present work provide a practical method for applying mine tailings as precast construction materials through alkali activation.
Similar content being viewed by others
References
Xu H, van Deventer JSJ (2000) The geopolymerisation of aluminosilicate minerals. Int J Miner Process 59(3):247–266
Xu H, van Deventer JSJ (2002) Factors affecting the geopolymerization of alkali-feldspars. Miner Metall Process 19(4):209–214
Xu H, van Deventer JSJ (2002) Geopolymerisation of multiple minerals. Miner Eng 15:1131–1139
Ahmari S, Zhang L, Zhang J (2012) Effects of activator type/concentration and curing temperature on alkali-activated binder based on copper mine tailings. J Mater Sci 47:5933–5945
Pacheco-Torgal F, Castro-Gomes JP, Jalali S (2008) Investigation on mix design of tungsten mine waste geopolymeric binder, 2007. Constr Build Mater 22:1939–1949
Pacheco-Torgal F, Jalali S (2007) Influence of sodium carbonate addition on the thermal reactivity of tungsten mine waste mud based binders. Constr Build Mater 24:56–60
Mouhamadou B, Michael D, Grutzeck MW (2008) Low temperature process to create brick. Constr Build Mater 22:1114–1121
Somna K, Jaturapitakkul C, Kajitvichyanukul P, Chindaprasirt P (2011) NaOH activated ground fly ash geopolymer cured at ambient temperature. Fuel 90(6):2118–2124
Luz Granio M, Blanco Varela MT, Martinez Ramirez S (2007) Alkali activation of metakaolins: parameters affecting mechanical. Structural and microstructural properties. J Mater Sci 42:2934–2943
Yip CK, Van Deventer JSJ (2008) Effect of granulated blast furnace slag on geopolymerization. Proc World Congress Chem Eng Chem Res 40(17):3749–3756
Van Jaarsveld JGS, van Deventer JSJ, Lukey GC (2002) The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers. Chem Eng J 89:63–73
Phair JW, van Deventer JSJ, Smith JD (2004) Effect of Al source and alkali activation on Pb and Cu immobilization in fly-ash based "geopolymers". Appl Geochem 19:423–434
Panagiotopoulou CH, Kontori E, Perraki TH, Kakali G (2007) Dissolution of aluminosilicate minerals and by-products in alkaline media. J Mater Sci 2007(42):2967–2973
Palomo A, Grutzeck MW, Blanco MT (1999) Alkali-activated fly ashes: a cement for the future. Cement Concr Res 29(18):1323–1329
Duxson P, Mallicoat SW, Lukey GC, Kriven WM, van Deventer JSJ (2007) The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers. Colloid Surf A Physicochem Eng Aspects 292:8–20
Hanjitsuwan S, Hunpratub S, Thongbai P, Maensiri S, Sata V, Chindaprasirt P (2014) Effects of NaOH concentrations on physical and electrical properties of high calcium fly ash geopolymer paste. Cement Concrete Composites 45:9–14
Guo X, Shi H, Dick WA (2010) Compressive strength and microstructural characteristics of class C fly ash geopolymer. Cement Concrete Composites 32:142–147
Pangdaeng S, Phoo-ngernkham T, Sata V, Chindaprasirt P (2014) Influence of curing conditions on properties of high calcium fly ash geopolymer containing Portland cement as additive. Mater Des 53:269–274
Nazari A, Bagheri A, Riahi S (2011) Properties of geopolymer with seeded fly ash and rice husk bark ash. Mater Sci Eng A 528:24
Yang F (2012) Geopolymerization of copper mine tailings, Thesis, University of Arizona
Ken PW, Ramli M, Ban CC (2015) An overview on the influence of various factors on the properties of geopolymer concrete derived from industrial by-products. Constr Build Mater 77:370–395
García-Lodeiro I, Fernández-Jiménez A, Teresa Blanco M, Palomo A (2008) FTIR study of the sol–gel synthesis of cementitious gels: C–S–H and N–A–S–H gel. J Sol-Gel Sci Technol 45:63–72
Farmer VC (1974) The infrared spectra of minerals. Mineralogical Society, London
Gadsden JA (1975) Infrared spectra of minerals and related inorganic compounds. Butterworth, London
Lee WKW, Van Deventer JSJ (2003) Use of infrared spectroscopy to study geopolymerization of heterogeneous amorphous aluminosilicates. Langmuir 19:26–34
Uchino T, Sakka T, Hotta K, Iwasaki M (1989) Attenuated total reflectance Fourier-transform infrared spectra of a hydrated sodium silicates glass. M J Am Ceram Soc 72:2173–2175
Sitarz M, Mozgawa W, Handke M (1997) Vibrational spectra of complex ring silicate anions – method of recognition. J Mol Struct 404:193–197
Davidovits J (2008) Geopolymer chemistry and application, Institute of geopolymer, Saint-Quentin
Criado M, Fernández-Jiménez A, Palomo A (2007) Alkali activation of fly ash: effect of the SiO2/Na2O ratio: part I: FTIR study. Microporous Mesoporous Mater 106:180–191
Criado M, Aperador W, Sobrados I (2016) Microstructural and mechanical properties of alkali activated Colombian raw materials. Materials 9:158
Provis JL, Lukey GC, Van Deventer JSJ (2005) Do geopolymers actually contain nanocrystalline zeolites? A re-examination of existing results. Chem Mater 17:3075–3085
Acknowledgements
The authors greatly appreciate industry financial support for the present research work and the publication of the manuscript. J. Zhang is grateful to Freeport-McMoRan Copper & Gold, Inc. for sponsoring the Freeport McMoRan Copper and Gold Chair in Mineral Processing in the Department of Mining and Geological Engineering in the University of Arizona. Reviewers’ comments and their suggestions for the future work are greatly appreciated.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Huang, B., Feng, Q., An, D. et al. Use of Mine Tailings as Precast Construction Materials through Alkali Activation. Mining, Metallurgy & Exploration 37, 251–265 (2020). https://doi.org/10.1007/s42461-019-00149-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42461-019-00149-w