Abstract
This article investigates the effects of activator type/concentration and curing temperature on alkali-activated binder based on copper mine tailings (MT). Different alkaline activators including sodium hydroxide (NaOH), sodium silicate (SS), and sodium aluminate (SA) at different compositions and concentrations were used and four different curing temperatures, 60, 75, 90, and 120 °C, were considered. Scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX), and X-ray diffraction (XRD) were conducted to investigate the effect of these factors on the unconfined compressive strength (UCS), microstructure, and phase composition of the binder. The results indicate that NaOH concentration and curing temperature are two important factors that affect the UCS and micro-structural properties of the alkali-activated MT binder. The optimum curing temperature, i.e., the curing temperature at the maximum UCS, depends on the NaOH concentration, lower optimum curing temperature at smaller NaOH concentration. Addition of aqueous SS to the NaOH solution can lead to strength improvement, with the highest UCS obtained at a SiO2/Na2O ratio of 1.0–1.26. Addition of powder SA to the NaOH solution profoundly delays the setting at 60 °C but improves the UCS at 90 °C. The SEM/EDX results show highly heterogeneous microstructure for the alkali-activated MT binder as evidenced by the variable Si/Al ratios in different phases. The XRD patterns indicate a newly formed crystalline phase, zeolite, in the 90 °C-cured specimens. The results of this study provide useful information for recycling and utilization of copper MT as construction material through the geopolymerization technology.
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References
Meyer C (2009) Cement Concr Compos 31:601–605
World Business Council for Sustainable Development (2010) Cement sustainability initiative. http://wbcsdcement.org
Davidovits J (1994) In: Metha PK (ed) Proceedings of V. Mohan Malhotra symposium: concrete technology, past, present and future. ACI SP-144, p 383–397
Malhotra VM (2000) In: Gjorv OE, K Sakai (eds) Concrete technology for a sustainable development in the 21st century. E & FN Spon, London, p 226
McCaffrey R (2002) Climate change and the cement industry. Glob Cem Lime Mag (Environmental Special Issue): 15
Arm M (2003) Mechanical properties of residues as unbound road materials—experimental tests on MSWI bottom ash, crushed concrete and blast furnace slag. KTH Land and Water Resources Engineering, Stockholm
USEPA (2009) Wastes-resource conservation-reduce, reuse, recycle-construction & demolition materials. http://www.epa.gov/epawaste/conserve/rrr/imr/cdm/index.htm
Pacheco-Torgal F, Castro-Gomes J, Jalali S (2008) Constr Build Mater 22(11):2212–2219
Rattanasak U, Chindaprasirt P (2009) Miner Eng 22:1073–1078
Alonso S, Palomo A (2001) Cem Concr Res 31(1):25–30
Duxson P, Provis JL, Lukey GC, Mallicoat SW, Kriven WM, Van Deventer JSJ (2005) Colloids Surf A 269:47–58
Duxson P, Fernandez-Jimenez A, Provis JL, Lukey GC, Palomo A, Van Deventer JSJ (2007) J Mater Sci 42:2917–2933
Li Z, Ding Z, Zhang Y (2004) In: Proceedings of international workshop on sustainable development and concrete technology, Beijing, China, p 55
Drechsler M, Graham A (2005) Innovative material technologies: bringing resources sustainability to construction and mining industries. 48th Institute of Quarrying Conference, Adelaide
Shi C, Fernandez-Jimenez A (2006) J Hazard Mater B137:1656–1663
Majidi B (2009) Mater Technol 24(2):79–87
Giannopoulou IP, Panias D (2006) In: 2nd International conference on advances in mineral resources management and environmental geotechnology, Greece
Southam DC, Brent GF, Felipe F, Carr C, Hart RD, Wright K (2007) Towards more sustainable mine fills—replacement of ordinary Portland cement with geopolymer cements. World Gold Conference, Australia
Pacheco-Torgal F, Castro-Gomes J, Jalali S (2008) Constr Build Mater 22(6):1201–1211
Pacheco-Torgal F, Castro-Gomes J, Jalili S (2010) J Mater Civ Eng 22:897–904
Collins RJ, Ciesielski SK (1994) Recycling and use of waste materials and by-products in highway construction. National Cooperative Highway Research Program Synthesis of Highway Practice 199. Transportation Research Board, Washington, DC
FHWA (Federal Highway Administration) (2008) User guidelines for byproduct and secondary use materials in pavement construction. Report no. FHWA-RD-97-148
Pacheco-Torgal F, Castro-Gomes JP, Jalali S (2008) Constr Build Mater 22:1939–1949
Xu H, Van Deventer JSJ (2000) Int J Miner Process 59(3):247–266
Chindaprasirt P, Chareerat T, Siricicatnanon V (2007) Cement Concr Compos 29(3):224–229
Guo X, Shi H, Dick WA (2010) Cement Concr Compos 32:142–147
Yunfen H, Dongmin W, Wenjuan Z, Hongbo L, Lin W (2009) J Wuhan Univ Technol Mater Sci Ed 24(5):711–715
Villa C, Pecina ET, Torres R, Gómez L (2010) Constr Build Mater 24:2084–2090
Chindaprasirt P, Rattanasak U (2008) In: Technology and innovation for sustainable development conference (TISD2008), p 77
Cheng TW, Chiu JP (2003) Miner Eng 16:205–210
Provis JL, Yong CZ, Duxson P, Van Deventer JSJ (2009) Colloids Surf A 336:57–63
Detphan S, Chindaprasirt P (2008) In: Technology and innovation for sustainable development conference (TISD2008), p 111
Ma Y, Hu J, Ye G (2012) J Mater Sci. doi:10.1007/s10853-012-6316-3
Law DW, Adam A, Molyneaux TK, Patnaikuni I (2012) Mater Struc. doi:10.1617/s11527-012-9842-1
Silva PD, Sagoe-Crenstil K, Sirivivatnanon V (2007) Cem Concr Res 37:512–518
Bernal SA, Rodriguez ED, de Gutierrez RM, Provis JL, Delvasto S (2012) J Mater Sci 3(1):99–108
Lee WKW, Van Deventer JSJ (2002) Colloid Surf 211:115–126
Duxson P, Lukey GC, Separovic F, Van Deventer JSJ (2005) Ind Eng Chem Res 44:832–839
Sindhunata Van, Deventer JSJ, Lukey GC, Xu H (2006) Ind Eng Chem Res 45(10):3559–3568
Fernandez-Jimenez A, Palomo A, Sobrados I, Sanz J (2006) Microporous Mesoporous Mater 91(1–3):111–119
Rowles M, O’Connor B (2003) J Mater Chem 13:1161–1165
Schmucker M, MacKenzie KJD (2005) Ceram Int 31(3):433–437
Hajimohammadi A, Provis JL, Van Deventer JSJ (2008) Ind Eng Chem Res 47(23):9396–9405
Krivenko PV, Kovalchuk GY (2002) In: International conference on geopolymer-2002—turn potential into profit, Melbourne, October 28–29
Fletcher RA, MacKenzie KJD, Nicholson CL, Shimada S (2005) J Eur Ceram Soc 25(9):1471–1477
Phair JW, Van Deventer JSJ (2002) Ind Eng Chem Res 41:4242–4251
Brew DRM, MacKenzie KJD (2007) J Mater Sci 42:3990–3993
Verdolotti L, Iannace S, Lavorgna M, Lamanna R (2008) J Mater Sci 43:865–873
Temuujin J, Minjigmaa A, Rickard W, Lee M, Williams I, Van Riessen A (2009) Appl Clay Sci 46:265–270
Kawano M, Tomita K (1997) Clays Clay Miner 45(3):365–377
Ahmari S, Zhang L (2012) Constr Build Mater 29:323–331
Zhang L, Ahmari S, Zhang S (2011) Constr Build Mater 25(9):3773–3781
Chen C, Gong W, Lutze W, Pegg IL (2011) J Mater Sci 46(9):3073–3083. doi:10.1007/s10853-010-5186-9
Khale D, Chaudhary R (2007) J Mater Sci 42:729–746. doi:10.1007/s10853-006-0401-4
Panagiotopoulou CH, Kontori E, Perraki TH, Kakali G (2007) J Mater Sci 42:2967–2973. doi:10.1007/s10853-006-0531-8
Thakur RN, Ghosh S (2009) ARPN J Eng Appl Sci 4(4):68–74
Yao X, Zhang Z, Zhua H, Chen Y (2009) Thermochim Acta 493(1–2):49–54
Cyr M, Idir R, Poinot T (2012) J Mater Sci 47(6):2782–2797. doi:10.1007/s10853-011-6107-2
Muñiz-Villarreal MS, Manzano-Ramírez A, Sampieri-Bulbarela S, Gasca-Tirado JR, Reyes-Araiza JL, Rubio-Ávalos JC, Pérez-Bueno JJ, Apatiga LM, Zaldivar-Cadena A, Amigó-Borrás V (2010) The effect of temperature on the geopolymerization process of a metakaolin-based geopolymer. Mater Lett 65:995
Acknowledgements
This work is partially supported by the National Science Foundation under Grant No. CMMI-0969385, the University of Arizona Faculty Seed Grants Program, and a local mine company in Tucson, AZ.
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Ahmari, S., Zhang, L. & Zhang, J. Effects of activator type/concentration and curing temperature on alkali-activated binder based on copper mine tailings. J Mater Sci 47, 5933–5945 (2012). https://doi.org/10.1007/s10853-012-6497-9
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DOI: https://doi.org/10.1007/s10853-012-6497-9