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Thickness-Regulated Harmonious Effect on the Optical and Electrical Characteristics of ZnO Nano-Crystalline Thin Films for High Mobility Transparent Electrode

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Abstract

The effect of thickness modifications of zinc oxide (ZnO) thin films and the impressions over the electrical and optical characteristics were analyzed. ZnO thin films were deposited by the sol–gel spin coating method. For measuring the thickness of the films, a surface profilometer was operated. By maintaining an unvarying density of sol–gel (with 2% fabrication tolerance), the thin films were deposited on glass substrates. To identify the changes in optical variables, an ultraviolet–visible (UV–Vis) spectrophotometer was used. With the increment of deposition thickness, a nonlinear difference in skin depth has been observed. The bandgap showed a redshift and was in the range of 3.27–3.25 eV which is suitable for photonic applications. Electrical parameters were defined by ECOPIA Hall effect measurement system. The maximum measured sheet resistance in the current research is 5.43 × 107 (Ω/square) for 200 nm thin film. For 100 nm thickness, high mobility (221 cm2 V−1 s−1) and small resistivity (306.3) (Ω-cm) has been obtained. The above-mentioned high mobility and small resistivity are highly desirable for the transparent electrode of CIS solar cells and buffer layer.

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Acknowledgements

The authors want to concede the generous assistance from the Department of Glass and Ceramic Engineering (GCE) of Bangladesh University of Engineering and Technology (BUET), for SEM images and the Institute of Fuel Research & Development (IFRD) of Bangladesh Council of Scientific and Industrial Research (BCSIR), Bangladesh for XRD graphs.

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Authors and Affiliations

  1. Department of Electrical and Computer Engineering, The University of Alabama, Tuscaloosa, AL, 35487, USA

    M. Reefaz Rahman

  2. Department of Electrical and Electronic Engineering, American International University-Bangladesh, Dhaka, 1229, Bangladesh

    M. Reefaz Rahman & M. Nasir Uddin

  3. Department of Environmental Science, State University of Bangladesh, Dhaka, 1205, Bangladesh

    Tasnim Ashrafy

  4. Institute of Electronics, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, 1349, Bangladesh

    Mahbubul Hoq

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Rahman, M.R., Uddin, M.N., Ashrafy, T. et al. Thickness-Regulated Harmonious Effect on the Optical and Electrical Characteristics of ZnO Nano-Crystalline Thin Films for High Mobility Transparent Electrode. Trans. Electr. Electron. Mater. 24, 323–329 (2023). https://doi.org/10.1007/s42341-023-00450-y

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