Abstract
We report experimental study on an indium–tin oxide (ITO)-coated surface plasmon resonance-based fiber-optic hydrogen gas sensor operating at room temperature. The sensor works on intensity modulation interrogation. Indium–tin oxide (In2O3 + SnO2) films were grown on unclad core of the fiber by thermal evaporation technique. The surface plasmon resonance (SPR) spectra for 100 % nitrogen gas as well as for a mixture of 4 % hydrogen gas and 96 % nitrogen gas were obtained. In the case of mixture of hydrogen and nitrogen gases, a sharp dip in the SPR spectrum was observed implying that the hydrogen gas changes the dielectric properties of ITO. The performance of the sensor has been studied for different percentages of tin oxide in indium oxide and for different thicknesses of ITO film. Both the parameters have been optimized for the best performance of the sensor.
Similar content being viewed by others
References
Homola J, Yee SS, Gauglitz G (1999) Surface plasmon resonance sensor: review. Sens Actuators B 54:3–15
Sharma AK, Jha R, Gupta BD (2007) Fiber-optic sensors based on surface plasmon resonance: a comprehensive review. IEEE Sens J 7:1118–1129
Jorgenson RC, Yee SS (1993) A fiber optic chemical sensor based on surface plasmon resonance. Sens Actuators B 12:213–220
Homola J, Slavik R (1996) Fiber optic sensor based on surface plasmon resonance. Electron Lett 32:480–482
Cheng SF, Chau LK (2003) Colloidal gold-modified optical fiber for chemical and biochemical sensing. Anal Chem 75:16–21
Kim YC, Peng W, Banerji S, Booksh KS (2005) Tapered fiber optic surface plasmon resonance sensor for analyses of vapor and liquid phases. Opt Lett 30:2218–2220
Rajan, Chand S, Gupta BD (2006) Fabrication and characterization of a surface plasmon resonance based fiber optic sensor for bittering component- naringin. Sens Actuators B 115:344–348
Rajan, Chand S, Gupta BD (2007) Surface plasmon resonance based fiber optic sensor for the detection of pesticide. Sens Actuators B 123:661–666
Srivastava SK, Verma R, Gupta BD (2011) Surface plasmon resonance based fiber optic sensor for the detection of low water content in ethanol. Sens Actuators B 153:194–198
Bhatia P, Gupta BD (2011) Surface plasmon resonance based fiber optic refractive index sensor: sensitivity enhancement. Appl Opt 50:2032–2036
Rhodes C, Franzen S, Maria JP, Losego M, Leonard DN, Laughlin B, Duscher G, Weibel S (2006) Surface plasmon resonance in conducting metal oxides. J Appl Phys 100:054905
Rhodes C, Cerruti M, Efremenko A, Losego M, Aspens DE, Maria JP, Franzen S (2008) Dependence of plasmon polaritons on the thickness of ITO thin films. J Appl Phys 103:093108
Franzen S, Rhodes C, Cerruti M, Gerber RW, Losego M, Maria JP, Aspens DE (2009) Plasmonic phenomenon in indium tin oxide and ITO-Au hybrid films. Opt Lett 34:2867–2869
Verma RK, Gupta BD (2010) Surface plasmon resonance based fiber optic sensor for the IR region using a conducting metal oxide film. J Opt Soc Am A 27:846–851
Gupta SK, Joshi A, Kaur M (2010) Development of gas sensors using ZnO nanostructures. J Chem Sci 122:57–62
Patil GE, Kajale DD, Chavan DN, Pawar NK, Ahire PT, Shinde SD, Gaikwad VB, Jain GH (2011) Synthesis, characterization and gas sensing performance of SnO2 thin films prepared by spray pyrolysis. Bull Mater Sci 34:1–9
Suchea M, Katsarakis N, Christoulakis S, Nikolopoulo S, Kiriakidi G (2006) Low temperature indium oxide gas sensors. Sens Actuators B 118:135–141
Maruyama T, Fukui K (1991) Indium tin oxide thin films prepared by chemical vapour deposition. Thin Solid Films 203:297–302
Zheng JP, Kwok HS (1993) Low resistivity indium tin oxide films by pulsed laser deposition. Appl Phys Lett 63:1–3
Ali MKM, Ibrahim K, Hamad OS, Eisa MH, Faraj MG, Azhari F (2011) Deposited indium tin oxide (ITO) thin films by dc-magnetron sputtering on polyethylene terephthalate substrate (PET). Rom J Phys 56:730–741
Korotcenkov G, Brinzari V, Schwank J, DiBattista M, Vasiliev (2001) Peculiarities of SnO2 thin film deposition by spray pyrolysis for gas sensor application. Sens Actuators B 77:244–252
Bevenot X, Trouillet A, Veillas C, Gagnaire H, Clement M (2000) Hydrogen leak detection using an optical fiber sensor for aerospace applications. Sens Actuators B 67:57–67
Neri G, Bonavita A, Micali G, Rizzo G, Pinna N, Niederberger M, Ba J (2008) Effect of the chemical composition on the sensing properties of In2O3–SnO2 nanoparticles synthesized by a non-aqueous method. Sens Actuators B 130:222–230
Patel NG, Patel PD, Vaishnav VS (2003) Indium tin oxide (ITO) thin film gas sensor for detection of methanol at room temperature. Sens Actuators B 96:180–189
Acknowledgments
The present work is partially supported by the Council of Scientific and Industrial Research (India).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mishra, S.K., Gupta, B.D. Surface Plasmon Resonance-Based Fiber-Optic Hydrogen Gas Sensor Utilizing Indium–Tin Oxide (ITO) Thin Films. Plasmonics 7, 627–632 (2012). https://doi.org/10.1007/s11468-012-9351-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11468-012-9351-7