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Highly reversible and rapid charge transfer Zn-MnO2 battery by MnO2 nanosheet arrays anchored nanocellulose-based carbon aerogel

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Abstract

Zn-MnO2 batteries are eco-friendly energy storage devices, but their practical application is hindered by challenges such as low conductivity, sluggish Zn2+ diffusion kinetics, and instability in the crystal structure of manganese dioxide (MnO2) cathode materials during Zn2+ insertion/extraction. In this work, a composite nanocellulose-based carbon aerogel@MnO2 (CA@MnO2) cathode with enhanced Zn2+ insertion/de-insertion kinetics and storage capacity was fabricated by bi-directional freezing, carbonization, and following hydrothermal deposition. The nanocellulose-based carbon aerogels with ordered porous structure and high specific surface area served as the substrate, which facilitated the rapid Zn2+ migration and efficient electrode contact interface. In the two-electrode system, the CA@MnO2 can provide a reversible specific capacity of 480 mAh g−1 at 0.5 A g−1 and a high multiplicative capacity of 160 mAh g−1 at 5 A g−1 with outstanding stability of operation over 3000 cycles. The assembled Zn//CA@MnO2 batteries attained a remarkable specific capacitance of 397 mAh g−1 at a current density of 0.1 A g−1. This study provides a feasible route for the preparation of high-performance Zn-ion batteries.

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Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Funding

This work was supported by the National Natural Science Foundation of China (32071720, 32371809, 32301530), State Key Laboratory of Pulp and Paper Engineering (202204), Young Elite Scientist Sponsorship Program by Cast (No.YESS20230242), the China Postdoctoral Science Foundation (2023M740563), Tianjin Excellent Special Commissioner for Agricultural Science and Technology Project (23ZYCGSN00580), Natural Science Foundation of Tianjin (23JCZDJC00630), and Key R & D Program of Shaanxi Province (No. 2023GXLH-045, 2022SF-168).

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Authors and Affiliations

  1. State Key Laboratory of Biobased Fiber Manufacturing Technology, Tianjin Key Laboratory of Pulp and Paper, College of Light Industry and Engineering, Tianjin University of Science and Technology, Tianjin, 300457, China

    Qingshuang Zhao, Han Zhang, Xuan Wang, Ting Xu, Meng Zhang, Yaxuan Wang & Chuanling Si

  2. Key Laboratory of Bio-based Material Science and Technology, Material Science and Engineering College, Ministry of Education, Northeast Forestry University, Harbin, 150040, China

    Ting Xu & Zhanhua Huang

  3. Zhejiang Jinchang Special Paper Co Ltd, Quzhou, 324400, China

    Ting Xu & Shuhua Tong

  4. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, China

    Ting Xu

  5. College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou, 311300, Zhejiang Province, China

    Lizhong Zhu, Jie Li & Weiwei Huan

  6. School of Mechanical and Precision Instrument Engineering, Xi’an University of Technology, Xi’an, 710048, PR China

    Xing Zhou

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  1. Qingshuang Zhao
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Contributions

Qingshuang Zhao and Ting Xu designed the experiments. Qingshuang Zhao, Lizhong Zhu, Meng Zhang, Yaxuan Wang, Han Zhang, and Xuan Wang conducted experiments and drafted the manuscript. Ting Xu, Shuhua Tong, Xing Zhou, Jie Li, Weiwei Huan, Zhanhua Huang, and Chuanling Si supervised the manuscript. All authors discussed the experiments and results and have given approval for the final version of the manuscript.

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Correspondence to Ting Xu, Xing Zhou, Jie Li or Chuanling Si.

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Zhao, Q., Zhang, H., Wang, X. et al. Highly reversible and rapid charge transfer Zn-MnO2 battery by MnO2 nanosheet arrays anchored nanocellulose-based carbon aerogel. Adv Compos Hybrid Mater 7, 90 (2024). https://doi.org/10.1007/s42114-024-00900-y

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