Skip to main content

Advertisement

Log in

Use of graphene substrates for wastewater treatment of textile industries

  • Original Research
  • Published:
Advanced Composites and Hybrid Materials Aims and scope Submit manuscript

Abstract

Dyes are among the main pollutants in the textile wastewaters, which, due to their complex molecular structure, are often poisonous, carcinogenic, and environmentally perilous. Therefore, the main objective of this study is to evaluate the removal efficiency of textile dye (tested on methylene blue, MB) from aqueous medium using graphene oxide (GO)-containing hydrogels due to their high surface area and ability to adsorb a large amount of water and water-soluble species. Therefore, a series of GO-based nanocomposites based on acrylamide and sodium alginate crosslinked by methylene bis-acrylamide (MBA) have been prepared to be used and evaluated as the starter. The effect of different parameters such as initial dye concentration, temperature, and contact time on the removal of MB is investigated as well as determination of the adsorption isotherm of MB on GO/hydrogel using the Langmuir model. Various concentrations, temperatures, and contact time have also been investigated on GO/hydrogels. The chemical structure of the GO/hydrogel is determined by scanning electron microscopy, FTIR, and X-ray diffraction. The results show that the GO/hydrogel can absorb MB by up to 95.76% efficiency in removal of MB from an aqueous media.

The efficiency of removal of textile colorants from aqueous medium with graphene oxide containing hydrogels examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Mane VS, Mall ID, Srivastava VC (2007) Use of bagasse fly ash as an adsorbent for the removal of brilliant green dye from aqueous solution. Dyes Pigments 73(3):269–278

    Article  CAS  Google Scholar 

  2. Xiao X, Zhang F, Feng Z, Deng S, Wang Y (2015) Adsorptive removal and kinetics of methylene blue from aqueous solution using NiO/MCM-41 composite. Physica E: Low-dimensional Systems and Nanostructures 65:4–12

    Article  CAS  Google Scholar 

  3. Donia AM, Atia AA, Al-amrani WA, El-Nahas AM (2009) Effect of structural properties of acid dyes on their adsorption behaviour from aqueous solutions by amine modified silica. J Hazard Mater 161(2):1544–1550

    Article  CAS  Google Scholar 

  4. Deng JH, Zhang XR, Zeng GM, Gong JL, Niu QY, Liang J (2013) Simultaneous removal of cd (II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent. Chem Eng J 226:189–200

    Article  CAS  Google Scholar 

  5. Houa H, Zhou R, Wua P, Wu L (2012) Removal of Congo red dye from aqueous solution with hydroxyapatite/chitosan composite. Chem Eng J 211:336–342

    Article  Google Scholar 

  6. Wu Z, Zhong H, Yuan X, Wang H, Wang L, Chen X, Zeng G, Wu Y (2014) Adsorptive removal of methylene blue by rhamnolipid-functionalized graphene oxide from wastewater. Water Res 67:330–344

    Article  CAS  Google Scholar 

  7. Li Y, Du Q, Liu T, Sun J, Wang Y, Wu S, Wang Z, Xia Y, Xia L (2013) Methylene blue adsorption on graphene oxide/calcium alginate. Carbohydr Polym 95(1):501–507

    Article  CAS  Google Scholar 

  8. Hamidi M, Azadi A, Rafiei P (2008) Hydrogel nanoparticles in drug delivery. Adv Drug Deliv Rev 60(15):1638–1649

  9. Chang C, Duan B, Cai J, Zhang L (2010) Superabsorbent hydrogels based on cellulose for smart swelling and controllable delivery. Eur Polym J 46:92–100

    Article  CAS  Google Scholar 

  10. Richter A, Paschew G, Klatt S, Lienig J, Arndt K-F, Adler H-JP (2008) Review on hydrogel-based pH sensors and microsensors. Sensors 8:561–581

    Article  CAS  Google Scholar 

  11. Dittmeyer R, Höllein V, Daub K (2001) Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium. J Mol Catal A Chem 173:135–184

    Article  CAS  Google Scholar 

  12. Yang J, Xu C, Kopečková P, Kopeček J (2006) Hybrid hydrogels self-assembled from HPMA copolymers containing peptide grafts. Macromol Biosci 6:201–209

    Article  CAS  Google Scholar 

  13. Malkoch M, Vestberg R, Gupta N, Mespouille L, Dubois P, Mason AF (2006) Synthesis of well-defined hydrogel networks using click chemistry. Chem Commun:2774–2776

  14. Lee KY, Bouhadir KH, Mooney DJ (2000) Degradation behavior of covalently cross-linked poly (aldehyde guluronate) hydrogels. Macromolecules 33:97–101

    Article  CAS  Google Scholar 

  15. Kataoka T, Kidowaki M, Zhao C, Minamikawa H, Shimizu T, Ito K (2006) Local and network structure of thermoreversible polyrotaxane hydrogels based on poly (ethylene glycol) and methylated α-cyclodextrins. J Phys Chem B 110:24377–24383

    Article  CAS  Google Scholar 

  16. Peppas NA (1997) Hydrogels and drug delivery. Curr Opin Colloid Interface Sci 2:531–537

    Article  CAS  Google Scholar 

  17. Spanoudaki A, Fragiadakis D, Vartzeli-Nikaki K, Pissis P, Hernandez JCR, Pradas MM (2006) Nanostructured and nanocomposite hydrogels for biomedical applications. Surface Chemistry in Biomedical and Environmental Science (Nato Science Series II):229–240

  18. Lester CL, Smith SM, Colson CD, Guymon CA (2003) Physical properties of hydrogels synthesized from lyotropic liquid crystalline templates. Chem Mater 15:3376–3384

    Article  CAS  Google Scholar 

  19. Xu J, Li X, Sun F (2010) Cyclodextrin-containing hydrogels for contact lenses as a platform for drug incorporation and release. Acta Biomater 6:486–493

    Article  CAS  Google Scholar 

  20. Yoshida R, Uchida K, Kaneko Y, Sakai K, Kikuchi A, Sakurai Y (1995) Comb-type grafted hydrogels with rapid deswelling response to temperature changes. Nature 374:240–242

    Article  CAS  Google Scholar 

  21. Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. J Chem Eng 156:2–10

    Article  CAS  Google Scholar 

  22. Zohuriaan-Mehr MJ, Kabiri K (2008) Superabsorbent polymer materials: a review. Iran Polym J 17:451–477

    CAS  Google Scholar 

  23. Y. Li, Y. Q. Du, T. Liu, J. Sun, Y. Wang, S. Wu, Z. Wang, Y. Xia, L. Xia L., Methylene blue adsorption on graphene oxide/calcium alginate. Carbohydr Polym, 2013, 95 (1): 501–507

  24. He F, Fan J, Ma D, Zhang L, Leung C, Chan HL (2010) The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding. Carbon 48(11):3139–3144

    Article  CAS  Google Scholar 

  25. Li Y, Qiuju D, Liu T, Peng X, Wang J, Sun J, Wang Y, Wu S, Wang Z, Xia Y, Xi L (2013) Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chem Eng Res Des 91(2):361–368

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Behzad Pourabbas.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fallah, S., Mamaghani, H.R., Yegani, R. et al. Use of graphene substrates for wastewater treatment of textile industries. Adv Compos Hybrid Mater 3, 187–193 (2020). https://doi.org/10.1007/s42114-020-00146-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42114-020-00146-4

Keywords

Navigation