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Synthesis and thermal transformations of layered double hydroxide containing samarium

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Abstract

Nickel-aluminum layered double hydroxide with aluminum ions partially substituted by samarium ones was successfully synthesized via coprecipitation followed by hydrothermal treatment. X-ray diffraction data showed that the obtained sample is single-phase material with hydrotalcite-like structure. The presence of samarium in the sample was confirmed by elemental analysis. Electron microscopy demonstrated that the compound consists of very small plate-like particles with a shape similar to hexagonal. The study of thermal transformations of the material revealed that it decomposed upon heating above 300 °C with the formation of mixed oxide, and spinel-type oxide was formed while the heating temperature was increased up to 1000 °C. The rehydration ability of the sample was rather limited: no reconstruction of layered structure took place after mixed oxide was formed. The “memory effect” was observed only after heating the hydroxide at a temperature not higher than 300 °C. The thermal properties of samarium-containing samples resemble closely those of nickel-containing hydrotalcites.

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References

  1. Cavani, F., Trifirò, F., Vaccari, A.: Hydrotalcite-type anionic clays: preparation, properties and applications. Catal. Today 11, 173–301 (1991). https://doi.org/10.1016/0920-5861(91)80068-K

    Article  CAS  Google Scholar 

  2. Xu, Z.P., Zhang, J., Adebajo, M.O., Zhang, H., Zhou, C.: Catalytic applications of layered double hydroxides and derivatives. Appl. Clay Sci. 53, 139–150 (2011). https://doi.org/10.1016/j.clay.2011.02.007

    Article  CAS  Google Scholar 

  3. Sarfraz, M., Shakir, I.: Recent advances in layered double hydroxides as electrode materials for high-performance electrochemical energy storage devices. J. Energy Storage 13, 103–122 (2017). https://doi.org/10.1016/j.est.2017.06.011

    Article  Google Scholar 

  4. Mishra, G., Dash, B., Pandey, S.: Layered double hydroxides: a brief review from fundamentals to application as evolving biomaterials. Appl. Clay Sci. 153, 172–186 (2018). https://doi.org/10.1016/j.clay.2017.12.021

    Article  CAS  Google Scholar 

  5. Zümreoglu-Karan, B., Ay, A.N.: Layered double hydroxides—multifunctional nanomaterials. Chem. Pap. 66, 1–10 (2012). https://doi.org/10.2478/s11696-011-0100-8

    Article  CAS  Google Scholar 

  6. Wei, M., Xu, X., Wang, X., Li, F., Zhang, H., Lu, Y., Pu, M., Evans, D.G., Duan, X.: Study on the photochromism of Ni–Al layered double hydroxides containing nitrate anions. Eur. J. Inorg. Chem. 2006, 2831–2838 (2006). https://doi.org/10.1002/ejic.200600058

    Article  CAS  Google Scholar 

  7. Takei, T., Miura, A., Kumada, N.: Soft-chemical synthesis and catalytic activity of Ni-Al and Co-Al layered double hydroxides (LDHs) intercalated with anions with different charge density. J. Asian. Ceram. Soc. 2, 289–296 (2014). https://doi.org/10.1016/j.jascer.2014.06.002

    Article  Google Scholar 

  8. Deng, X., Huang, J., Wan, H., Chen, F., Lin, Y., Xu, X., Ma, R., Sasaki, T.: Recent progress in functionalized layered double hydroxides and their application in efficient electrocatalytic water oxidation. J. Energy Chem. 32, 93–104 (2019). https://doi.org/10.1016/j.jechem.2018.07.007

    Article  Google Scholar 

  9. Pérez-Ramírez, J., Ribera, A., Kapteijn, F., Coronado, E., Gómez-García, C.J.: Magnetic properties of Co–Al, Ni–Al, and Mg–Al hydrotalcites and the oxides formed upon their thermal decomposition. J. Mater. Chem. 12, 2370–2375 (2002). https://doi.org/10.1039/B110314H

    Article  Google Scholar 

  10. Abellán, G., Coronado, E., Martí-Gastaldo, C., Waerenborgh, J., Ribera, A.: Interplay between chemical composition and cation ordering in the magnetism of Ni/Fe layered double hydroxides. Inorg. Chem. 52, 10147–10157 (2013). https://doi.org/10.1021/ic401576q

    Article  CAS  Google Scholar 

  11. Coronado, E., Galán-Mascarós, J.R., Martí-Gastaldo, C., Ribera, A., Palacios, E., Castro, M., Burreil, M.: Spontaneous magnetization in Ni-Al and Ni-Fe layered double hydroxides. Inorg. Chem. 47, 9103–9110 (2008). https://doi.org/10.1021/ic801123v

    Article  CAS  Google Scholar 

  12. Liu, X.-M., Zhang, Y.-H., Zhang, X.-G., Fu, S.-Y.: Studies on Me/Al-layered double hydroxides (Me = Ni and Co) as electrode materials for electrochemical capacitors. Electrochim. Acta 49, 3137–3141 (2004). https://doi.org/10.1016/j.electacta.2004.02.028

    Article  CAS  Google Scholar 

  13. Wang, J., Song, Y., Li, Z., Liu, Q., Zhou, J., Jing, X., Zhang, M., Jiang, Z.: In situ Ni/Al layered double hydroxide and its electrochemical capacitance performance. Energy Fuels 24, 6463–6467 (2010). https://doi.org/10.1021/ef101150b

    Article  CAS  Google Scholar 

  14. Wang, W., Zhang, N., Shi, Z., Ye, Z., Gao, Q., Zhi, M., Hong, Z.: of Ni-Al layered double hydroxide hollow microspheres for supercapacitor electrode. Chem. Eng. J. 338, 55–61 (2018). https://doi.org/10.1016/j.cej.2018.01.024

    Article  CAS  Google Scholar 

  15. Sanati, S., Rezvani, Z.: Co-intercalation of acid Red-27/sodium dodecyl sulfate in a Ce-containing Ni-Al-layered double hydroxide matrix and characterization of its luminescent properties. J. Mol. Liq. 249, 318–325 (2018). https://doi.org/10.1016/j.molliq.2017.10.145

    Article  CAS  Google Scholar 

  16. Bellardita, M., Di Paola, A., Palmisano, L., Parrino, F., Buscarino, G., Amadelli, R.: Preparation and photoactivity of samarium loaded anatase, brookite and rutile catalysts. Appl. Catal. B 104, 291–299 (2011). https://doi.org/10.1016/j.apcatb.2011.03.016

    Article  CAS  Google Scholar 

  17. Dillip, G.R., Kumar, P.M., Raju, B.D.P., Dhoble, S.J.: Synthesis and luminescence properties of a novel Na6CaP2O9:Sm3+ phosphor. J. Lumin. 134, 333–338 (2013). https://doi.org/10.1016/j.jlumin.2012.08.025

    Article  CAS  Google Scholar 

  18. Ashwini, K., Pandurangappa, C., Avinash, K., Srinivasan, S., Stefanakos, E.: Synthesis, characterization and photoluminescence studies of samarium doped zinc sulfide nanophosphors. J. Lumin. 221, 117097 (2020). https://doi.org/10.1016/j.jlumin.2020.117097

    Article  CAS  Google Scholar 

  19. Singh, S., Kaur, P., Kumar, V., Tikoo, K.B., Singhal, S.: Traversing the advantageous role of samarium doped spinel nanoferrites for photocatalytic removal of organic pollutants. J. Rare Earths 39, 781–789 (2021). https://doi.org/10.1016/j.jre.2020.12.008

    Article  CAS  Google Scholar 

  20. Smalenskaite, A., Şen, S., Salak, A.N., Ferreira, M.G.S., Beganskiene, A., Kareiva, A.: Sol–gel derived lanthanide-substituted layered double hydroxides Mg3/Al1−xLnx. Acta Phys. Pol. A 133, 884–886 (2018). https://doi.org/10.12693/APhysPolA.133.884

    Article  CAS  Google Scholar 

  21. Mitran, G., Urda, A., Tanchoux, N., Fajula, F., Marcu, I.-C.: Propane oxidative dehydrogenation over Ln-Mg-Al-O catalysts (Ln = Ce, Sm, Dy, Yb). Catal. Lett. 131, 250–257 (2009). https://doi.org/10.1007/s10562-009-0057-1

    Article  CAS  Google Scholar 

  22. Urdă, A., Popescu, I., Cacciaguerra, T., Tanchoux, N., Tichit, D., Marcu, I.-C.: Total oxidation of methane over rare earth cation-containing missed oxides derived from LDH precursors. Appl. Catal., A. 464–465, 20–27 (2013). https://doi.org/10.1016/j.apcata.2013.05.012

    Article  CAS  Google Scholar 

  23. Taherian, Z., Gharahshiran, V.S., Khataee, A., Orooji, Y.: Anti-coking freeze-dried NiMgAl catalysts for dry and steam reforming of methane. J. Ind. Eng. Chem. 103, 187–194 (2021). https://doi.org/10.1016/j.jiec.2021.07.032

    Article  CAS  Google Scholar 

  24. Shen, S., Guo, W., Zhuang, W., Yang, W., Qin, L., Liu, X., Yue, Z.: Effect of Sm-doped Ni-Al layered double hydroxide on electrochemical performance for supercapacitors. J. Phys. Conf. Ser. 2009, 012008 (2021). https://doi.org/10.1088/1742-6596/2009/1/012008

    Article  CAS  Google Scholar 

  25. Kulyukhin, S.A., Krasavina, E.P., Rumer, I.A.: Sorption of 60Co, 90Sr, 90Y and 137Cs from aqueous solutions onto Mg-Ln layered double hydroxides (Ln = Ce, Pr, Sm, Gd). Radiochemistry 55, 569–600 (2013). https://doi.org/10.1134/S1066362213060052

    Article  CAS  Google Scholar 

  26. Golovin, S.N., Yapryntsev, M.N., Ryltsova, I.G., Veligzhanin, A.A., Lebedeva, O.E.: Novel cerium-containing layered double hydroxide. Chem. Pap. 74, 367–370 (2020). https://doi.org/10.1007/s11696-019-00877-9

    Article  CAS  Google Scholar 

  27. Golovin, S. N., Yapryntsev, M. N., Ryl’tsova, I. G., Savilov, S. V., Maslakov, K. I., Lebedeva, O. E.: Synthesis and thermal behavior of Co AlCe layered double hydroxide. Solid State Sci. 111:106498 (2021). https://doi.org/10.1016/j.solidstatesciences.2020.106498

  28. Bugaenko, L.T., Ryabykh, S.M., Bugaenko, A.L.: A nearly complete system of average crystallographic ionic radii and its use for determining ionization potentials. Moscow Univ. Chem. Bull. 63, 303–317 (2008). https://doi.org/10.3103/S0027131408060011

    Article  Google Scholar 

  29. Ramesh, T.N., Jayashree, R.S., Kamath, P.V.: Disorder in layered hydroxides: DIFFaX simulation of the X-ray powder diffraction patterns of nickel hydroxide. Clays Clay Miner. 51, 570–576 (2003). https://doi.org/10.1346/CCMN.2003.0510511

    Article  CAS  Google Scholar 

  30. Shivaramaiah, R., Navrotsky, A.: Energetics of order-disorder in layered magnesium aluminum double hydroxides with interlayer carbonate. Inorg. Chem. 54, 3253–3259 (2015). https://doi.org/10.1021/ic502820q

    Article  CAS  Google Scholar 

  31. Sławińsky, W.A., Sjåstad, A.O., Fjellvåg, H.: Stacking faults and polytypes for layered double hydroxides: what can we learn from simulated and experimental X-ray powder diffraction data? Inorg. Chem. 55, 12881–12889 (2016). https://doi.org/10.1021/acs.inorgchem.6b02247

    Article  CAS  Google Scholar 

  32. Wang, L., Lü, Z., Li, F., Duan, X.: Study on the mechanism and kinetics of the thermal decomposition of Ni/Al layered double hydroxide nitrate. Ind. Eng. Chem. Res. 47, 7211–7218 (2008). https://doi.org/10.1021/ie800609c

    Article  CAS  Google Scholar 

  33. Mahjoubi, F.Z., Elhalil, A., Elmoubarki, R., Sadiq, M., Khalidi, A., Cherkaoui, O., Barka, N.: Performance of of Zn-, Mg- and Ni-Al layered double hydroxides in treating an industrial textile wastewater. J. Appl. Surf. Interfaces. 2, 1–11 (2017). https://doi.org/10.48442/IMIST.PRSM/jasi-v2i1-3.10033

    Article  Google Scholar 

  34. Herrero, M., Benito, P., Labajos, F.M., Rives, V.: Stabilization of Co2+ in layered double hydroxides (LDHs) by microwave-assisted ageing. J. Solid State Chem. 180, 873–884 (2007). https://doi.org/10.1016/j.jssc.2006.12.011

    Article  CAS  Google Scholar 

  35. Zhang, Y., Liu, J., Li, Y., Yu, M., Yin, X., Li, S.: Enhancement of active anticorrosion via Ce-doped Zn-Al layered double hydroxides embedded in sol-gel coatings on aluminum alloy. J. Wuhan. Univ. Technol. Mater. Sci. Ed. 32, 1199–1204 (2017). https://doi.org/10.1007/s11595-017-1731-6

    Article  CAS  Google Scholar 

  36. Rey, F., Fornés, V., Rojo, J.M.: Thermal decomposition of hydrotalcites An infrared and nuclear magnetic resonance spectroscopic study. J Chem Soc Faraday Trans. 88, 2233–2238 (1992). https://doi.org/10.1039/FT9928802233

    Article  CAS  Google Scholar 

  37. Prevot, V., Caperaa, N., Taviot-Guého, C., Forano, C.: Glycine-assisted hydrothermal synthesis of NiAl-layered double hydroxide nanostructures. Cryst. Growth Des. 9, 3646–3654 (2009). https://doi.org/10.1021/cg900384n

    Article  CAS  Google Scholar 

  38. Vicente, P., Pérez-Bernal, M.E., Ruano-Casero, R.J., Duarte, A., Almeida Paz, F.A., Rocha, J., Rives, V.: Luminescence properties of lanthanide-containing layered double hydroxides. Microporous Mesoporous Mater. 226, 209–220 (2016). https://doi.org/10.1016/j.micromeso.2015.12.036

    Article  CAS  Google Scholar 

  39. Dubey, P., Kaurav, N.: Stoichiometric and nonstoichiometric compounds. In: Tanasescu, S. (ed.) Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides. IntechOpen, London (2019). https://doi.org/10.5772/intechopen.89402

  40. Sato, T., Fujita, H., Endo, T., Shimada, M., Tsunashima, A.: Synthesis of hydrotalcite-like compounds and their physico-chemical properties. React. Solids 5, 216–228 (1988). https://doi.org/10.1016/0168-7336(88)80089-5

    Article  Google Scholar 

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Funding

The reported study was funded by Russian Foundation for Basic Research according to the research project no. 20–33-90178. The work was carried out using the equipment of the Joint Research Center of Belgorod State National Research University «Technology and Materials».

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  1. Institute of Pharmacy, Chemistry and Biology, Belgorod State National Research University, Pobedy Str. 85, Belgorod, 308015, Russian Federation

    Sergei N. Golovin, Maksim N. Yapryntsev & Olga E. Lebedeva

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  1. Sergei N. Golovin
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  2. Maksim N. Yapryntsev
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  3. Olga E. Lebedeva
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Conceptualization: OEL; methodology: OEL; investigation: SNG, MNY; writing — original draft: SNG; writing — review and editing: OEL; funding acquisition: OEL; resources: MNY; supervision: OEL; visualization: SNG.

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Correspondence to Sergei N. Golovin.

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Golovin, S.N., Yapryntsev, M.N. & Lebedeva, O.E. Synthesis and thermal transformations of layered double hydroxide containing samarium. J Aust Ceram Soc 58, 1615–1622 (2022). https://doi.org/10.1007/s41779-022-00798-z

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