Skip to main content
Log in

Long-Term Efficiency of Silica Fume in Terms of Sulfate Resistance of Concrete Immersed in Sulfate Solutions and Seawater

  • Research Paper
  • Published:
Iranian Journal of Science and Technology, Transactions of Civil Engineering Aims and scope Submit manuscript

Abstract

This study aims to assess the long-term efficiency of silica fume used in the production of concrete exposed to sulfate solutions and seawater. The sulfate solutions used in the study were sodium sulfate and magnesium sulfate, and the seawater was provided from Black sea. The experimentation has continued for 4 years. The sulfate ion concentration of the sodium and magnesium sulfate solutions was adjusted to be 1300 ppm, which would be equivalent to the sulfate ion concentration of the seawater used in the test program. The total binder was 350 kg/m3, and cement was replaced by silica fume at a ratio of 10%. The concrete prisms produced were 40 × 40 × 160 mm standard prisms. In order to evaluate the efficiency of silica fume preventing sulfate attack, mass variation along with strength change has been taken into consideration as well as observational evaluation implemented throughout the experimentation. Concrete prisms cured under standard curing conditions were also produced for comparison purposes. Considering the compressive strength, seawater seemed particularly detrimental for concrete that does not contain silica fume. Hence, regarding the compressive strength change of concrete, it is realized that it is worth to take particularly into account the seawater effect in addition to the effect of sulfate solutions. The strength deterioration process of concrete prisms immersed in sodium and magnesium sulfate solutions seemed to be associated with the loss of stiffness and cohesiveness rather than expansion and cracking as opposed to the deterioration observed in case of seawater immersion. Visible cracks were formed in the prisms that did not contain silica fume immersed in seawater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Aköz F, Türker F, Koral S, Yüzer N (1995) Effects of sodium sulfate concentration on the sulfate resistance of mortars with and without silica fume. Cem Concr Res 25(6):1360–1368

    Article  Google Scholar 

  • Al-Amoudi OSB (1995) Performance of 15 reinforced concrete mixtures in magnesium sulpahte environments. Constr Build Mater 9(3):149–158

    Article  Google Scholar 

  • Al-Amoudi OSB (2002) Attack on plain and blended cements exposed to aggressive sulfate environments. Cem Concr Compos 24(3–4):305–316

    Article  Google Scholar 

  • Al-Dulaijan SU (2007) Sulfate resistance of plain and blended cements exposed to magnesium sulfate solutions. Constr Build Mater 21(8):1792–1802

    Article  Google Scholar 

  • Aye T, Oguchi CT (2011) Resistance of plain and blended cement mortars exposed to severe sulfate attacks. Constr Build Mater 25(6):2988–2996

    Article  Google Scholar 

  • Baghabra OS, Maslehuddin M, Saadi MM (1995) Effect of magnesium sulfate and sodium sulfate on the durability performance of plain and blended cements. ACI Mater J 92(1):15–24

    Google Scholar 

  • Bingöl A, Balaneji HH (2019) Determination of sulfate resistance of concretes containing silica fume and fly ash. Iran J Sci Technol Trans Civ Eng 43(1):219–230

    Article  Google Scholar 

  • Bonen D (1993) A microstructural study of the effect produced by magnesium sulfate on plain and silica fume-bearing Portland cement mortars. Cem Concr Res 23(3):541–553

    Article  Google Scholar 

  • Cao Y, Guo L, Chen BM, Fan H (2019) Influence of sulfate on the chloride diffusion mechanism in mortar. Constr Build Mater 197:398–405

    Article  Google Scholar 

  • Chen JK, Jiang MQ (2009) Long-term evaluation of delayed ettringite and gypsum in Portland cement mortars under sulfate erosion. Constr Build Mater 23(2):812–816

    Article  Google Scholar 

  • Cohen MD, Bentur A (1988) Durability of Portland Cement-Silica Fume Pastes in Magnesium and Sodium Sulfate Solutions. ACI Mater J 85(3):148–157

    Google Scholar 

  • De Weerdt K, Justnes H (2015) The effect of sea water on the phase assemblage of hydrated cement paste. Cem Concr Compos 55:215–222

    Article  Google Scholar 

  • Dehwah HAF (2007) Effect of sulfate concentration and associated cation type on concrete deterioration and morphological in cement hydrates. Constr Build Mater 21:29–39

    Article  Google Scholar 

  • Gonzalez MA, Irassar EF (1997) Ettringite formation in low C3A Portland cement exposed to sodium sulfate solution. Cem Concr Res 27(7):1061–1071

    Article  Google Scholar 

  • Hashemi SMS (2014) Experimental study on mechanical properties of different lightweight aggregate concretes. Engineering Solid Mechanics 2(3):201–208

    Article  Google Scholar 

  • Hossack AM, Thomas MDA (2015) The effect of temperature on the rate of sulfate attack of Portland cement blended mortars in Na2SO4 solution. Cem Concr Res 73:136–142

    Article  Google Scholar 

  • Imam A, Kumar V, Srivastava V (2018) Review study towards effect of silica fume on the fresh and hardened properties of concrete. Adv Concr Constr 6(2):145–157

    Google Scholar 

  • Irassar EF, Di Maio A, Batic OR (1996) Sulfate attack on concrete with mineral admixtures. Cem Concr Res 26(1):113–123

    Article  Google Scholar 

  • Irassar EF, Gonzalez M, Rahhal V (2000) Sulfate resistance of Type V cements with limestone filler and natural pozzolana. Cem Concr Compos 22(5):361–368

    Article  Google Scholar 

  • Khatri RP, Sirivivatnanon V, Yang JL (1997) Role of permeability in sulphate attack. Cem Concr Res 27(8):1179–1189

    Article  Google Scholar 

  • Lawrance CD (1992) The influence of binder type on sulfate resistance. Cem Concr Res 22(6):1047–1058

    Article  Google Scholar 

  • Lee ST, Moon HY, Swamy RN (2005) Sulfate attack and role of silica fume in resisting strength loss. Cem Concr Compos 27(1):65–76

    Article  Google Scholar 

  • Ma X, Çopuroğlu O, Schlangen E, Han N, Xing F (2018) Expansion and degradation of cement paste in sodium sulfate solutions. Constr Build Mater 158:410–422

    Article  Google Scholar 

  • Maes M, De Belie N (2014) Resistance of concrete and mortar against combined attack of chloride and sodium sulphate. Cem Concr Compos 53:59–72

    Article  Google Scholar 

  • Maher AB (2003) Performance of concrete in a coastal environment. Cem Concr Compos 25(4–5):539–548

    Google Scholar 

  • Malathy R, Subramanian K (2007) Effficiency factor for silica fume and metakaoline at various replacement levels. 32nd Conference on our World in Concrete and Structure, Singapore.

  • Monteiro PJ, Kurtis KE (2003) Time to failure for concrete exposed to severe sulfate attack. Cem Concr Res 33(7):987–993

    Article  Google Scholar 

  • Neville A (2004) The confused world of sulphate attack on concrete. Cem Concr Res 34(8):1275–1296

    Article  Google Scholar 

  • Park YS, Suh JK, Lee JH, Shin YS (1999) Strength deterioration of high strength concrete in sulfate environment. Cem Concr Res 29(9):1379–1402

    Article  Google Scholar 

  • Ragab AM, Elgammal MA, Hodhod OA, Ahmed TE (2016) Evaluation of field concrete deterioration under real sonditions of seawater attack. Constr Build Mater 119:130–144

    Article  Google Scholar 

  • Saafan MA, Etman ZA, El lakayn DM (2021) Microstructure and Durability of Ground Granulated Blast Furnace Slag Cement Mortars. Iran Journal of Science and Technology-Transactions of Civil Engineering 1–9

  • Samimi K, Javid AKS (2021) Magnesium Sulfate (MgSO4) attack and chloride isothermal effects on the self-consolidating Concrete Containing Metakaolin and Zeolite. Iran Journal of Science and Technology-Transactions of Civil Engineering 45(1):165–180

    Article  Google Scholar 

  • Seleem HEDH, Rashad AM, El-Sabbagh BA (2010) Durability and strength evaluation of high-performance concrete in marine environment. Constr Build Mater 24(6):878–884

    Article  Google Scholar 

  • Shannag MJ, Shaia HA (2003) Sulfate resistance of high-performance concrete. Cem Concr Compos 25(3):363–369

    Article  Google Scholar 

  • Skalny J, Marchand J, Odler I (2002) Sulfate attack on concrete. Spon Press, London UK

    Google Scholar 

  • Tian B, Cohen MD (2000) Does gypsum formation during sulfate attack on concrete lead to expansion? Cem Concr Res 30(1):117–123

    Article  Google Scholar 

  • Tian W, Han N (2017) Experiment analysis of concrete’s mechanical property deterioration suffered sulfate attack and drying-wetting cycles. Adv Mater Sci Eng 2017:1–13

    Google Scholar 

  • Türker F, Aköz F, Koral S, Yüzer N (1997) Effects of magnesium sulfate concentration on the sulfate resistance of mortars with and without silica fume. Cem Concr Res 27(2):205–214

    Article  Google Scholar 

  • Wee TH, Suryavanshi AK, Wong SF, Anisur Rahman AKM (2000) Sulfate resistance of concrete containing mineral admixtures. ACI Mater J 97(5):536–549

    Google Scholar 

  • Yu C, Sun W, Scrivener K (2013) Expansion and degradation of cement paste in sodium sulfate solutions. Cem Concr Res 43:105–111

    Article  Google Scholar 

  • Zhao G, Li J, Han F, Shi M, Fan H (2019) Sulfate-induced degradation of cast-in-situ concrete influenced by magnesium. Constr Build Mater 199:194–206

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Şakir Erdoğdu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Erdoğdu, Ş., Kurbetci, Ş. & Nayır, S. Long-Term Efficiency of Silica Fume in Terms of Sulfate Resistance of Concrete Immersed in Sulfate Solutions and Seawater. Iran J Sci Technol Trans Civ Eng 46, 2739–2746 (2022). https://doi.org/10.1007/s40996-021-00750-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40996-021-00750-4

Keywords

Navigation