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Investigation of the Effect of Seawater and Sulfate on the Properties of Cementitious Composites Containing Silica Fume

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Abstract

Concrete consumes over two billion tons of freshwater every year and 75 % of regions of the world will become water shortages in 2050. Because of increasing freshwater scarcity seawater may become reasonable as an alternative mixing and curing water for concrete. In this study, seawater (SW) was utilized for mixing and curing of concrete and investigated the seawater and sulfate on the properties of cementitious composites containing silica fume (SF). Hence, SF was replaced with the cement at ratios corresponding to 0 %, 2.5 %, 5 %, 7.5 %, 10 %, 12.5 %, and 15 % by weight of cement, and SW and tap water (TW) were used as mixing water in the production of cementitious composites. Thus, the effect of SW on the properties of fresh cement pastes and the flexural and compressive strengths of 7-day, 28-day, and 90-day old cementitious composites were examined. Additionally, the lengthening change values of cementitious composites containing SF that were kept in 5 % Na2SO4 solution for 7-day, 28-day, and 90-day were determined. The SF delayed the setting period while increasing the water requirement of the cement paste. It is determined that the SW accelerated the setting period of cement. In the case when 10 % SF in cementitious composites was used, the maximum compressive and flexural strengths were obtained for cementitious composites produced by mixing with SW and SF fume at an age corresponding to 28-day and 90-day. It was observed that the length change of the cementitious composites decreased due to the increase in the SF replacement ratio.

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References

  1. Bellport BP (1968) Combating sulphate attack on concrete on bureau of reclamation projects. In: Swenson EG (ed) Performance of concrete: resistance of concrete to sulphate and other environmental conditions. University of Toronto Press, Toronto

  2. Miller SA, Horvath A, Monteiro PJM (2016) Readily implementable techniques can cut annual CO2 emissions from the production of concrete by over 20 %. Environ Res Lett 11:74029. https://doi.org/10.1088/1748-9326/11/7/074029

    Article  CAS  Google Scholar 

  3. Miller SA, Horvath A, Monteiro PJM (2018) Impacts of booming concrete production on water resources worldwide. Nat Sustain 1:69–76. https://doi.org/10.1038/s41893-017-0009-5

    Article  Google Scholar 

  4. Mekonnen MM, Hoekstra AY (2016) Four billion people facing severe water scarcity. Sci Adv 2(2):e1500323, https://doi.org/10.1126/sciadv.1500323e1500323

    Article  PubMed  PubMed Central  Google Scholar 

  5. Islam MM, Islam MS, Mondal BC, Das A (2009) Strength behavior of mortar using slag with cement in sea water environment. J Civ Eng 37(2):111–122

    Google Scholar 

  6. Islam MS, Islam MM, Mondal BC (2010) Effect of freeze-thaw action on physical and mechanical behavior of marine concrete. J Inst Eng Malaysia 71(1):53–64

    Google Scholar 

  7. Mohammed TU, Hamada H, Yamaji T (2004) Performance of seawater-mixed concrete in the tidal environment. Cem Concr Res 34(4):593–601. https://doi.org/10.1016/j.cemconres.2003.09.020

    Article  CAS  Google Scholar 

  8. Park SS, Kwon SJ, Song HW (2011) Analysis technique for restrained shrinkage of concrete containing chlorides. Mater Struct 44(2):475–486. https://doi.org/10.1617/s11527-010-9642-4

    Article  CAS  Google Scholar 

  9. Guo Q, Chen L, Zhao H, Admilson J, Zhang (2018) The effect of mixing and curing sea water on concrete strength at different ages. In: MATEC Web of Conferences, 142:1–6. https://doi.org/10.1051/matecconf/201714202004

  10. Wegian FM (2010) Effect of seawater for mixing and curing on structural concrete. IES J Part A Civ Struct Eng 3(4):235–243. https://doi.org/10.1080/19373260.2010.521048

    Article  Google Scholar 

  11. Griffin DF, Henry RL (1964) The effect of salt in concrete on compressive strength, water vapor transmission, and corrosion of reinforcing steel. Port Hueneme, California

  12. Dewar JD (1963) The workability and compressive strength of concrete made with sea water. Cement and Concrete Association, London

  13. TS 3440 (1982) Rules for making concrete exposed to aggressive effects of liquids, soils and gases. Turkish Standard Institution, Ankara

    Google Scholar 

  14. Monteiro PJM, Kurtis KE (2003) Time to failure for concrete exposed to severe sulfate attack. Cem Concr Res 33:987–993. https://doi.org/10.1016/S0008-8846(02)01097-9

    Article  CAS  Google Scholar 

  15. Al-Dulaijan SU, Maslehuddin M, Al-Zahrani MM, Sharif AM, Shameem M, Ibrahim M (2003) Sulphate resistance of plain and blended cements exposed to varying concentrations of sodium sulphate. Cem Concr Comp 25:429–437. https://doi.org/10.1016/S0958-9465(02)00083-5

    Article  CAS  Google Scholar 

  16. Demir İ, Sevim Ö (2017) Effect of sulfate on cement mortars containing Li2SO4, LiNO3, Li2CO3 and LiBr. Constr Build Mater 156:46–55. https://doi.org/10.1016/j.conbuildmat.2017.08.148

    Article  CAS  Google Scholar 

  17. Demir İ, Güzelkücük S, Sevim Ö (2018) Effects of sulfate on cement mortar with hybrid pozzolan substitution. Eng Sci Technol 21(3):275–283. https://doi.org/10.1016/j.jestch.2018.04.009

    Article  Google Scholar 

  18. Taban S, Şimşek O (2009) The effect of zeolitic tuff addition ratio and sea water on physical and mechanical properties on cement. J Fac Eng Arch Gazi Univ 24:145–153

    Google Scholar 

  19. Guzelkucuk S, Demir I, Sevim O, Kalkan I (2020) Mechanical properties and microstructure of cement multicomponent systems containing pozzolan materials under sulfate attack. Cem Wapno Beton 25(2):137–153. https://doi.org/10.32047/CWB.2020.25.2.6

    Article  CAS  Google Scholar 

  20. Neville (2004) The confused world of sulphate attack on concrete. Cem Concr Res 34:1275–1296. https://doi.org/10.1016/j.cemconres.2004.04.004

    Article  CAS  Google Scholar 

  21. Sevim Ö, Demir İ (2019) Optimization of fly ash particle size distribution for cementitious systems with high compactness. Constr Build Mater 195:104–114. https://doi.org/10.1016/j.conbuildmat.2018.11.080

    Article  Google Scholar 

  22. Sevim Ö, Demir İ (2019) Physical and permeability properties of cementitious mortars having fly ash with optimized particle size distribution. Cem Concr Compos 96:266–273. https://doi.org/10.1016/j.cemconcomp.2018.11.017

    Article  CAS  Google Scholar 

  23. Mehta PK, Monteiro PJM (2006) Concrete: microstructure, properties and materials. The McGraw Hill companies, Inc., USA

  24. Sevim O, Sengul CG (2021) Comparison of the Influence of Silica‐rich Supplementary Cementitious Materials on Cement Mortar Composites: Mechanical and Microstructural Assessment. Silicon. https://doi.org/10.1007/s12633-021-01013-7

  25. Toklu K (2021) Investigation of mechanical and durability behaviour of high strength cementitious composites containing natural zeolite and blast-furnace slag. Silicon. https://doi.org/10.1007/s12633-020-00866-8

  26. Mehta PK, Haynes H (1975) Durability of concrete in sea water. J Am Soc Civil Eng Struct Div 101:1679–1686

    Google Scholar 

  27. Al-Amoudi OSB, Maslehuddin M, Shameem M, İbrahim M (2007) Shrinkage of plain and silica fume cement concrete under hot weather. Cem Concr Compos 29:690–699. https://doi.org/10.1016/j.cemconcomp.2007.05.006

    Article  CAS  Google Scholar 

  28. Carette GG, Malhotra VM (1983) Mechanical properties, durability, and drying shrinkage of Portland cement concrete incorporating silica fume. Cem Concr Aggr 5:3–13

    Article  CAS  Google Scholar 

  29. Nagataki S (1994) Mineral admixtures in concrete: state of the art and trends. In: Wieczorek V (ed) Concrete technology: Past, present, and future. Proceedings of the V. Mohan Malhotra Symposium ACISP-144, American Concrete Institute, Detroit, pp 447–482

  30. Rao GA (2001) Development of strength with age of mortars containing silica fume. Cem Concr Res 31:1141–1146. https://doi.org/10.1016/S0008-8846(01)00540-3

    Article  CAS  Google Scholar 

  31. Toutanji HA, Liu L, El-Korchi T (1999) The role of silica fume in the direct tensile strength of cement-based materials. Mater Struct 32:203–209. https://doi.org/10.1007/BF02481516

    Article  CAS  Google Scholar 

  32. EN 1008 (2003) Mixing water for concrete–Specification for sampling, testing, and assessing the suitability of water, including water recovered from processes in the concrete industry, as mixing water for concrete. British Standard Institution, South Jakarta

  33. Shekarchi M, Rafiee A, Layssi H (2009) Long-term chloride diffusion in silica fume concrete in harsh marine climates. Cem Concr Compos 31(10):769–775. https://doi.org/10.1016/j.cemconcomp.2009.08.005

    Article  CAS  Google Scholar 

  34. Neville A (2000) Good reinforced concrete in the Arabian Gulf. Mater Struct 33(234):655–664. https://doi.org/10.1007/BF02480605

    Article  Google Scholar 

  35. 35 Bentz DP (2000) Influence of silica fume on diffusivity in cement-based materials II. Multi-scale modeling of concrete diffusivity. Cem Concr Res 30:1121–1129. https://doi.org/10.1016/S0008-8846(00)00263-5

    Article  CAS  Google Scholar 

  36. Wegian FM (2010) Effect of seawater for mixing and curing on structural concrete. J Civ Struct Eng 3:235–243. https://doi.org/10.1080/19373260.2010.521048

    Article  Google Scholar 

  37. Guo Q, Chen L, Zhao H, Admilson J, Zhang W (2018) The effect of mixing and curing sea water on concrete strength at different ages, MATEC Web Conf., EDP Sciences, 02004

  38. Chłądzyński S (2005) Influence of lowered temperature on the sea water resistance of mortars of cement with mineral additions. Cem Wapno Beton 5:283–295

    Google Scholar 

  39. Pawluk J (2017) Concrete sulphate attack, analysis of the problem. Cem Wapno Beton 3:230–238

    Google Scholar 

  40. Yüzer N, Aköz F (2005) The relation between tensile and compressive strengths of concrete exposed to chlorides. Tech J 4:3673–3681

    Google Scholar 

  41. Yüzer N, Aköz F (2005) The relation between tensile and compressive strengths of concrete exposed to chlorides. Teknik Dergi 16(4):3673–3681 (in Turkish)

  42. Osuji SO, Nwankwo E (2015) Marine water effect on compressive strength of concrete: a case study of Escravos Area of Nigerian Delta. Nigerian J Technol 34(2):240–244. https://doi.org/10.4314/njt.v34i2.4

    Article  Google Scholar 

  43. Otsuki N, Furuya D, Saitoand T, Tadokoro Y (2011) Possibility of sea water as mixing water in concrete, 36th Conference on Our World in Concrete & Structures, Singapore

  44. Bhaskar S, Smitha MS, John E (2016) Relevance of sea water as mixing water in concrete. Int J Innov Res Sci Eng Technol 5(9):17084–17090

    Google Scholar 

  45. Shi Z, Shui Z, Li Q, Geng H (2015) Combined effect of metakaolin and seawater on performance and microstructures of concrete. Constr Build Mater 74:57–64. https://doi.org/10.1016/j.conbuildmat.2014.10.023

    Article  Google Scholar 

  46. Shi Z, Shui Z, Li Q, Geng H (2015) Chloride resistance of concrete with metakaolin addition and seawater mixing: A comparative study. Constr Build Mater 101:184–192. https://doi.org/10.1016/j.conbuildmat.2015.10.076

    Article  Google Scholar 

  47. Khayat KH, Vachon M, Lanctot MC (1997) Use of blended silica fumes cement in commercial concrete mixtures. ACI Mater J 94(3):183–192

    CAS  Google Scholar 

  48. Yogendran V, Langan BW, Haque MN, Ward MA (1987) Silica fumes in high strength concrete. ACI Mater J 84(2):124–129

    CAS  Google Scholar 

  49. Ramakrishnan V, Srinivasan V (1982) Silica fume in fibre reinforced concrete. Ind. Concr J 56:326–334

  50. Nader G, Hamidou D (2007) Strength and wear resistance of sand -replaced silica fume concrete. ACI Mater J 104(2):206–214

    Google Scholar 

  51. Srivastava V, Agarwal VC, Kumar R (2012) Effect of silica fume on mechanical properties of concrete. J Acad Indust Res 1(4):176–179

    Google Scholar 

  52. Weina M, Aditya K, Kayat KH (2019) Effect of silica fume and slump-retaining polycarboxylate-based dispersant on the development of properties of portland cement paste. Cem Concr Compos 99:181–190. https://doi.org/10.1016/j.cemconcomp.2019.03.021

    Article  CAS  Google Scholar 

  53. Mazloom M, Ramezanianpour AA, Brooks JJ (2004) Effect of silica fume on mechanical properties of high-strength concrete. Cem Concr Compos 26(4):347–357. https://doi.org/10.1016/S0958-9465(03)00017-9

    Article  CAS  Google Scholar 

  54. Roy DKS, Sil A (2012) Effect of partial replacement of cement by silica fume on hardened concrete. Int J Emerg Technol Adv Eng 2(8):472–475

    Google Scholar 

  55. Kumar R, Dhaka J (2016) Partial replacement of cement with silica fume and effects on concrete properties. Int J Technol Res Eng 4(1):86–88

    Google Scholar 

  56. Memon FA, Nuruddin MF, Shafiq N (2013) Effect of silica fume on the fresh and hardened properties of fly ash-based self-compacting geopolymer concrete. Int J Mine Metal Mater 20(2):205–213. https://doi.org/10.1007/s12613-013-0714-7

    Article  CAS  Google Scholar 

  57. Perumal K, Sundararajan R (2004) Effect of partial replacement of cement with silica fume on the strength and durability characteristics of High performance concrete. Proceedings of the 29th Conference on Our World in Concrete & Structure, Singapore

  58. Ismeik M (2009) Effect of mineral admixtures on mechanical properties of high strength concrete made with locally available materials. Jordan J Civil Eng 3(1):78–90

    Google Scholar 

  59. Etxeberria M, Gonzalez-Corominas A, Pardo P (2016) Influence of seawater and blast furnace cement employment on recycled aggregate concretes’ properties. Constr Build Mater 115:496–505. https://doi.org/10.1016/j.conbuildmat.2016.04.064

    Article  CAS  Google Scholar 

  60. Wild S, Sabir BB, Khatib JM (1995) Factors influencing strength development of concrete containing silica fume. Cem Concr Res 25:1567–1580. https://doi.org/10.1016/0008-8846(95)00150-B

    Article  CAS  Google Scholar 

  61. Almusallam AA, Beshr H, Maslehuddin M, Al-Amoudi OS (2004) Effect of silica fume on the mechanical properties of low quality coarse aggregate concrete. Cem Concr Compos 26:891–900. https://doi.org/10.1016/j.cemconcomp.2003.09.003

    Article  CAS  Google Scholar 

  62. Cohen MD, Bentur A (1988) Durability of Portland cement–silica fume pastes in magnesium sulfate and sodium sulfate solutions. ACI Mater J 85(3):148–157

    CAS  Google Scholar 

  63. Akoz F, Turker F, Koral S, Yuzer N (1995) Effects of sodium sulfate concentration on the sulfate resistance of mortars with and without silica fume. Cem Concr Res 25:1360–1368. https://doi.org/10.1016/0008-8846(95)00128-Y

    Article  CAS  Google Scholar 

  64. Turker F, Akoz F, Koral S, Yuzer N (1997) Effects of magnesium sulfate concentration on the sulfate resistance of mortars with and without silica fume. Cem Concr Res 27:205–214. https://doi.org/10.1016/S0008-8846(97)00009-4

    Article  CAS  Google Scholar 

  65. Mangat PS, Khatib JM (1993) Influence of fly ash, silica fume and slag on sulphate resistance of concrete. ACI Mater J 92(5):542–552

    Google Scholar 

  66. Mangat PS, El-Khatib JM (1992) Influence of initial curing on sulphate resistance of blended cement concrete. Cem Concr Res 22:1089–1100. https://doi.org/10.1016/0008-8846(92)90039-X

    Article  CAS  Google Scholar 

  67. Wee TH, Suryavanshi AK, Wong SF, Anisur Rahman KM (2000) Sulfate resistance of concrete containing mineral admixture ACI Mater. J 97(5):536–549

    CAS  Google Scholar 

  68. Lee ST, Moon HY, Swamy RN (2005) Sulfate attack and role of silica fume in resisting strength loss. Cem Conc Compos 27(1):65–76. https://doi.org/10.1016/j.cemconcomp.2003.11.003

    Article  CAS  Google Scholar 

  69. Demir İ, Sevim Ö, Kalkan İ (2018) Microstructural properties of lithium-added cement mortars subjected to alkali–silica reactions. Sādhanā 43(7):1–10. https://doi.org/10.1007/s12046-018-0901-3

    Article  CAS  Google Scholar 

  70. Demir I, Sevim O, Ozel G, Dogan O (2020) Microstructural, physical and mechanical properties of aerated concrete containing fly ash under high temperature and pressure. Rom J Mater 50(2):240–249

    CAS  Google Scholar 

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Şimşek, O., Aruntaş, H.Y., Demir, İ. et al. Investigation of the Effect of Seawater and Sulfate on the Properties of Cementitious Composites Containing Silica Fume. Silicon 14, 663–675 (2022). https://doi.org/10.1007/s12633-021-01052-0

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