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Magnetic Dispersive Solid Phase Extraction of Cu (II) as 1- (2-pyridylazo)-2-naphthol Chelates on Fe3O4@XAD-16

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Abstract

Fe3O4@XAD-16 has been used as adsorbent for magnetic dispersive solid phase extraction of Cu(II) as with 1- (2-pyridylazo) -2-naphthol (PAN) complex prior to flame atomic absorption spectrometric detection of copper. The effects of important parameters affecting extraction efficiency such as pH, adsorbent amount, eluent concentration and volume, model solution volume and ultrasonic bath time on magnetic solid phase extraction were studied in detail. The optimum pH for the extraction of Cu (II) was 6.0. The enrichment factor was 25. The accuracy of the extraction method was determined by the analysis of HR-1 (river sediment) and TMDA-53.3 (lake water) certified reference materials. The method was applied to determination of copper contents of food and water samples.

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Funding

The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Erciyes University (FBG-2020-10013) (Kayseri, Turkey).

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Authors and Affiliations

  1. Faculty of Sciences, Department of Chemistry, Erciyes University, 38039, Kayseri, Turkey

    Ozgur Ozalp & Mustafa Soylak

  2. Technology Research and Application Center (TAUM), Erciyes University, 38039, Kayseri, Turkey

    Ozgur Ozalp & Mustafa Soylak

  3. Turkish Academy of Sciences (TUBA), Cankaya, Ankara, Turkey

    Mustafa Soylak

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  1. Ozgur Ozalp
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  2. Mustafa Soylak
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OO contributed to investigation, methodology, writing—review and editing, MS contributed to methodology, visualization, writing—review and editing, supervision.

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Correspondence to Mustafa Soylak.

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Ozalp, O., Soylak, M. Magnetic Dispersive Solid Phase Extraction of Cu (II) as 1- (2-pyridylazo)-2-naphthol Chelates on Fe3O4@XAD-16. Iran J Sci Technol Trans Sci 45, 1971–1980 (2021). https://doi.org/10.1007/s40995-021-01194-1

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  • DOI: https://doi.org/10.1007/s40995-021-01194-1

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