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Structural, Optical and Electrical Properties of Cu-Doped ZnO Nanorods Grown on Flexible Polyethylene Terephthalate Substrate

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Abstract

The research successfully revealed the fabrication of Cu-doped ZnO nanorods grown on flexible polyethylene terephthalate (PET) substrate using chemical bath deposition method. The grown Cu-doped ZnO nanorods have been systematically characterized by X-ray diffraction, field-emission scanning electron microscopy and photoluminescence spectroscopy. The low compressive strain, strong and sharp (0 0 2) peak of the Cu-doped ZnO nanorods revealed a high-quality crystal structure. The average diameters of the undoped and Cu-doped ZnO nanorods grown on the PET substrate were 60 and 75 nm, respectively. The photoluminescence study exhibited an increased intensity in UV emission and decreased intensity in green emission with Cu doping. The current–voltage measurements demonstrate that the current level (with the bias voltage of + 5 V) increases from 205 µA to 1.83 mA with doping Cu into the ZnO nanorods. The well-aligned Cu-doped ZnO nanorods with high-density and quality crystal structure can be very suitable for applications in optoelectronic devices.

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References

  • Hammad TM, Salem JK, Harrison RG, Hempelmann R, Hejazy NK (2013) Optical and magnetic properties of Cu-doped ZnO nanoparticles. J Mater Sci Mater Electron 24:2846–2852

    Article  Google Scholar 

  • Hashim NH, Subramani S, Devarajan M, Ibrahim AR (2016) Structural and surface characterization of undoped ZnO and Cu doped ZnO using sol–gel spin coating method. J Mater Sci Mater Electron 27:3520–3530

    Article  Google Scholar 

  • Herng T, Lau S, Yu S, Yang H, Wang L, Tanemura M, Chen J (2007) Magnetic anisotropy in the ferromagnetic Cu-doped ZnO nanoneedles. Appl Phys Lett 90:032509

    Article  Google Scholar 

  • Iqbal J, Jan T, Shafiq M, Arshad A, Ahmad N, Badshah S, Yu R (2014) Synthesis as well as Raman and optical properties of Cu-doped ZnO nanorods prepared at low temperature. Ceram Int 40:2091–2095

    Article  Google Scholar 

  • Kouklin N (2008) Cu-doped ZnO nanowires for efficient and multispectral photodetection applications. Adv Mater Deerfield Beach Then Weinheim 20:2190

    Article  Google Scholar 

  • Lin J-P, Wu J-M (2008) The effect of annealing processes on electronic properties of sol-gel derived Al-doped ZnO films. Appl Phys Lett 92:134103

    Article  Google Scholar 

  • Lockett AM, Thomas PJ, O’Brien P (2012) Influence of seeding layers on the morphology, density, and critical dimensions of ZnO nanostructures grown by chemical bath deposition. J Phys Chem C 116:8089–8094

    Article  Google Scholar 

  • Lupan O, Pauporté T, Viana B, Ursaki V, Tiginyanu I, Sontea V, Chow L (2012) UV-blue and green electroluminescence from Cu-doped ZnO nanorod emitters hydrothermally synthesized on p-GaN. J Nanoelectron Optoelectron 7:712–718

    Article  Google Scholar 

  • Lv J, Liu C, Gong W, Zi Z, Chen X, Huang K, Liu F, Wang T, He G, Song X (2012) Facile synthesis of Zn1 − xCuxO nanorods with a very broad visible band. Electron Mater Lett 8:477–480

    Article  Google Scholar 

  • Noipa K, Rujirawat S, Yimnirun R, Promarak V, Maensiri S (2014) Synthesis, structural, optical and magnetic properties of Cu-doped ZnO nanorods prepared by a simple direct thermal decomposition route. Appl Phys A 117:927–935

    Article  Google Scholar 

  • Panda N, Acharya B, Nayak P, Bag B (2014) Studies on growth morphology, UV absorbance and luminescence properties of sulphur doped ZnO nanopowders synthesized by the application of ultrasound with varying input power. Ultrason Sonochem 21:582–589

    Article  Google Scholar 

  • Peng F, Zhou Q, Zhang D, Lu C, Ni Y, Kou J, Wang J, Xu Z (2015) Bio-inspired design: inner-motile multifunctional ZnO/CdS heterostructures magnetically actuated artificial cilia film for photocatalytic hydrogen evolution. Appl Catal B 165:419–427

    Article  Google Scholar 

  • Rakhshani A (2014) Visible light emission and UV light detection properties of solution-grown ZnO/polymer heterojunction diodes on stainless steel foil. Appl Surf Sci 311:614–620

    Article  Google Scholar 

  • Sáenz-Trevizo A, Amézaga-Madrid P, Pizá-Ruiz P, Antúnez-Flores W, Ornelas-Gutiérrez C, Miki-Yoshida M (2015) Single and multi-layered core-shell structures based on ZnO nanorods obtained by aerosol assisted chemical vapor deposition. Mater Charact 105:64–70

    Article  Google Scholar 

  • Santoshkumar B, Kalyanaraman S, Vettumperumal R, Thangavel R, Kityk I, Velumani S (2016) Structure-dependent anisotropy of the photoinduced optical nonlinearity in calcium doped ZnO nanorods grown by low cost hydrothermal method for photonic device applications. J Alloy Compd 658:435–439

    Article  Google Scholar 

  • Sarkar S, Basak D (2013) Defect controlled ultra high ultraviolet photocurrent gain in Cu-doped ZnO nanorod arrays: de-trapping yield. Appl Phys Lett 103:041112

    Article  Google Scholar 

  • Shabannia R (2015) Vertically aligned ZnO nanorods on porous silicon substrates: effect of growth time. Prog Nat Sci Mater Int 25:95–100

    Article  Google Scholar 

  • Shabannia R (2016) Effects of growth duration and precursor concentration on the growth of ZnO nanorods synthesized by chemical bath deposition. Iran J Sci Technol Trans A Sci 40:19–25

    Article  Google Scholar 

  • Shabannia R, Abu Hassan H (2014) Growth of Aligned ZnO nanorods grown on polyethylene naphthalate substrates: effect of the growth duration. Adv Mater Res 925:195–199

    Article  Google Scholar 

  • Shabannia R, Ghasemtabar M (2016) Self-assembly of densely packed ZnO nanorods grown chemically on porous silicon substrate. Iran J Chem Chem Eng (IJCCE) 35:57–61

    Google Scholar 

  • Shabannia R, Hassan HA (2014) Characteristics of photoconductive UV photodetector based on ZnO nanorods grown on polyethylene naphthalate substrate by chemical bath deposition method. Electron Mater Lett 10:837–843

    Article  Google Scholar 

  • Shabannia R, Hassan HA, Mahmodi H, Naderi N, Abd H (2013) ZnO nanorod ultraviolet photodetector on porous silicon substrate. Semicond Sci Technol 28:115007

    Article  Google Scholar 

  • Sharma PK, Dutta RK, Kumar M, Singh PK, Pandey AC, Singh V (2011) Highly stabilized monodispersed citric acid capped nanoparticles: synthesis and characterization for their applications in white light generation from UV LEDs. IEEE Trans Nanotechnol 10:163–169

    Article  Google Scholar 

  • Srinet G, Kumar R, Sajal V (2013) Effects of Ni doping on structural, optical and dielectric properties of ZnO. Ceram Int 39:7557–7561

    Article  Google Scholar 

  • Wang R-C, Su W-S (2016) Valence control and periodic structures in Cu-doped ZnO nanowires. J Alloy Compd 654:1–7

    Article  Google Scholar 

  • Wang Y, Hou Z, Guo H, Shen L, Wang G, Cui F, Zhang Q (2013) Preparation of ZnO nanorods via aqueous solution process and their PL properties. Mater Lett 91:107–110

    Article  Google Scholar 

  • Zhou P, Liu H, Zhang L, Suo X, Liang Z, Liu Y, Li Y, Jiang Z, Wang Z (2016) Study of substrate temperature and copper doping effects on structural, electrical and optical properties of Cu-doped and undoped ZnO thin films. J Mater Sci Mater Electron 27:7822–7828

    Article  Google Scholar 

Download references

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Shabannia, R. Structural, Optical and Electrical Properties of Cu-Doped ZnO Nanorods Grown on Flexible Polyethylene Terephthalate Substrate. Iran J Sci Technol Trans Sci 42, 2349–2353 (2018). https://doi.org/10.1007/s40995-017-0370-2

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  • DOI: https://doi.org/10.1007/s40995-017-0370-2

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