Abstract
The treatment of municipal solid waste leachate using electrocoagulation–flocculation with metal electrodes: aluminium (Al) and iron (Fe) were investigated in this work. The feasibility of using this method for leachate treatment was determined in terms of turbidity, chemical oxygen demand (COD), and colour removal. The influence of pH, current dosage, electrolysis time, setting time, temperature and NaCl concentration on the process were examined. The effects of using the hybrid of Al and Fe in different arrangements (Al–Al, Fe–Fe, Fe–Al and Al–Fe) were also considered for the ECF process. The applicability of the perikinetic flocculation theory proposed by Von Smoluchowski was confirmed for the study through the regression coefficient (R2) values. The time evolution of aggregating particles or species was predicted. The properties of the sludge (flocs) were determined via the Fourier transform infrared (FTIR) analysis. The optimum pH using Al–Al, Fe–Fe, Al–Fe, and Fe–Al were 2, 4, 10 and 2, respectively. Al–Al electrode presented a higher turbidity removal (93.12%) and COD removal (75.28%) on the leachate than the other electrodes arrangements. Fe–Fe electrodes were the best for colour reduction (73.25%). The kinetic data obeyed the Brownian perikinetic flocculation theory. The mechanisms that accounted for the particle distribution evolution were both sweep flocculation and charge neutralisation. The FTIR results indicate that the particles were adsorbed from the leachate and no significant changes in the composition of the sludge were observed using the different electrode arrangements. The electrocoagulation–flocculation was very effective for pollutants reduction from municipal leachate.
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Afsharnia M, Biglari H, Rasouli SS, Karimi A, Kianmehr M (2018) Sono-electrocoagulation of fresh leachate from municipal solid waste; simultaneous applying of iron and copper electrodes. Int J Electrochem Sci 13:472–484
APHA (1995) Standard methods for the examination of water and wastewater American Public Health Association, American Water Works Association, and Water Environment Federation, 9th ed, Washington DC, USA
APHA (1998) Standard methods for the examination of water and wastewater. American Public Health Association, American Water Works Association, and Water Environment Federation, Washington DC, pp 3–37
Bhagawan D, Poodari S, Chaitanya N, Ravi S, Rani YM, Himabindu V, Vidyavathi S (2017) Industrial solid waste landfill leachate treatment using electrocoagulation and biological methods Desalin. Water Treat 68:137–142
Bukhari AA (2008) Investigation of the electro-coagulation treatment process for the removal of total suspended solids and turbidity from municipal wastewater. Biores Technol 99:914–921
Calvo LS, Leclerc JP, Tanguy G, Cames M, Paternotte G, Valentin G, Rostan A, Lapicque F (2003) An electrocoagulation unit for the purification of soluble oil wastes of high COD. Environ Prog 22:57–65
Chou W-L, Wang C-T, Chang S-Y (2009) Study of COD and turbidity removal from real oxide-CMP wastewater by iron electrocoagulation and the evaluation of specific energy consumption. J Hazard Mater 168:1200–1207
Daneshvar N, Khataee A, Djafarzadeh N (2006) The use of artificial neural networks (ANN) for modeling of decolorization of textile dye solution containing CI Basic Yellow 28 by electrocoagulation process. J Hazard Mater 137:1788–1795
Elkacmi R, Kamil N, Bennajah M (2017) Upgrading of Moroccan olive mill wastewater using electrocoagulation: kinetic study and process performance evaluation. J Urban Environ Eng 11:30–41
El-Shazly A, Daous M (2013) Kinetics and performance of phosphate removal from hot industrial effluents using a continuous flow electrocoagulation reactor. Int J Electrochem Sci 8:184–194
El-Taweel YA, Nassef EM, Elkheriany I, Sayed D (2015) Removal of Cr (VI) ions from waste water by electrocoagulation using iron electrode. Egypt J Pet 24:183–192
EPA U (1993) Method 180.1: determination of turbidity by nephelometry. Rev. 2.0 Methods for chemical analisys of water and wastes
Fridrikhsberg DA (1986) A course in colloid chemistry. Imported Pubn, Chicago
Ghalwa A, Nasser M, Farhat N (2015) Removal of abamectin pesticide by electrocoagulation process using stainless steel and iron electrodes. J Env Anal Chem 2:134
Holt PK, Barton GW, Mitchell CA (2005) The future for electrocoagulation as a localised water treatment technology. Chemosphere 59:355–367
Holthoff H, Schmitt A, Fernández-Barbero A, Borkovec M, Ángel Cabrerízo-Vílchez M, Schurtenberger P, Hidalgo-Alvarez R (1997) Measurement of absolute coagulation rate constants for colloidal particles: comparison of single and multiparticle light scattering techniques. J Colloid Interface Sci 192:463–470
Hu C, Lo S, Kuan W (2003) Effects of co-existing anions on fluoride removal in electrocoagulation (EC) process using aluminum electrodes. Water Res 37:4513–4523
Hunter RJ (1993) Introduction to modern colloid science. Macmillan, London
Ighalo JO, Adeniyi AG (2020) A comprehensive review of water quality monitoring and assessment in Nigeria. Chemosphere 260:127569. https://doi.org/10.1016/j.chemosphere.2020.127569
Ighalo JO, Adeniyi AG, Adeniran JA, Ogunniyi S (2020) A systematic literature analysis of the nature and regional distribution of water pollution sources in Nigeria. J Clean Prod 283:124566. https://doi.org/10.1016/j.jclepro.2020.124566
Ighalo JO, Igwegbe CA, Aniagor CO, Oba SN (2021) A review of methods for the removal of penicillins from water. J Water Process Eng 39:101886. https://doi.org/10.1016/j.jwpe.2020.101886
Igwegbe CA (2019) Evaluation of bio- and electro-coagulants' activities on Fish pond wastewater and Solid waste leachate. Ph.D. dissertation submitted to the Department of Chemical Engineering
Igwegbe CA, Onukwuli OD (2019) Removal of total dissolved solids (TDS) from aquaculture wastewater by coagulation-flocculation process using sesamum indicum extract: effect of operating parameters and coagulation-flocculation kinetics. Pharm Chem J 6:32–45
Igwegbe CA, Onukwuli OD, Onyechi PC (2019) Optimal route for turbidity removal from aquaculture wastewater by electrocoagulation-flocculation process. J Eng Appl Sci 15:99–108
Igwegbe CA, Onukwuli OD, Ighalo JO, Menkiti MC (2021a) Bio-coagulation-flocculation (BCF) of municipal solid waste leachate using picralima nitida extract: RSM and ANN modelling. Curr Res Green Sustain Chem 100078
Igwegbe CA, Onukwuli OD, Ighalo JO, Umembamalu CJ (2021b) Electrocoagulation-flocculation of aquaculture effluent using hybrid iron and aluminium electrodes: a comparative study. Chem Eng J Adv 100107
Inyinbor Adejumoke A, Adebesin Babatunde O, Oluyori Abimbola P, Adelani Akande Tabitha A, Dada Adewumi O, Oreofe Toyin A (2018) Water pollution: effects, prevention, and climatic impact. Water Chall Urban World 33, pp 1–25
Ilhan F, Kurt U, Apaydin O, Gonullu MT (2008) Treatment of leachate by electrocoagulation using aluminum and iron electrodes. J Hazard Mater 154:381–389
Inanc B, Calli B, Saatci A (2000) Characterization and anaerobic treatment of the sanitary landfill leachate in Istanbul. Water Sci Technol 41:223–230
Irki S, Ghernaout D, Naceur MW, Alghamdi A, Aichouni M (2018) Decolorizing methyl orange by Fe-electrocoagulation process—a mechanistic insight. Int J Environ Chem 2:18
Janpoor F, Torabian A, Khatibikamal V (2011) Treatment of laundry waste-water by electrocoagulation. J Chem Technol Biotechnol 86:1113–1120
Jotin R, Ibrahim S, Halimoon N (2012) Electro coagulation for removal of chemical oxygen demand in sanitary landfill leachate. Int J Environ Sci 3:921–930
Kabdaşlı I, Arslan-Alaton I, Ölmez-Hancı T, Tünay O (2012) Electrocoagulation applications for industrial wastewaters: a critical review. Environ Technol Rev 1:2–45
Karichappan T, Venkatachalam S, Jeganathan PM (2014) Optimization of electrocoagulation process to treat grey wastewater in batch mode using response surface methodology. J Environ Health Sci Eng 12:29
Kim K-J, Baek K, Ji S, Cheong Y, Yim G, Jang A (2016) Study on electrocoagulation parameters (current density, pH, and electrode distance) for removal of fluoride from groundwater. Environ Earth Sci 75:45
Kjeldsen P, Barlaz MA, Rooker AP, Baun A, Ledin A, Christensen TH (2002) Present and long-term composition of MSW landfill leachate: a review. Crit Rev Environ Sci Technol 32:297–336
Kobya M, Demirbas E, Dedeli A, Sensoy M (2010) Treatment of rinse water from zinc phosphate coating by batch and continuous electrocoagulation processes. J Hazard Mater 173:326–334
Kurt U, Gonullu MT, Ilhan F, Varinca K (2008) Treatment of domestic wastewater by electrocoagulation in a cell with Fe–Fe electrodes. Environ Eng Sci 25:153–162. https://doi.org/10.1089/ees.2006.0132
Li X, Song J, Guo J, Wang Z, Feng Q (2011) Landfill leachate treatment using electrocoagulation. Procedia Environ Sci 10:1159–1164
Lippi M, Ley MBRG, Mendez GP, Junior RAFC (2018) State of art of landfill leachate treatment: literature review and critical evaluation. Ciência e Natura 40:78
Mahmad MKN, Rozainy MMR, Abustan I, Baharun N (2016) Electrocoagulation process by using aluminium and stainless steel electrodes to treat total chromium, colour and turbidity. Procedia Chem 19:681–686
Menkiti M (2007) Studies on coagulation and flocculation of coal washery effluent: turbid metric approach. M. Sc thesis, Nnamdi Azikiwe University Awka, Nigeria
Menkiti MC, Ezemagu IG (2015) Sludge characterization and treatment of produced water (PW) using Tympanotonos Fuscatus coagulant (TFC). Petroleum 1:51–62
Menkiti M, Igbokwe P, Ugodulunwa F, Onukwuli O (2008) Rapid coagulation/flocculation kinetics of coal effluent with high organic content using blended and unblended chitin derived coagulant (CSC) research. J Appl Sci 3:317–323
Menkiti MC, Nwoye CI, Onyechi CA, Onukwuli OD (2011) Factorial optimization and kinetics of coal washery effluent coag-flocculation by Moringa oleifera seed biomass. Adv Chem Eng Sci 1:125
Menkiti M, Onyechi C, Onukwuli O (2011) Evaluation of perikinetics compliance for the coag-flocculation of brewery effluent by Brachystegia eurycoma seed extract. Int J Multidiscip Sci Eng 2:77–83
Mishra S, Maiti A (2019) Study of simultaneous bioremediation of mixed reactive dyes and Cr (VI) containing wastewater through designed experiments. Environ Monit Assess 191:1–21
Mishra S, Cheng L, Maiti A (2020) The utilization of agro-biomass/byproducts for effective bio-removal of dyes from dyeing wastewater: a comprehensive review. J Environ Chem Eng 104901
Nwabanne JT, Obi CC (2017) Abattoir wastewater treatment by electrocoagulation using iron electrodes Der. Chem Sin 8:254–260
Nwabanne JT, Igwegbe CA, Okpo SO (2018a) Removal of copper, nickel, and chromium from simulated wastewater using electrocoagulation technique. In: International conference proceedings: faculty of engineering, Unizik. pp 448–4580
Nwabanne JT, Oguegbu OO, Agu CM (2018b) Removal of solids from palm oil mill effluent and paint wastewater using electrocoagulation technique. Int J Electrochem 2018:1–9
Ozturk D, Yilmaz A (2020) Investigation of electrochemical degradation of Basic Red 13 dye in aqueous solutions based on COD removal: numerical optimization approach. Int J Environ Sci Technol 17:3099–3110
Ozturk D, Dagdas E, Fil BA, Bashir MJ (2021) Central composite modeling for electrochemical degradation of paint manufacturing plant wastewater: one-step/two-response optimization. Environ Technol Innov 21:101264
Park S, Kruis F, Lee K, Fissan H (2002) Evolution of particle size distributions due to turbulent and Brownian coagulation. Aerosol Sci Technol 36:419–432
Parsa JB, Vahidian HR, Soleymani A, Abbasi M (2011) Removal of Acid Brown 14 in aqueous media by electrocoagulation: optimization parameters and minimizing of energy consumption. Desalination 278:295–302
Phalakornkule C, Polgumhang S, Tongdaung W (2009) Performance of an electrocoagulation process in treating direct dye: batch and continuous upflow processes. World Acad Sci Technol 57:277–282
Pletcher F, Walsh D (1990) Industrial electrochemistry, vol 1, 2nd edn. Chapman and Hall, London, p 5
Prasetyaningrum A, Jos B, Dharmawan Y, Prabowo BT, Fathurrazan M (2018) The influence of electrode type on electrocoagulation process for removal of chromium (VI) metal in plating industrial wastewater. J Phys 1025:01212
Raghab SM, Abd El Meguid AM, Hegazi HA (2013) Treatment of leachate from municipal solid waste landfill. HBRC J 9:187–192
Renou S, Givaudan J, Poulain S, Dirassouyan F, Moulin P (2008) Landfill leachate treatment: review and opportunity. J Hazard Mater 150:468–493
Sadeddin K, Naser A, Firas A (2011) Removal of turbidity and suspended solids by electro-coagulation to improve feed water quality of reverse osmosis plant. Desalination 268:204–207
Safari S, Aghdam MA, Kariminia H-R (2016) Electrocoagulation for COD and diesel removal from oily wastewater. Int J Environ Sci Technol 13:231–242
Salman RH, Hassan HA, Abed KM, Al-Alawy AF, Tuama DA, Hussein KM, Jabir HA (2020) Removal of chromium ions from a real wastewater of leather industry using electrocoagulation and reverse osmosis processes. In: AIP conference proceedings. vol 1. AIP Publishing LLC, p 020186
Shak KPY, Wu TY (2014) Coagulation–flocculation treatment of high-strength agro-industrial wastewater using natural Cassia obtusifolia seed gum: treatment efficiencies and flocs characterization. Chem Eng J 256:293–305
Smoluchowski M (1917) Versuch einer mathematischen Theorie der Koagulationskinetik kolloider Lösungen
Song P, Yang Z, Zeng G, Yang X, Xu H, Wang L, Xu R, Xiong W, Ahmad K (2017) Electrocoagulation treatment of arsenic in wastewaters: a comprehensive review. Chem Eng J 317:707–725
Sontaya K, Pitiyont B, Punsuvon V (2013) Decolorization and COD removal of palm oil mill wastewater by electrocoagulation. Int J Environ Sci Eng 7:370–374
Teh CY, Wu TY, Juan JC (2014) Optimization of agro-industrial wastewater treatment using unmodified rice starch as a natural coagulant. Ind Crops Prod 56:17–26
Ugonabo V, Menkiti M, Onukwuli O (2012) Coagulation kinetics and performance evaluation of Corchorus olitorus seed in pharmaceutical effluent. Int J Multidiscip Sci Eng 3:20–32
Ugonabo VI, Emembolu LN, Igwegbe CA (2016) Bio-coag-flocculation of refined petroleum wastewater using plant extract: a turbidimeric approach. Int J:19–26
Yoosefian M, Ahmadzadeh S, Aghasi M, Dolatabadi M (2017) Optimization of electrocoagulation process for efficient removal of ciprofloxacin antibiotic using iron electrode; kinetic and isotherm studies of adsorption. J Mol Liq 225:544–553
Yousefi M, Ghoochani M, Mahvi AH (2018) Health risk assessment to fluoride in drinking water of rural residents living in the Poldasht city, Northwest of Iran. Ecotoxicol Environ Saf 148:426–430
Zaied M, Bellakhal N (2009) Electrocoagulation treatment of black liquor from paper industry. J Hazard Mater 163:995–1000
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We wish to acknowledge Prof. J. T. Nwabanne, Prof. M. C. Menkiti and Prof. (Mrs.) N.E. Nwaiwu for giving us insights.
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Igwegbe, C.A., Onukwuli, O.D., Ighalo, J.O. et al. Comparative analysis on the electrochemical reduction of colour, COD and turbidity from municipal solid waste leachate using aluminium, iron and hybrid electrodes. Sustain. Water Resour. Manag. 7, 39 (2021). https://doi.org/10.1007/s40899-021-00524-w
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DOI: https://doi.org/10.1007/s40899-021-00524-w