Abstract
Electrocatalytic carbon dioxide reduction reaction (CO2RR) offers a promising solution for mitigating environmental challenges by converting CO2 into value-added chemicals and fuels. However, the long-term stability of CO2RR systems remains a major bottleneck impeding large-scale commercial implementation. This review summarizes recent progress on elucidating the root causes underlying stability declines in CO2RR and strategies to address them. First, catalysts undergo structural transformations (e.g., reconstruction, aggregation, dissolution) under applied reduction potentials, decreasing the density of active sites. Catalyst poisoning via carbon deposition or feed impurities (e.g., SO2) also reduces site availability. Second, gas diffusion layer (GDL) flooding and salt precipitation hinder reactant/product transport and destroy catalyst-electrolyte-gas three-phase interfaces. High applied pressures induce GDL cracking over prolonged operation. Third, alkaline electrolytes neutralize with CO2 and precipitate carbonate salts, while acidic media corrode catalysts and favor competing hydrogen evolution reaction. Metal ion impurities deposit on catalyst surfaces further exacerbating decays. Rational catalyst and GDL design can construct stabilized microenvironments, though additional advances in materials properties, operating conditions, and impurity removal are essential to extend CO2RR lifetime for commercial needs (>50,000 h). Understanding cross-coupling between the diverse deteriorative phenomena will advance the development of this important frontier.
摘要
电催化二氧化碳还原反应(CO2RR)能够利用可再生电能将CO2转化为高附加值化学品和燃料, 是一项有望缓解当下环境挑战的技术方案. 本文总结了CO2RR稳定性下降的根本原因, 并探讨了解决这一问题的有效策略以及最新的研究进展. 首先, 在外加电位的作用下, 催化剂会发生结构转变, 且碳沉积或气体杂质引起的催化剂中毒都会降低CO2RR的稳定性. 其次, 气体扩散层(GDL)附近发生水淹和盐沉淀会阻碍反应物/生成物的传输, 三相界面会受到破坏. 在长时间服役时, 液压和电流的作用会导致GDL开裂. 在电解质方面, 碱性电解质会与CO2中和, 形成碳酸盐沉淀; 而酸性介质腐蚀催化剂, 并伴随严重的析氢副反应. 另外, 电解质中的金属离子杂质的优先还原进一步加剧了稳定性的衰减. 深入理解CO2RR中各类失活现象对设计稳定、高效的CO2电催化系统具有指导意义. 针对CO2RR稳定性研究目前所面临的困境, 本文最后展望了该领域未来的研究方向.
Similar content being viewed by others
References
Gao FY, Bao RC, Gao MR, et al. Electrochemical CO2-to-CO conversion: Electrocatalysts, electrolytes, and electrolyzers. J Mater Chem A, 2020, 8: 15458–15478
Li L, Ozden A, Guo S, et al. Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites. Nat Commun, 2021, 12: 5223
Wu ZZ, Zhang XL, Niu ZZ, et al. Identification of Cu(100)/Cu(111) interfaces as superior active sites for CO dimerization during CO2 electroreduction. J Am Chem Soc, 2022, 144: 259–269
Wang P, Yang H, Tang C, et al. Boosting electrocatalytic CO2-to-ethanol production via asymmetric C-C coupling. Nat Commun, 2022, 13: 3754
Wang X, Ou P, Ozden A, et al. Efficient electrosynthesis of n-propanol from carbon monoxide using a Ag–Ru–Cu catalyst. Nat Energy, 2022, 7: 170–176
Kim D, Kley CS, Li Y, et al. Copper nanoparticle ensembles for selective electroreduction of CO2 to C2–C3 products. Proc Natl Acad Sci USA, 2017, 114: 10560–10565
Cai T, Sun H, Qiao J, et al. Cell-free chemoenzymatic starch synthesis from carbon dioxide. Science, 2021, 373: 1523–1527
Wang Z, Li Y, Zhao X, et al. Localized alkaline environment via in situ electrostatic confinement for enhanced CO2-to-ethylene conversion in neutral medium. J Am Chem Soc, 2023, 145: 6339–6348
Wen CF, Zhou M, Liu PF, et al. Highly ethylene-selective electrocatalytic CO2 reduction enabled by isolated Cu–S motifs in metal-organic framework based precatalysts. Angew Chem Int Ed, 2022, 61: e202111700
Zhao Y, Zu X, Chen R, et al. Industrial-current-density CO2-to-C2+ electroreduction by anti-swelling anion-exchange ionomer-modified oxide-derived Cu nanosheets. J Am Chem Soc, 2022, 144: 10446–10454
Xi D, Li J, Low J, et al. Limiting the uncoordinated N species in M–Nx single-atom catalysts toward electrocatalytic CO2 reduction in broad voltage range. Adv Mater, 2022, 34: 2104090
Nam DH, Shekhah O, Lee G, et al. Intermediate binding control using metal-organic frameworks enhances electrochemical CO2 reduction. J Am Chem Soc, 2020, 142: 21513–21521
Stephens IEL, Chan K, Bagger A, et al. 2022 roadmap on low temperature electrochemical CO2 reduction. J Phys Energy, 2022, 4: 042003
Martin AJ, Mitchell S, Mondelli C, et al. Unifying views on catalyst deactivation. Nat Catal, 2022, 5: 854–866
Popović S, Smiljanić M, Jovanovič P, et al. Stability and degradation mechanisms of copper-based catalysts for electrochemical CO2 reduction. Angew Chem Int Ed, 2020, 59: 14736–14746
Lei Q, Huang L, Yin J, et al. Structural evolution and strain generation of derived-Cu catalysts during CO2 electroreduction. Nat Commun, 2022, 13: 4857
Yanson AI, Rodriguez P, Garcia-Araez N, et al. Cathodic corrosion: A quick, clean, and versatile method for the synthesis of metallic nanoparticles. Angew Chem Int Ed, 2011, 50: 6346–6350
Osowiecki WT, Nussbaum JJ, Kamat GA, et al. Factors and dynamics of Cu nanocrystal reconstruction under CO2 reduction. ACS Appl Energy Mater, 2019, 2: 7744–7749
Liu F, Ren X, Zhao J, et al. Inhibiting sulfur dissolution and enhancing activity of SnS for CO2 electroreduction via electronic state modulation. ACS Catal, 2022, 12: 13533–13541
De Luna P, Quintero-Bermudez R, Dinh CT, et al. Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction. Nat Catal, 2018, 1: 103–110
Zhong D, Zhao ZJ, Zhao Q, et al. Coupling of Cu(100) and (110) facets promotes carbon dioxide conversion to hydrocarbons and alcohols. Angew Chem Int Ed, 2021, 60: 4879–4885
Peng H, Tang MT, Liu X, et al. The role of atomic carbon in directing electrochemical CO(2) reduction to multicarbon products. Energy Environ Sci, 2021, 14: 473–482
Xiang K, Zhu F, Liu Y, et al. A strategy to eliminate carbon deposition on a copper electrode in order to enhance its stability in CO2RR catalysis by introducing crystal defects. Electrochem Commun, 2019, 102: 72–77
Luc W, Ko BH, Kattel S, et al. SO2-induced selectivity change in CO2 electroreduction. J Am Chem Soc, 2019, 141: 9902–9909
Legrand U, Apfel UP, Boffito DC, et al. The effect of flue gas contaminants on the CO2 electroreduction to formic acid. J CO2 Util, 2020, 42: 101315
Skafte TL, Blennow P, Hjelm J, et al. Carbon deposition and sulfur poisoning during CO2 electrolysis in nickel-based solid oxide cell electrodes. J Power Sources, 2018, 373: 54–60
Ma Y, Meng X, Li K, et al. Scrutinizing synergy and active site of nitrogen and selenium dual-doped porous carbon for efficient triiodide reduction. ACS Catal, 2023, 13: 1290–1298
Du Y, Meng X, Wang Z, et al. Graphene-based catalysts for CO2 electroreduction. Acta Physico Chim Sin, 2021, 0: 2101009–0
Meng X, Yu C, Song X, et al. Scrutinizing defects and defect density of selenium-doped graphene for high-efficiency triiodide reduction in dye-sensitized solar cells. Angew Chem Int Ed, 2018, 57: 4682–4686
Wakerley D, Lamaison S, Wicks J, et al. Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers. Nat Energy, 2022, 7: 130–143
Nguyen TN, Dinh CT. Gas diffusion electrode design for electrochemical carbon dioxide reduction. Chem Soc Rev, 2020, 49: 7488–7504
Li L, Chen J, Mosali VSS, et al. Hydrophobicity graded gas diffusion layer for stable electrochemical reduction of CO2. Angew Chem Int Ed, 2022, 61: e202208534
Shi R, Guo J, Zhang X, et al. Efficient wettability-controlled electro-reduction of CO2 to CO at Au/C interfaces. Nat Commun, 2020, 11: 3028
Gabardo CM, O’Brien CP, Edwards JP, et al. Continuous carbon dioxide electroreduction to concentrated multi-carbon products using a membrane electrode assembly. Joule, 2019, 3: 2777–2791
Monteiro MCO, Koper MTM. Measuring local pH in electrochemistry. Curr Opin Electrochem, 2021, 25: 100649
Nguyen TN, Chen Z, Zeraati AS, et al. Catalyst regeneration via chemical oxidation enables long-term electrochemical carbon dioxide reduction. J Am Chem Soc, 2022, 144: 13254–13265
Kong Y, Liu M, Hu H, et al. Cracks as efficient tools to mitigate flooding in gas diffusion electrodes used for the electrochemical reduction of carbon dioxide. Small Methods, 2022, 6: 2200369
Yang PP, Gao MR. Enrichment of reactants and intermediates for electrocatalytic CO2 reduction. Chem Soc Rev, 2023, 52: 4343–4380
Chen X, Yang T, Kataoka S, et al. Specific ion effects on interfacial water structure near macromolecules. J Am Chem Soc, 2007, 129: 12272–12279
Li H, Liu T, Wei P, et al. High-rate CO2 electroreduction to C2+ products over a copper-copper Iodide catalyst. Angew Chem Int Ed, 2021, 60: 14329–14333
Kastlunger G, Wang L, Govindarajan N, et al. Using pH dependence to understand mechanisms in electrochemical CO reduction. ACS Catal, 2022, 12: 4344–4357
Zhao Y, Hao L, Ozden A, et al. Conversion of CO2 to multicarbon products in strong acid by controlling the catalyst microenvironment. Nat Synth, 2023, 2: 403–412
Shen H, Jin H, Li H, et al. Acidic CO2-to-HCOOH electrolysis with industrial-level current on phase engineered tin sulfide. Nat Commun, 2023, 14: 2843
Hao Q, Liu DX, Zhong HX, et al. Electrocatalytic CO2 reduction in acidic medium. Chem Catal, 2023, 3: 100542
Schuhle P, Schmidt M, Schill L, et al. Influence of gas impurities on the hydrogenation of CO2 to methanol using indium-based catalysts. Catal Sci Technol, 2020, 10: 7309–7322
Gunathunge CM, Li X, Li J, et al. Spectroscopic observation of reversible surface reconstruction of copper electrodes under CO2 reduction. J Phys Chem C, 2017, 121: 12337–12344
Li F, Medvedeva XV, Medvedev JJ, et al. Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts. Nat Catal, 2021, 4: 479–487
Jeong S, Choi MH, Jagdale GS, et al. Unraveling the structural sensitivity of CO2 electroreduction at facet-defined nanocrystals via correlative single-entity and macroelectrode measurements. J Am Chem Soc, 2022, 144: 12673–12680
Lei Q, Zhu H, Song K, et al. Investigating the origin of enhanced C2+ selectivity in oxide-/hydroxide-derived copper electrodes during CO2 electroreduction. J Am Chem Soc, 2020, 142: 4213–4222
Ren S, Lees EW, Hunt C, et al. Catalyst aggregation matters for immobilized molecular CO2RR electrocatalysts. J Am Chem Soc, 2023, 145: 4414–4420
Meng X, Liu X, Fan X, et al. Single-atom catalyst aggregates: Size-matching is critical to electrocatalytic performance in sulfur cathodes. Adv Sci, 2022, 9: 2103773
Velasco-Vélez JJ, Jones T, Gao D, et al. The role of the copper oxidation state in the electrocatalytic reduction of CO2 into valuable hydrocarbons. ACS Sustain Chem Eng, 2019, 7: 1485–1492
Velasco-Vélez JJ, Chuang CH, Gao D, et al. On the activity/selectivity and phase stability of thermally grown copper oxides during the electrocatalytic reduction of CO2. ACS Catal, 2020, 10: 11510–11518
Yang KD, Ko WR, Lee JH, et al. Morphology-directed selective production of ethylene or ethane from CO2 on a Cu mesopore electrode. Angew Chem Int Ed, 2017, 56: 796–800
Pang Y, Li J, Wang Z, et al. Efficient electrocatalytic conversion of carbon monoxide to propanol using fragmented copper. Nat Catal, 2019, 2: 251–258
Eren B, Weatherup RS, Liakakos N, et al. Dissociative carbon dioxide adsorption and morphological changes on Cu(100) and Cu(111) at ambient pressures. J Am Chem Soc, 2016, 138: 8207–8211
Wu ZZ, Zhang XL, Yang PP, et al. Gerhardtite as a precursor to an efficient CO-to-acetate electroreduction catalyst. J Am Chem Soc, 2023, 145: 24338–24348
Gao FY, Hu SJ, Zhang XL, et al. High-curvature transition-metal chalcogenide nanostructures with a pronounced proximity effect enable fast and selective CO2 electroreduction. Angew Chem Int Ed, 2020, 59: 8706–8712
Mariano RG, Kang M, Wahab OJ, et al. Microstructural origin of locally enhanced CO2 electroreduction activity on gold. Nat Mater, 2021, 20: 1000–1006
Moller T, Scholten F, Thanh TN, et al. Electrocatalytic CO2 reduction on CuOx nanocubes: Tracking the evolution of chemical state, geometric structure, and catalytic selectivity using operando spectroscopy. Angew Chem Int Ed, 2020, 59: 17974–17983
Peng J, Chen B, Wang Z, et al. Surface coordination layer passivates oxidation of copper. Nature, 2020, 586: 390–394
Zhang Y, Lan J, Xie F, et al. Aligned InS nanorods for efficient electrocatalytic carbon dioxide reduction. ACS Appl Mater Interfaces, 2022, 14: 25257–25266
Gao FY, Wu ZZ, Gao MR. Electrochemical CO2 reduction on transition-metal chalcogenide catalysts: Recent advances and future perspectives. Energy Fuels, 2021, 35: 12869–12883
Chi LP, Niu ZZ, Zhang XL, et al. Stabilizing indium sulfide for CO2 electroreduction to formate at high rate by zinc incorporation. Nat Commun, 2021, 12: 5835
Huang J, Hörmann N, Oveisi E, et al. Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction. Nat Commun, 2018, 9: 3117
Grosse P, Gao D, Scholten F, et al. Dynamic changes in the structure, chemical state and catalytic selectivity of Cu nanocubes during CO2 electroreduction: Size and support effects. Angew Chem Int Ed, 2018, 57: 6192–6197
Zhong M, Tran K, Min Y, et al. Accelerated discovery of CO2 electrocatalysts using active machine learning. Nature, 2020, 581: 178–183
Ma J, Wu D, Feng Y, et al. Physical mixing of piezo-electrocatalysts and graphene oxide to promote CO2 conversion. Nano Energy, 2023, 115: 108719
Qiao H, Saray MT, Wang X, et al. Scalable synthesis of high entropy alloy nanoparticles by microwave heating. ACS Nano, 2021, 15: 14928–14937
Weng Z, Zhang X, Wu Y, et al. Self-cleaning catalyst electrodes for stabilized CO2 reduction to hydrocarbons. Angew Chem Int Ed, 2017, 56: 13135–13139
Moradzaman M, Mul G. In situ Raman study of potential-dependent surface adsorbed carbonate, CO, OH, and C species on Cu electrodes during electrochemical reduction of CO2. ChemElectroChem, 2021, 8: 1478–1485
Zhai Y, Chiachiarelli L, Sridhar N. Effect of gaseous impurities on the electrochemical reduction of CO2 on copper electrodes. ECS Trans, 2009, 19: 1–13
Birdja YY, Pérez-Gallent E, Figueiredo MC, et al. Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels. Nat Energy, 2019, 4: 732–745
Nie X, Luo W, Janik MJ, et al. Reaction mechanisms of CO2 electrochemical reduction on Cu(111) determined with density functional theory. J Catal, 2014, 312: 108–122
Duanmu JW, Wu ZZ, Gao FY, et al. Investigation and mitigation of carbon deposition over copper catalyst during electrochemical CO2 reduction. Precis Chem, 2024, 2: 151–160
Hauch A, Traulsen ML, Küngas R, et al. CO2 electrolysis–Gas impurities and electrode overpotential causing detrimental carbon deposition. J Power Sources, 2021, 506: 230108
Liu S, Yang C, Zha S, et al. Moderate surface segregation promotes selective ethanol production in CO2 hydrogenation reaction over CoCu catalysts. Angew Chem Int Ed, 2022, 61: 230108
Li F, Thevenon A, Rosas-Hernández A, et al. Molecular tuning of CO2-to-ethylene conversion. Nature, 2020, 577: 509–513
Zhang J, Luo W, Zuttel A. Crossover of liquid products from electrochemical CO2 reduction through gas diffusion electrode and anion exchange membrane. J Catal, 2020, 385: 140–145
Chen Q, Wang X, Zhou Y, et al. Electrocatalytic CO2 reduction to C2+ products in flow cells. Adv Mater, 2024, 36: 2303902
Clark EL, Resasco J, Landers A, et al. Standards and protocols for data acquisition and reporting for studies of the electrochemical reduction of carbon dioxide. ACS Catal, 2018, 8: 6560–6570
Burdyny T, Smith WA. CO2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions. Energy Environ Sci, 2019, 12: 1442–1453
García de Arquer FP, Dinh CT, Ozden A, et al. CO2 electrolysis to multicarbon products at activities greater than 1 A cm−2. Science, 2020, 367: 661–666
Xing Z, Hu L, Ripatti DS, et al. Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment. Nat Commun, 2021, 12: 136
Wakerley D, Lamaison S, Ozanam F, et al. Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface. Nat Mater, 2019, 18: 1222–1227
Li J, Chen G, Zhu Y, et al. Efficient electrocatalytic CO2 reduction on a three-phase interface. Nat Catal, 2018, 1: 592–600
Bienen F, Paulisch MC, Mager T, et al. Investigating the electrowetting of silver-based gas-diffusion electrodes during oxygen reduction reaction with electrochemical and optical methods. Electrochem Sci Adv, 2022, 3: e2100158
Leonard MLE, Clarke LE, Forner-Cuenca A, et al. Investigating electrode flooding in a flowing electrolyte, gas-fed carbon dioxide electrolyzer. ChemSusChem, 2019, 13: 400–411
Cao Y, Chen Z, Li P, et al. Surface hydroxide promotes CO2 electrolysis to ethylene in acidic conditions. Nat Commun, 2023, 14: 2387
Nam DH, Shekhah O, Ozden A, et al. High-rate and selective CO2 electrolysis to ethylene via metal-organic-framework-augmented CO2 availability. Adv Mater, 2022, 34: 2207088
Gao FY, Liu SN, Ge JC, et al. Nickel-molybdenum-niobium metallic glass for efficient hydrogen oxidation in hydroxide exchange membrane fuel cells. Nat Catal, 2022, 5: 993–1005
Wang Z, Yang Y, Zhao Z, et al. Green synthesis of olefin-linked covalent organic frameworks for hydrogen fuel cell applications. Nat Commun, 2021, 12: 1982
Wu Y, Charlesworth L, Maglaya I, et al. Mitigating electrolyte flooding for electrochemical CO2 reduction via infiltration of hydrophobic particles in a gas diffusion layer. ACS Energy Lett, 2022, 7: 2884–2892
Yang K, Kas R, Smith WA, et al. Role of the carbon-based gas diffusion layer on flooding in a gas diffusion electrode cell for electrochemical CO2 reduction. ACS Energy Lett, 2020, 6: 33–40
Barrio J, Pedersen A, Favero S, et al. Bioinspired and bioderived aqueous electrocatalysis. Chem Rev, 2023, 123: 2311–2348
DuanMu JW, Gao MR. Advances in bio-inspired electrocatalysts for clean energy future. Nano Res, 2024, 17: 515–533
Niu ZZ, Gao FY, Zhang XL, et al. Hierarchical copper with inherent hydrophobicity mitigates electrode flooding for high-rate CO2 electroreduction to multicarbon products. J Am Chem Soc, 2021, 143: 8011–8021
Li J, Shang B, Gao Y, et al. Mechanism-guided realization of selective carbon monoxide electroreduction to methanol. Nat Synth, 2023, 2: 1194–1201
Han Z, Han D, Chen Z, et al. Steering surface reconstruction of copper with electrolyte additives for CO2 electroreduction. Nat Commun, 2022, 13: 3158
Sassenburg M, Kelly M, Subramanian S, et al. Zero-gap electrochemical CO2 reduction cells: Challenges and operational strategies for prevention of salt precipitation. ACS Energy Lett, 2022, 8: 321–331
Subramanian S, Yang K, Li M, et al. Geometric catalyst utilization in zero-gap CO2 electrolyzers. ACS Energy Lett, 2022, 8: 222–229
Xiao L, Bian M, Zhu L, et al. High-density and low-density gas diffusion layers for proton exchange membrane fuel cells: Comparison of mechanical and transport properties. Int J Hydrogen Energy, 2022, 47: 22532–22544
Liu H, Wang C, Gao Q, et al. Fabrication of novel core-shell hybrid alginate hydrogel beads. Int J Pharm, 2008, 351: 104–112
Liu J, Li P, Bi J, et al. Design and preparation of electrocatalysts by electrodeposition for CO2 reduction. Chem Eur J, 2022, 28: e202200242
Zhang L, Wei Z, Thanneeru S, et al. A polymer solution to prevent nanoclustering and improve the selectivity of metal nanoparticles for electrocatalytic CO2 reduction. Angew Chem Int Ed, 2019, 58: 15834–15840
Nam DH, De Luna P, Rosas-Hernandez A, et al. Molecular enhancement of heterogeneous CO2 reduction. Nat Mater, 2020, 19: 266–276
Bi J, Li P, Liu J, et al. Construction of 3D copper-chitosan-gas diffusion layer electrode for highly efficient CO2 electrolysis to C2+ alcohols. Nat Commun, 2023, 14: 2823
Baricuatro JH, Kwon S, Kim YG, et al. Operando electrochemical spectroscopy for CO on Cu(100) at pH 1 to 13: Validation of grand canonical potential predictions. ACS Catal, 2021, 11: 3173–3181
Marcandalli G, Goyal A, Koper MTM. Electrolyte effects on the Faradaic efficiency of CO2 reduction to CO on a gold electrode. ACS Catal, 2021, 11: 4936–4945
Monteiro MCO, Dattila F, Hagedoorn B, et al. Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution. Nat Catal, 2021, 4: 654–662
Chen C, Li Y, Yang P. Address the “alkalinity problem” in CO2 electrolysis with catalyst design and translation. Joule, 2021, 5: 737–742
Ma M, Zheng Z, Yan W, et al. Rigorous evaluation of liquid products in high-rate CO2/CO electrolysis. ACS Energy Lett, 2022, 7: 2595–2601
Zhang L, Feng J, Liu S, et al. Atomically dispersed Ni-Cu catalysts for pH-universal CO2 electroreduction. Adv Mater, 2023, 35: 2209590
Xu K, Li J, Liu F, et al. Favoring CO intermediate stabilization and protonation by crown ether for CO2 electromethanation in acidic media. Angew Chem Int Ed, 2023, 62: e202311968
Ling N, Zhang J, Wang M, et al. Acidic media impedes tandem catalysis reaction pathways in electrochemical CO2 reduction. Angew Chem Int Ed, 2023, 62: e202308782
Ovalle VJ, Hsu YS, Agrawal N, et al. Correlating hydration free energy and specific adsorption of alkali metal cations during CO2 electroreduction on Au. Nat Catal, 2022, 5: 624–632
Gu J, Liu S, Ni W, et al. Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium. Nat Catal, 2022, 5: 268–276
Hori Y, Konishi H, Futamura T, et al. “Deactivation of copper electrode” in electrochemical reduction of CO2. Electrochim Acta, 2005, 50: 5354–5369
Welch AJ, Fenwick AQ, Böhme A, et al. Operando local pH measurement within gas diffusion electrodes performing electrochemical carbon dioxide reduction. J Phys Chem C, 2021, 125: 20896–20904
Zhang T, Bui JC, Li Z, et al. Highly selective and productive reduction of carbon dioxide to multicarbon products via in situ CO management using segmented tandem electrodes. Nat Catal, 2022, 5: 202–211
Dinh CT, Burdyny T, Kibria MG, et al. CO2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface. Science, 2018, 360: 783–787
Li L, Liu Z, Yu X, et al. Achieving high single-pass carbon conversion efficiencies in durable CO2 electroreduction in strong acids via electrode structure engineering. Angew Chem Int Ed, 2023, 62: e202300226
Xie Y, Ou P, Wang X, et al. High carbon utilization in CO2 reduction to multi-carbon products in acidic media. Nat Catal, 2022, 5: 564–570
Ma Z, Yang Z, Lai W, et al. CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment. Nat Commun, 2022, 13: 7596
Fan Q, Bao GX, Chen X, et al. Iron nanoparticles tuned to catalyze CO2 electroreduction in acidic solutions through chemical microenvironment engineering. ACS Catal, 2022, 12: 7517–7523
Chi LP, Niu ZZ, Zhang YC, et al. Efficient and stable acidic CO2 electrolysis to formic acid by a reservoir structure design. Proc Natl Acad Sci USA, 2023, 120: e2312876120
Kas R, Kortlever R, Yilmaz H, et al. Manipulating the hydrocarbon selectivity of copper nanoparticles in CO2 electroreduction by process conditions. ChemElectroChem, 2015, 2: 354–358
Wuttig A, Surendranath Y. Impurity ion complexation enhances carbon dioxide reduction catalysis. ACS Catal, 2015, 5: 4479–4484
Acknowledgements
This work was supported by the National Basic Research Program of China (2018YFA0702001), the National Natural Science Foundation of China (22225901, 21975237 and 51702312), the Fundamental Research Funds for the Central Universities (WK2340000101), the University of Science and Technology of China Research Funds of the Double First-Class Initiative (YD2340002007 and YD9990002017), the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization (RERU2022007), the China Postdoctoral Science Foundation (2023M733371, 2022M723032, and 2023T160617), the Natural Science Foundation Youth Project of Anhui Province (2308085QB37), and the China National Postdoctoral Program for Innovative Talents (BX2023341).
Author information
Authors and Affiliations
Contributions
Author contributions DuanMu JW collected the material references and wrote the review. Gao FY collected the materials of figures. Gao MR directed and revised the manuscript. All authors have given approval to the final version of the manuscript.
Corresponding author
Ethics declarations
Conflict of interest The authors declare that they have no conflict of interest.
Additional information
Jing-Wen DuanMu received her BSc degree in materials chemistry from the University of Science and Technology of China in 2021. She joined in Prof. Min-Rui Gao’s laboratory in 2021, focusing on the design and synthesis of nanomaterials and their stability. She is currently a master’s student at the University of Science and Technology of China. Her main research interests are carbon dioxide electroreduction reaction mechanism and catalyst design.
Min-Rui Gao received his PhD degree from the University of Science and Technology of China, under the supervision of Prof. Shu-Hong Yu in 2012. He then did postdoctoral research at the University of Delaware and Argonne National Laboratory (USA) in 2012–2015. After that, he worked in the Department of Colloid Chemistry, directed by Prof. Markus Antonietti, in the Max Plank Institute of Colloids and Interfaces in Potsdam (Germany) in 2015–2016. He is currently a full professor at the University of Science and Technology of China. His research interest involves the development of nanostructured materials and their applications in energy fields.
Rights and permissions
About this article
Cite this article
DuanMu, JW., Gao, FY. & Gao, MR. A critical review of operating stability issues in electrochemical CO2 reduction. Sci. China Mater. (2024). https://doi.org/10.1007/s40843-024-2835-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40843-024-2835-3