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Towards industrialization of graphene oxide

氧化石墨烯的工业化进展

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Abstract

Graphene oxide (GO) has demonstrated potential applications in various fields, and attracted intensive attention in industry as well. Numerous companies worldwide have been working on the industrial applications of GO-based materials in, e.g., thermal management, multifunctional composites, anti-corrosion paints, lubricants, energy storage, environment protection and biomedicals. This review presents a short summary on the proceedings of GO towards industrialization, including the large-scale production and some promising applications, by providing views on the processing strategies and challenges specifically for the industrial use of GO. This review would help the scientists in this area to find topics for overcoming challenges together with engineers.

摘要

相关研究表明氧化石墨烯(GO)在众多领域皆具有应用潜力, 因此GO越来越受工业界的关注. 目前, 全球已涌现了许多公司, 致 力于实现GO的工业级应用, 如热管理、多功能聚合物复合材料、 防腐、润滑剂、能源、环境和生物医学等. 本文主要介绍了当前 GO工业化的发展情况, 包括GO的大规模生产以及具有市场经济 价值的应用, 并讨论了GO在工业化过程中的挑战和处理策略, 旨 在为本领域的科学家提供研究素材, 以期在工业界实现GO的规模 化应用.

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References

  1. Dreyer DR, Park S, Bielawski CW, et al. The chemistry of graphene oxide. Chem Soc Rev, 2010, 39: 228–240

    CAS  Google Scholar 

  2. Chen D, Feng H, Li J. Graphene oxide: Preparation, functionalization, and electrochemical applications. Chem Rev, 2012, 112: 6027–6053

    CAS  Google Scholar 

  3. Bianco A, Cheng HM, Enoki T, et al. All in the graphene family-A recommended nomenclature for two-dimensional carbon materials. Carbon, 2013, 65: 1–6

    CAS  Google Scholar 

  4. He H, Klinowski J, Forster M, et al. A new structural model for graphite oxide. Chem Phys Lett, 1998, 287: 53–56

    CAS  Google Scholar 

  5. Gomez-Navarro C, Meyer JC, Sundaram RS, et al. Atomic structure of reduced graphene oxide. Nano Lett, 2010, 10: 1144–1148

    CAS  Google Scholar 

  6. Erickson K, Erni R, Lee Z, et al. Determination of the local chemical structure of graphene oxide and reduced graphene oxide. Adv Mater, 2010, 22: 4467–4472

    CAS  Google Scholar 

  7. Dimiev AM, Alemany LB, Tour JM. Graphene oxide. Origin of acidity, its instability in water, and a new dynamic structural model. ACS Nano, 2013, 7: 576–588

    CAS  Google Scholar 

  8. Rourke JP, Pandey PA, Moore JJ, et al. The real graphene oxide revealed: Stripping the oxidative debris from the graphene-like sheets. Angew Chem, 2011, 123: 3231–3235

    Google Scholar 

  9. Brodie BC. XIII. On the atomic weight of graphite. Philosophical Transactions of the Royal Society of London, 1859, 149: 249–259

    Google Scholar 

  10. Botas C, Álvarez P, Blanco P, et al. Graphene materials with different structures prepared from the same graphite by the Hummers and Brodie methods. Carbon, 2013, 65: 156–164

    CAS  Google Scholar 

  11. Staudenmaier L. Verfahren zur Darstellung der Graphitsäure. Ber Dtsch Chem Ges, 1898, 31: 1481–1487

    CAS  Google Scholar 

  12. Hummers Jr. WS, Offeman RE. Preparation of graphitic oxide. J Am Chem Soc, 1958, 80: 1339

    CAS  Google Scholar 

  13. Dimiev AM, Tour JM. Mechanism of graphene oxide formation. ACS Nano, 2014, 8: 3060–3068

    CAS  Google Scholar 

  14. Jeong HK, Jin MH, So KP, et al. Tailoring the characteristics of graphite oxides by different oxidation times. J Phys D-Appl Phys, 2009, 42: 065418

    Google Scholar 

  15. Botas C, Álvarez P, Blanco C, et al. The effect of the parent graphite on the structure of graphene oxide. Carbon, 2012, 50: 275–282

    CAS  Google Scholar 

  16. Chen J, Li Y, Huang L, et al. High-yield preparation of graphene oxide from small graphite flakes via an improved Hummers method with a simple purification process. Carbon, 2015, 81: 826–834

    CAS  Google Scholar 

  17. Dong L, Yang J, Chhowalla M, et al. Synthesis and reduction of large sized graphene oxide sheets. Chem Soc Rev, 2017, 46: 7306–7316

    CAS  Google Scholar 

  18. Pan S, Aksay IA. Factors controlling the size of graphene oxide sheets produced via the graphite oxide route. ACS Nano, 2011, 5: 4073–4083

    CAS  Google Scholar 

  19. Marcano DC, Kosynkin DV, Berlin JM, et al. Improved synthesis of graphene oxide. ACS Nano, 2010, 4: 4806–4814

    CAS  Google Scholar 

  20. Dong L, Chen Z, Lin S, et al. Reactivity-controlled preparation of ultralarge graphene oxide by chemical expansion of graphite. Chem Mater, 2017, 29: 564–572

    CAS  Google Scholar 

  21. Peng L, Xu Z, Liu Z, et al. An iron-based green approach to 1-h production of single-layer graphene oxide. Nat Commun, 2015, 6: 5716

    CAS  Google Scholar 

  22. Yu H, Zhang B, Bulin C, et al. High-efficient synthesis of graphene oxide based on improved Hummers method. Sci Rep, 2016, 6: 36143

    CAS  Google Scholar 

  23. Sofer Z, Luxa J, Jankovský O, et al. Synthesis of graphene oxide by oxidation of graphite with ferrate(VI) compounds: Myth or reality? Angew Chem Int Ed, 2016, 55: 11965–11969

    CAS  Google Scholar 

  24. Ambrosi A, Pumera M. Electrochemically exfoliated graphene and graphene oxide for energy storage and electrochemistry applications. Chem Eur J, 2016, 22: 435

    Google Scholar 

  25. Cao J, He P, Mohammed MA, et al. Two-step electrochemical intercalation and oxidation of graphite for the mass production of graphene oxide. J Am Chem Soc, 2017, 139: 17446–17456

    CAS  Google Scholar 

  26. Pei S, Wei Q, Huang K, et al. Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation. Nat Commun, 2018, 9: 145

    Google Scholar 

  27. Lu L, Zeng C, Wang L, et al. Graphene oxide and H2 production from bioelectrochemical graphite oxidation. Sci Rep, 2015, 5: 16242

    CAS  Google Scholar 

  28. Zhu Y, Ji H, Cheng HM, et al. Mass production and industrial applications of graphene materials. Natl Sci Rev, 2018, 5: 90–101

    CAS  Google Scholar 

  29. Dou X, Koltonow AR, He X, et al. Self-dispersed crumpled graphene balls in oil for friction and wear reduction. Proc Natl Acad Sci USA, 2016, 113: 1528–1533

    CAS  Google Scholar 

  30. Renteria JD, Ramirez S, Malekpour H, et al. Strongly anisotropic thermal conductivity of free-standing reduced graphene oxide films annealed at high temperature. Adv Funct Mater, 2015, 25: 4664–4672

    CAS  Google Scholar 

  31. Song NJ, Chen CM, Lu C, et al. Thermally reduced graphene oxide films as flexible lateral heat spreaders. J Mater Chem A, 2014, 2: 16563–16568

    CAS  Google Scholar 

  32. Wang N, Samani MK, Li H, et al. Tailoring the thermal and mechanical properties of graphene film by structural engineering. Small, 2018, 14: 1801346

    Google Scholar 

  33. Han N, Viet Cuong T, Han M, et al. Improved heat dissipation in gallium nitride light-emitting diodes with embedded graphene oxide pattern. Nat Commun, 2013, 4: 1452

    Google Scholar 

  34. Han H, Zhang Y, Wang N, et al. Functionalization mediates heat transport in graphene nanoflakes. Nat Commun, 2016, 7: 11281

    CAS  Google Scholar 

  35. Zhang S, Cheng Y, Xu W, et al. Dispersibility of different sized graphene oxide sheets and their reinforcement on polyamide 6 fibers. RSC Adv, 2017, 7: 56682–56690

    CAS  Google Scholar 

  36. Scaffaro R, Maio A. A green method to prepare nanosilica modified graphene oxide to inhibit nanoparticles re-aggregation during melt processing. Chem Eng J, 2017, 308: 1034–1047

    CAS  Google Scholar 

  37. Scaffaro R, Maio A. Optimization of two-step techniques engineered for the preparation of polyamide 6 graphene oxide nanocomposites. Compos Part B-Eng, 2019, 165: 55–64

    CAS  Google Scholar 

  38. O’Neill A, Bakirtzis D, Dixon D. Polyamide 6/graphene composites: The effect of in situ polymerisation on the structure and properties of graphene oxide and reduced graphene oxide. Eur Polymer J, 2014, 59: 353–362

    Google Scholar 

  39. Dixon D, Lemonine P, Hamilton J, et al. Graphene oxide-polyamide 6 nanocomposites produced via in situ polymerization. J Thermoplastic Composite Mater, 2015, 28: 372–389

    CAS  Google Scholar 

  40. Ma M, Zhu Z, Wu B, et al. Preparation of highly conductive composites with segregated structure based on polyamide-6 and reduced graphene oxide. Mater Lett, 2017, 190: 71–74

    CAS  Google Scholar 

  41. Li Y, Yang Z, Qiu H, et al. Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings. J Mater Chem A, 2014, 2: 14139–14145

    CAS  Google Scholar 

  42. Ramezanzadeh B, Ghasemi E, Mahdavian M, et al. Covalentlygrafted graphene oxide nanosheets to improve barrier and corrosion protection properties of polyurethane coatings. Carbon, 2015, 93: 555–573

    CAS  Google Scholar 

  43. Ramezanzadeh B, Niroumandrad S, Ahmadi A, et al. Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide. Corrosion Sci, 2016, 103: 283–304

    CAS  Google Scholar 

  44. Münzing B. Greener corrosion protection. Physics World, 2019, 32: 23–25

    Google Scholar 

  45. Wu ZS, Zhou G, Yin LC, et al. Graphene/metal oxide composite electrode materials for energy storage. Nano Energy, 2012, 1: 107–131

    CAS  Google Scholar 

  46. Yang Z, Tian J, Yin Z, et al. Carbon nanotube- and graphene-based nanomaterials and applications in high-voltage supercapacitor: A review. Carbon, 2019, 141: 467–480

    CAS  Google Scholar 

  47. Li F, Jiang X, Zhao J, et al. Graphene oxide: A promising nanomaterial for energy and environmental applications. Nano Energy, 2015, 16: 488–515

    CAS  Google Scholar 

  48. Raccichini R, Varzi A, Passerini S, et al. The role of graphene for electrochemical energy storage. Nat Mater, 2014, 14: 271–279

    Google Scholar 

  49. Georgakilas V, Tiwari JN, Kemp KC, et al. Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications. Chem Rev, 2016, 116: 5464–5519

    CAS  Google Scholar 

  50. Zhu Y, Murali S, Stoller MD, et al. Carbon-based supercapacitors produced by activation of graphene. Science, 2011, 332: 1537–1541

    CAS  Google Scholar 

  51. Lin D, Liu Y, Liang Z, et al. Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes. Nat Nanotech, 2016, 11: 626–632

    CAS  Google Scholar 

  52. Jung HG, Jeong YS, Park JB, et al. Ruthenium-based electro-catalysts supported on reduced graphene oxide for lithium-air batteries. ACS Nano, 2013, 7: 3532–3539

    CAS  Google Scholar 

  53. Down MP, Rowley-Neale SJ, Smith GC, et al. Fabrication of graphene oxide supercapacitor devices. ACS Appl Energy Mater, 2018, 1: 707–714

    CAS  Google Scholar 

  54. Farooqui UR, Ahmad AL, Hamid NA. Graphene oxide: A promising membrane material for fuel cells. Renew Sustain Energy Rev, 2018, 82: 714–733

    CAS  Google Scholar 

  55. Xu C, Cao Y, Kumar R, et al. A polybenzimidazole/sulfonated graphite oxide composite membrane for high temperature polymer electrolyte membrane fuel cells. J Mater Chem, 2011, 21: 11359–11364

    CAS  Google Scholar 

  56. Heo Y, Im H, Kim J. The effect of sulfonated graphene oxide on sulfonated poly (ether ether ketone) membrane for direct methanol fuel cells. J Membrane Sci, 2013, 425–426: 11–22

    Google Scholar 

  57. Khilari S, Pandit S, Ghangrekar MM, et al. Graphene oxide-impregnated PVA-STA composite polymer electrolyte membrane separator for power generation in a single-chambered microbial fuel cell. Ind Eng Chem Res, 2013, 52: 11597–11606

    CAS  Google Scholar 

  58. Ye YS, Cheng MY, Xie XL, et al. Alkali doped polyvinyl alcohol/ graphene electrolyte for direct methanol alkaline fuel cells. J Power Sources, 2013, 239: 424–432

    CAS  Google Scholar 

  59. Zhao F, Cheng H, Zhang Z, et al. Direct power generation from a graphene oxide film under moisture. Adv Mater, 2015, 27: 4351–4357

    CAS  Google Scholar 

  60. Zhao F, Wang L, Zhao Y, et al. Graphene oxide nanoribbon assembly toward moisture-powered information storage. Adv Mater, 2017, 29: 1604972

    Google Scholar 

  61. Cheng H, Huang Y, Zhao F, et al. Spontaneous power source in ambient air of a well-directionally reduced graphene oxide bulk. Energy Environ Sci, 2018, 11: 2839–2845

    CAS  Google Scholar 

  62. Joshi RK, Carbone P, Wang FC, et al. Precise and ultrafast molecular sieving through graphene oxide membranes. Science, 2014, 343: 752–754

    CAS  Google Scholar 

  63. Chen L, Shi G, Shen J, et al. Ion sieving in graphene oxide membranes via cationic control of interlayer spacing. Nature, 2017, 550: 380–383

    CAS  Google Scholar 

  64. Cohen-Tanugi D, Grossman JC. Water desalination across nanoporous graphene. Nano Lett, 2012, 12: 3602–3608

    CAS  Google Scholar 

  65. Nair RR, Wu HA, Jayaram PN, et al. Unimpeded permeation of water through helium-leak-tight graphene-based membranes. Science, 2012, 335: 442–444

    CAS  Google Scholar 

  66. Li X, Xu W, Tang M, et al. Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path. Proc Natl Acad Sci USA, 2016, 113: 13953–13958

    CAS  Google Scholar 

  67. Pu S, Xue S, Yang Z, et al. In situ co-precipitation preparation of a superparamagnetic graphene oxide/Fe3O4 nanocomposite as an adsorbent for wastewater purification: Synthesis, characterization, kinetics, and isotherm studies. Environ Sci Pollut Res, 2018, 25: 17310–17320

    CAS  Google Scholar 

  68. Banerjee P, Sau S, Das P, et al. Optimization and modelling of synthetic azo dye wastewater treatment using graphene oxide nanoplatelets: Characterization toxicity evaluation and optimization using Artificial Neural Network. Ecotoxicol Environ Saf, 2015, 119: 47–57

    CAS  Google Scholar 

  69. Song S, Ma Y, Shen H, et al. Removal and recycling of ppm levels of methylene blue from an aqueous solution with graphene oxide. RSC Adv, 2015, 5: 27922–27932

    CAS  Google Scholar 

  70. Banerjee P, Das P, Zaman A, et al. Application of graphene oxide nanoplatelets for adsorption of ibuprofen from aqueous solutions: Evaluation of process kinetics and thermodynamics. Process Saf Environ Protection, 2016, 101: 45–53

    CAS  Google Scholar 

  71. Upadhyay RK, Soin N, Roy SS. Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: A review. RSC Adv, 2014, 4: 3823–3851

    CAS  Google Scholar 

  72. Zou X, Zhang L, Wang Z, et al. Mechanisms of the antimicrobial activities of graphene materials. J Am Chem Soc, 2016, 138: 2064–2077

    CAS  Google Scholar 

  73. Konwar A, Kandimalla R, Kalita S, et al. Approach to fabricate a compact cotton patch without weaving: A smart bandage material. ACS Sustain Chem Eng, 2018, 6: 5806–5817

    CAS  Google Scholar 

  74. He J, Zhu X, Qi Z, et al. Killing dental pathogens using antibacterial graphene oxide. ACS Appl Mater Interfaces, 2015, 7: 5605–5611

    CAS  Google Scholar 

  75. Li S, Lee JK, Zhou S, et al. Synthesis of surface grown Pt nanoparticles on edge-enriched MoS2 porous thin films for enhancing electrochemical performance. Chem Mater, 2019, 31: 387–397

    CAS  Google Scholar 

  76. Berman D, Erdemir A, Sumant AV. Graphene: A new emerging lubricant. Mater Today, 2014, 17: 31–42

    CAS  Google Scholar 

  77. Liang H, Bu Y, Zhang J, et al. Graphene oxide film as solid lubricant. ACS Appl Mater Interfaces, 2013, 5: 6369–6375

    CAS  Google Scholar 

  78. Gupta B, Kumar N, Panda K, et al. Energy efficient reduced graphene oxide additives: Mechanism of effective lubrication and antiwear properties. Sci Rep, 2016, 6: 18372

    CAS  Google Scholar 

  79. Gupta B, Kumar N, Panda K, et al. Role of oxygen functional groups in reduced graphene oxide for lubrication. Sci Rep, 2017, 7: 45030

    CAS  Google Scholar 

  80. Kauling AP, Seefeldt AT, Pisoni DP, et al. The worldwide graphene flake production. Adv Mater, 2018, 30: 1803784

    Google Scholar 

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Acknowledgements

The authors acknowledge Yanlin Zhang for her assistance. This work was supported by the National Natural Science Foundation of China (51772282).

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Correspondence to Yanwu Zhu  (朱彦武).

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Yufei Ma received his BSc and PhD degrees at Lanzhou University in 2006 and 2012, respectively, and he was a visiting graduate student at the University of California, Berkeley during 2010–2012. He worked as a postdoctoral researcher at Suzhou Institute of NanoTech and NanoBionics, Chinese Academy of Sciences, and then joined The Sixth Element (Changzhou) Materials Technology Co., Ltd. in 2015. His research focuses on the industrial production of graphene (oxide) materials and their related applications.

Yanwu Zhu is currently a professor at the Department of Materials Science and Engineering, University of Science and Technology of China. He received his MSc (2003) from Peking University and PhD (2007) from the National University of Singapore (NUS), both in physics. He was a postdoctoral researcher at the NUS and the University of Texas at Austin. His research focuses on the preparation, characterization and property research of graphene and other novel carbon materials.

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Ma, Y., Zheng, Y. & Zhu, Y. Towards industrialization of graphene oxide. Sci. China Mater. 63, 1861–1869 (2020). https://doi.org/10.1007/s40843-019-9462-9

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