Abstract
This work represents the results from the experimental investigation conducted on the utilization of ferrochrome slag (FCS) as a replacement of Portland cement (PC) in cement composites. A total of seven mix compositions were made and the corresponding performance of the mix were evaluated in terms of its strength, durability and microstructural properties. Results from this study showed that the incorporation of FCS as partial replacement of the PC resulted in an increase in the set times and a decrease in the water content for normal consistency. The compressive strength of the mortar mixes was decreased with incorporation of FCS into the mortar mixtures. However, mortar mixtures up to 30% of PC replacement with FCS exhibited compressive strength higher than 30 MPa. In terms of durability, 30% FCS replacement resulted in 18% reduction in water absorption along with lower loss in the compressive strength and improved resistance to acid attack. Microstructural investigation showed that the use of FCS as a replacement to PC resulted in an increment in the formation of calcium silicate hydrate which results in a compact and densified microstructure of the mortars. Further, to ensure the environmental soundness of FCS mortars, a leaching test was conducted for the first 14 days of curing, and it was found that the Cr leaching values are under the permissible limits and can be used in general construction applications.
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Andrew RM (2018) Global CO2 emissions from cement production. Earth Syst Sci Data. https://doi.org/10.5194/essd-10-195-2018
Purnell P (2013) The carbon footprint of reinforced concrete. Adv Cem Res. https://doi.org/10.1680/adcr.13.00013
Das SK, Mishra J, Mustakim SM, et al (2022) Sustainable utilization of ultrafine rice husk ash in alkali activated concrete: characterization and performance evaluation. J Sustain Cem Based Mater 11(2):100–112. https://doi.org/10.1080/21650373.2021.1894265
Das SK, Mishra S, Das D et al (2021) Characterization and utilization of coal ash for synthesis of building materials. In: Jyothi RK, Parhi PK (eds) Clean coal technologies. Springer International Publishing, Cham, pp 487–509
Mishra J, Das SK, Krishna RS, Nanda B (2020) Utilization of ferrochrome ash as a source material for production of geopolymer concrete for a cleaner sustainable environment. Indian Concr J 94:40–49
Mustakim SM, Das SK, Sahu T, Adesina A (2022) Development of greener lightweight aggregates from industrial waste products for use in construction composites. Innov Infrastruct Solut 8:25. https://doi.org/10.1007/s41062-022-00997-4
Flower DJM, Sanjayan JG (2007) Green house gas emissions due to concrete manufacture. Int J Life Cycle Assess. https://doi.org/10.1007/s11367-007-0327-3
Das SK, Dan AK, Behera U et al (2021) A novel approach on leaching study for removal of toxic elements from thermal power plant-based fly ash using natural bio-surfactant. Case Stud Chem Environ Eng 4:100156. https://doi.org/10.1016/J.CSCEE.2021.100156
Behera U, Das SK, Mishra DP et al (2021) Sustainable transportation, leaching, stabilization, and disposal of fly ash using a mixture of natural surfactant and sodium silicate. ACS Omega. https://doi.org/10.1021/acsomega.1c03241
Adesina A, Awoyera P (2019) Overview of trends in the application of waste materials in self-compacting concrete production. SN Appl Sci. https://doi.org/10.1007/s42452-019-1012-4
Shayan A, Xu A (2004) Value-added utilisation of waste glass in concrete. Cem Concr Res. https://doi.org/10.1016/S0008-8846(03)00251-5
Shariq M, Prasad J, Masood A (2010) Effect of GGBFS on time dependent compressive strength of concrete. Constr Build Mater. https://doi.org/10.1016/j.conbuildmat.2010.01.007
Das SK, Mishra J, Singh SK et al (2020) Characterization and utilization of rice husk ash (RHA) in fly ash—blast furnace slag based geopolymer concrete for sustainable future. Mater Today Proc. https://doi.org/10.1016/j.matpr.2020.02.870
Das SK, Mishra J, Mustakim SM (2018) Rice husk ash as a potential source material for geopolymer concrete: a review. Int J Appl Eng Res 13:81–84
Das SK, Singh SK, Mishra J, Mustakim SM (2020) Effect of rice husk ash and silica fume as strength-enhancing materials on properties of modern concrete—a comprehensive review. In: Lecture notes in civil engineering. pp 253–266
Alomayri T, Adesina A, Das S (2021) Influence of amorphous raw rice husk ash as precursor and curing condition on the performance of alkali activated concrete. Case Stud Constr Mater 15:e00777. https://doi.org/10.1016/J.CSCM.2021.E00777
Ikponmwosa EE, Ehikhuenmen S, Emeshie J, Adesina A (2020) Performance of coconut shell alkali-activated concrete: experimental investigation and statistical modelling. Silicon. https://doi.org/10.1007/s12633-020-00435-z
Ikponmwosa EE, Falade FA, Fashanu T et al (2020) Experimental and numerical investigation of the effect of sawdust ash on the performance of concrete. J Build Pathol Rehabil 5:15. https://doi.org/10.1007/s41024-020-00081-3
Sivakrishna A, Adesina A, Awoyera PO, Rajesh Kumar K (2019) Green concrete: a review of recent developments. Mater Today Proc. https://doi.org/10.1016/j.matpr.2019.08.202
Thomas M (2011) The effect of supplementary cementing materials on alkali-silica reaction: a review. Cem Concr Res 41(12):1224–1231. https://doi.org/10.1016/j.cemconres.2010.11.003
Kumar Das S, Adediran A, Rodrigue Kaze C et al (2022) Production, characteristics, and utilization of rice husk ash in alkali activated materials: an overview of fresh and hardened state properties. Constr Build Mater 345:128341. https://doi.org/10.1016/J.CONBUILDMAT.2022.128341
Mishra J, Nanda B, Patro SK et al (2022) Strength and microstructural characterization of ferrochrome ash- and ground granulated blast furnace slag-based geopolymer concrete. J Sustain Metall 8:156–169. https://doi.org/10.1007/s40831-021-00469-6
Kaze CR, Tome S, Lecomte-Nana GL et al (2021) Development of alkali-activated composites from calcined iron-rich laterite soil. Materialia (Oxford) 15:101032. https://doi.org/10.1016/j.mtla.2021.101032
Das SK, Mustakim SM, Adesina A et al (2021) Solid wastes: alternative materials for cementitious composites production. In: Hussain CM, Velasco-Muñoz JF (eds) Sustainable resource management. Elsevier, Amsterdam, pp 199–220
Niemelä P, Kauppi M (2007) Production, characteristics and use of ferrochromium slags. In: Innovations in the ferro alloy industry—proceedings of the XI international conference on innovations in the ferro alloy industry, Infacon XI
Das SK, Tripathi AK, Kandi SK et al (2023) Ferrochrome slag: a critical review of its properties, environmental issues and sustainable utilization. J Environ Manag 326:116674. https://doi.org/10.1016/J.JENVMAN.2022.116674
Adesanya E, Karhu M, Ismailov A et al (2020) Thermal behaviour of ladle slag mortars containing ferrochrome slag aggregates. Adv Cem Res. https://doi.org/10.1680/jadcr.19.00040
Acharya PK, Patro SK (2016) Utilization of ferrochrome wastes such as ferrochrome ash and ferrochrome slag in concrete manufacturing. Waste Manag Res. https://doi.org/10.1177/0734242X16654751
Al-Jabri KS (2018) Research on the use of Ferro-Chrome slag in civil engineering applications. In: MATEC web of conferences. p 1017
Al-Jabri K, Shoukry H, Khalil IS et al (2018) Reuse of waste ferrochrome slag in the production of mortar with improved thermal and mechanical performance. J Mater Civ Eng 30:04018152. https://doi.org/10.1061/(asce)mt.1943-5533.0002345
IS: 4031 (Part 6) (2005) Methods of physical tests for hydraulic cement part 6 determination of compressive strength of hydraulic cement other than masonry cement (first revision)
IS 4031—Part V (1988) Methods of physical tests for hydraulic cement. Part V—determination of initial and final setting times. India
IS 4031—Part IV (1988) Methods of physical tests for hydraulic cement. Part IV—determination of consistency of standard cement paste
ASTM C 642-2006 (2006) Standard test method for density, absorption, and voids in hardened concrete. ASTM International, West Conshohocken, pp 1–3. https://doi.org/10.1520/C0642-13.5
Sunayana S, Barai SV (2021) Partially fly ash incorporated recycled coarse aggregate based concrete: microstructure perspectives and critical analysis. Constr Build Mater 278:122322. https://doi.org/10.1016/j.conbuildmat.2021.122322
Wild S, Khatib JM (1997) Portlandite consumption in metakaolin cement pastes and mortars. Cem Concr Res. https://doi.org/10.1016/S0008-8846(96)00187-1
Deschner F, Winnefeld F, Lothenbach B et al (2012) Hydration of Portland cement with high replacement by siliceous fly ash. Cem Concr Res. https://doi.org/10.1016/j.cemconres.2012.06.009
Vance K, Aguayo M, Oey T et al (2013) Hydration and strength development in ternary Portland cement blends containing limestone and fly ash or metakaolin. Cem Concr Compos. https://doi.org/10.1016/j.cemconcomp.2013.03.028
Rahman MA, Sarker PK, Shaikh FUA, Saha AK (2017) Soundness and compressive strength of Portland cement blended with ground granulated ferronickel slag. Constr Build Mater. https://doi.org/10.1016/j.conbuildmat.2017.02.023
IS 456 (2000) Plain and reinforced concrete—code of practice
Pacheco-Torgal F, Ding Y, Miraldo S, et al (2012) Are geopolymers more suitable than Portland cement to produce high volume recycled aggregates HPC? Constr Build Mater 36:1048–1052. https://doi.org/10.1016/j.conbuildmat.2012.07.004
Wang W, Noguchi T (2020) Alkali-silica reaction (ASR) in the alkali-activated cement (AAC) system: a state-of-the-art review. Constr Build Mater 252:119105. https://doi.org/10.1016/j.conbuildmat.2020.119105
Jaritngam S, Prachasaree W, Somchainuek O, Taneerananon P (2012) An investigation of lateritic soil cement for sustainable pavements. Indian J Sci Technol: Trans of Civil Eng 38:275–284
Phummiphan I, Horpibulsuk S, Sukmak P et al (2016) Stabilisation of marginal lateritic soil using high calcium fly ash-based geopolymer. Road Mater Pavement Des. https://doi.org/10.1080/14680629.2015.1132632
Hosan A, Shaikh FUA (2020) Influence of nano-CaCO3 addition on the compressive strength and microstructure of high volume slag and high volume slag-fly ash blended pastes. J Build Eng. https://doi.org/10.1016/j.jobe.2019.100929
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The authors are thankful the CSIR-Institute of Minerals and Materials Technology, Bhubaneswar, India for giving permission to publish this research.
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Das, S.K., Rajput, P., Mustakim, S.M. et al. Towards Sustainable Construction: Utilization of Ferrochrome Slag as Portland Cement Replacement in Cementitious Composites. J. Sustain. Metall. 9, 329–340 (2023). https://doi.org/10.1007/s40831-023-00653-w
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DOI: https://doi.org/10.1007/s40831-023-00653-w