Abstract
Radionuclides activity concentrations in soil around ten solid mineral mining sites have been investigated using sodium iodide [Na(TI)] gamma spectroscopy. Four soil samples and a control sample were collected from each of the selected sites for analyses. The obtained results showed mean concentration values of 33.2 Bq kg−1 for 226Ra, 100.7 Bq kg−1 for 40K and 77.7 Bq kg−1 for 232Th. The estimated radiological risk parameter results have shown average values of 67.5 ηGy h−1 for the Absorbed Dose Rate (DR), 82.8 μSv y−1 for the Annual Effective Dose Equivalent (AEDE), 151.4 Bq kg−1 for the Radium Equivalent (Raeq) and 457.1 mSv y−1 for the Annual Gonadal Equivalent Dose (AGED) which is highly comparable to the allowable WHO value of 300 mSv y−1 and the control value of 177.7 mSv y−1. The average Excess Life Cancer Risk (ELCR) value obtained was 289.6 × 10−6 and the control value 112.9 × 10−6. The average External Hazard Index (Hex), Internal Hazard Index (Hin), Representative Gamma index ( Iγ), and Activity Utilization Index (AUI) obtained were 0.4, 0.5, 1.1 and 1.3, respectively. The Radiogenic Heat produced Q ranged from 248.4 pW kg−1 in Awkuke (ironstone mine) to 608.5 pW kg−1 in Ama-Echi (Silica mine) with an average heat value of 415.8 pW kg−1. The obtained result for lithology [clay] identification showed a mixed clay lithology type. The overall results were found to be higher when compared to previously reported values from similar mineral mining areas, which indicates radiological contamination.
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References
Abbady A, Al-Amoudi Z (2013) Comparative study of radioactive content in soil from different countries. Life Science Journal 10(1):3016–3020
Ademola JA (2008) Determination of natural radionuclides content in some building materials in Nigeria by gamma-ray spectrometry. Health Phys 94(1):43–48
Ademola AK, Obed RI (2012) Gamma radioactivity levels and their corresponding external exposure of soil samples from tantalite mining areas in Oke-Ogun, South-Western Nigeria. Radioprotection Journal 47:243–252
Ademola AK, Adekunle KB, Adeyeni CA (2014) Determination of natural radioactivity and hazard in soil samples in and around gold mining area in Itagunmodi, south-western, Nigeria. Journal of Radiation Research and Applied Sciences 7:249-255
Ademola JA, Onyema UC (2014) Assessment of natural radionuclides in fly ash produced at Orji River thermal Power Station, Nigeria and the associated radiological impact. Nat Sci 6:752–759
Aigbedion I, Iyayi SE (2007) Radiation studies. International Journal of Physical Sciences 2: 33-38
Agbalagba EO, Avwiri GO, Chad-Umoreh YE (2012) γ-spectroscopy measurement of natural radioactivity and assessment of radiation hazard indices in soil samples from oil fields environment of Delta State, Nigeria. J Environ Radioact 109:64–70
Agbalagba EO, Onoja RA (2011) Evaluation of natural radioactivity in soil, sediment and water samples of Niger delta (Biseni) flood plain lakes, Nigeria. J Environ Rad 102:667-671
Al-Mugren KS (2015) Assessment of natural radioactivity levels and radiation dose rate in some soil samples from historical area, Al-Rakkah, Saudi Arabia. Nat Sci 7:238–247
Al-Hamarnel FI, Awadallah MI (2009) Soil radioactivity levels and radiation hazard assessment in the highlands of northern Jordan. Radiat Meas 44:102–110
Aliyu AS, Ibrahim U, Akpa CT, Garba NN, Ramli AT (2015) Health and ecological hazards due to natural radioactivity in soil from mining areas of Nasarawa State, Nigeria. Isotopes Environ Health Study 51(3):448-468
Amrani D, Tahtat M (2001) Natural radioactivity in Algeria building materials. Jounal of Applied Radiation and Isotopes, 54:687-689
Anagnostakis MJ, Hinis EP, Simopoulos SE, Angelopoulos MG (1996) Natural radioactivity mapping of Greek surface soil. Environ Int 22:3–8
Ashraf EMK, Layia HA, Amany AA, Al-Omran AM (2010) NORM in clay deposits. Proceedings of Third European IRPA Congress 2010 June 14- 18, Helsinki, Finland, pp. 1–9
Avwiri GO, Enyinna PI, Agbalagba EO (2010) Occupational radiation levels in solid mineral producing areas of Abia State, Nigeria. Scientia Africana 9(1):93–97
Avwiri GO, Osimobi JC, Agbalagba EO (2012) Evaluation of radiation hazard indices and excess lifetime cancer risk due to natural radioactivity in soil profile of Udi and Ezeagu local government areas of Enugu state, Nigeria. Comprehensive Journal of Environmental and Earth Sciences 1(1):1–10
Balogun FA, Mokobia CE, Fasasi MK, Ogundare FO (2003) Natural radioactivity associated with bituminous coal mining in Nigeria. Nucl Inst Methods Phys Res A 505:444–448
Baratta EJ (1990) Radon, radium and uranium in drinking water. Lewis Publisher, Washington DC, pp 203–213
Beretka J, Mathew PJ (1985) Natural radioactivity of Australian building materials in industrial wastes and by products. Health Phys 48:87–95
Du J, Wu Y, Huang D, Zhang J (2010) Use of 7Be, 210Pb and 137Cs tracer to the transport of surface sediments of the Changjiang estuary, China. J Mar Syst 82(4):286–294
El Afifi EM, Hilal MA, Khalifa SM, Aly HF (2006) Evaluation of U, Th, K and emanated radon in some NORM and TENORM samples. Radiat Meas 41:627–633
El-Bahi SM (2004) Assessment of radioactivity and radon exhalation rate in Egyptian cement. Health Phys 86:517–522
El-Dine NW, EL-Shershaby A, Ahmed F, Abdel-Haleem A (2001) Measurement of radioactivity and radon exhalation rate in different kinds of marble and granites. Appl Radiat Isot 55(6):853–860
El-Gamal A, Nasr S, El-Taher A (2007) Study of the spatial distribution of natural radioactivity in Upper Egypt Nile river sediments. Radiat Meas 42:457–465
El-Taher A, Madkour HA (2014) Environmental and radio-ecological studies on shallow marine sediments from harbour areas along the Red Sea coast of Egypt for identification of anthropogenic impacts. Isot Environ Health Stud 50:120–133
Enugu State Ministry of Environment and Mineral Development (2010) Enugu state investment potentials in solid minerals. Government Bulletin, 23
Ezeh CC (2011) Geoelectrical studies for estimating aquifer hydraulic properties in Enugu state, Nigeria. International Journal of the Physical Sciences 6(14):3319–3329
Ezeh CC, Ugwu GZ (2010) Geoelectrical sounding for estimating groundwater potential in Nsukka L.G.A. Enugu State, Nigeria. International Journal of the Physical Sciences 5(5):415–420
Faanu A, Darko EO, Ephraim JH (2011) Determination of natural radioactivity and hazard in soil and rock samples in a mining area in Ghana. W Afr J Appl Ecol 19:77–92
Gang S, Diyun C, Zeping T, Zhiquang Z, Wenbiao X (2012) Natural radioactivity levels in topsoil from the Pearl River Delta zone, Guangdong, China. J Environ Radioact 103:48–53
Gonzalez-Fernandez D, Garrido-Perez MC, Cases-Ruiz M, Barbero L, Nebot-Sanz E (2012) Radiological risk assess of naturally occurring radioactivity materials in marine sediments and its application in industrial coastal areas. Bay of Algeciras. Environ Earth Sci 66:1175–1181
Hannan M, Wahid K, Nguyen N (2015) Assessment of natural and artificial radionuclides in Mission (Texas) surface soils. J Radioanal Nucl Chem 305(2):573–582
Harb S, El-Kamel AH, Zahran AM, Abbady A, Ahmed FA (2014) Assessment of natural radioactivity in soil and water samples from Aden Governorate South of Yemen region. IJRRPCS 1(1):1–7
Harb S, Ahmed N, Badawy W, Saad N (2016) Estimation of radioecological parameters of soil samples from Phosphatic area. Nuclear Technology and Radiation Protection 31(2):165–172
Imperial College London (ICL) (2014) Wire-line Petrophysics lecture notes. An MSc Petroleum Geophysics Course
Innocent JA, Onimisi MY, Jonah SA (2013) Evaluation of naturally occurring radionuclide materials in soil samples collected from some mining sites in Zamfara state, Nigeria. British Journal of Applied Science & Technology 3(4):684–692
International Commission on Radiological Protection (ICRP) (1999) The 1995–99 recommendation of the international Commission on Radiological Protection Publication 76. Pergamon Press
Joshua EO, Ehinola AO, Akpanowo MA, Onyebanjo OA (2008) Radiogenic heat production in crustal rock samples of southeastern Nigeria. Eur J Sci Res 23(2):305–316
Kam E, Bozkurt A (2007) Environmental radioactivity measurements in Kastamonu region of northern Turkey. Appl Radiat Isot 65(4):440–444. https://doi.org/10.1016/j.apradiso.2006.11.005
Kessaratikoon P, Boonkrongcheep R, Benjakul S, Youngchauy U (2013) Specific activities and radioactive contour maps of natural and anthropogenic radionuclides in beach sand samples (Patong, Kamala, Kata, Karon and Nai Yang) after tsunami disaster in Phuket province, Thailand. J Radioanal Nucl Chem 297:247–255
Kovacs T, Szeiler G, Fabian F, Kardos R, Gregoric A, Vaupotic J (2013) Systematic survey of natural radioactivity of soil in Slovenia. J Environ Radioact 122:70–78
Mohammad MK, Khali MT, Khrais FW (2014) Measurement of activity concentration levels of radionuclides in soil samples collected from Bethlehem Province, West Bank, Palestine. Turk J Eng Environ Sci 38:113–125
Mokobia CE, Adebiyi FM, Akpan I, Olise FS, Tchokossa P (2006) Radioassay of prominent Nigerian fossil fuels using gamma and TXRF spectroscopy. Fuel 85:1811–1814
Muhammad BG, Jaafer MS, Rahman AA, Ingawa FA (2012) Determination of radioactive elements and heavy metals in sediments and soil from domestic water sources in northern peninsular Malaysia. Environ Monit Assess 184(8):5043–5049
Nisha M, Sushil K, Amit K, Chauhan RP, Garg AK (2014) Measurement of radon exhalation rates in soil samples from Western Haryana. J Appl Phys 5(2):56–59
Ononugbo CP, Avwiri GO, Agbalagba EO (2017) Radioactivity pollution and excess lifetime cancer risk due to gamma exposure of soil and ground water around open landfills in Rivers state, Nigeria. Canadian Journal of Pure and Applied Sciences 11(1):4121–4130
Orgun Y, Altinsoy N, Sahin SY, Gungor Y, Gultekin AH, Karaham G, Karaak Z (2007) Natural and anthropogenic radionuclide in rocks and beach sands from Ezine region, Western Anatolia, Turkey. Appl Radiat Isot 65:739–747
PetroWiki (2015) Grain Densities of some common rock forming minerals. http://petrowiki.org/File%3AVol1_Page_583_Image_0001.png. Published by Society of petroleum Engineers
Sadiq AA, Agba EH (2011) Background radiation in Akwanga, Nigeria. Facta Universitatis; Series: Working and Living Environmental Protection 8(1):7–11
Sam AK, Abbas N (2001) Assessment of radioactivity and the associated hazards in local and imported cement types used in Sudan. Radiat Prot Dosim 93:275–277
Sivakumar S, Chandrasekaranb A, Ravisankarc R, Ravikumarc S, Prince MJ, Prakash J, Vijayagopale P, Vijayalakshmie I, Jose MT (2014) Measurement of natural radioactivity and evaluation of radiation hazards in coastal sediments of east coast of Tamilnadu using statistical approach. Journal of Taibah University for Science 8:375–384
Sun Z, Wang A, Liu J, Baoqun H, Hu B, Chen G (2015) Radiogenic heat production of granites and potential for hot dry rock geothermal resource in Guangdong Province, southern China. Proceedings World Geothermal Congress 2015 Melbourne, Australia, 19–25
Taskin H, Karavus M, Ay P, Topuzoghi A, Hindiroglu S, Karaha G (2009) Radionuclide concentrations in soil and lifetime cancer risk due to the gamma radioactivity in Kirklareli, Turkey. J Environ Radioact 100:49–53
Tufail M, Akhtar N, Jaried S, Hamid T (2007) Natural radioactivity hazards of building bricks fabrication from soil of two districts of Pakistan. J Radiol Prot 27:481–492
Turhan S, Gunduz L (2008) Determination of specific activity of 226Ra, 232Th and 40K for assessment of radiation hazards from Turkish pumice samples. J Environ Radioact 101:54–62. https://doi.org/10.1016/j.jenvrad.2007.08.002
UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (1988) Sources, effects and risks of ionizing radiation, Annex B, United Nations, New York
UNSCEAR United Nation Scientific Committee on the Effects of Atomic Radiation) (2000) Sources and effect of Ionizing radiation. Report to the general assembly with scientific annexes. United Nations; New York
UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (2008) Report vol.1 to the general assembly with scientific annexes: United Nations Sales Publications. United Nations, New York
Vukasinovic I, Todorovic D, Zivotic LJ, Kaluderovic L, Ðordevic A (2017) An analysis of naturally occurring radionuclides and 137Cs in the soils of urban areas using gamma-ray spectrometry. Int J Environ Sci Technol 15:1049–1060. https://doi.org/10.1007/s13762-017-1467-z
Wang Z, He J, Du Y, Li Z, Chen Z, Yang C (2011) Natural and artificial radionuclide measurements and radioactivity assessment of soil samples in eastern Sichuan province (China). Radiat Prot Dosim 150(4):391–397
Wang Z, Du Y, Baskaran M, Zhang J (2016) Mobile mud dynamics in the East China Sea elucidated using 210Pb, 137Cs, 7Be and 234Th as tracers. J Geophys Res Oceans 121(1):224–239
Wang J, Du J, Bi Q (2017) Natural radioactivity assessment of surface sediments in the Yangtze estuary. Mar Pollut Bull 114:602–608
Yang SL, Ding PX, Chen SL (2001) Changes in progradation rate of the tidal flats at the mouth of the Changjiang (Yangtze) River, China. Geomophology 38(1):167–180
Zarie KA, Al Mugren KS (2010) Measurement of natural radioactivity and assessment of radiation hazard in soil samples from Tayma area (KSA). Isotope and Rad Res 42(1):1–9
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The authors wish to thank the Enugu State Ministry of Environment for granting us the permission and access to the studied mining sites.
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Osimobi, J.C., Avwiri, G.O. & Agbalagba, E.O. Radiometric and Radiogenic Heat Evaluation of Natural Radioactivity in Soil Around Solid Minerals Mining Environment in South-Eastern Nigeria. Environ. Process. 5, 859–877 (2018). https://doi.org/10.1007/s40710-018-0336-1
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DOI: https://doi.org/10.1007/s40710-018-0336-1