Abstract
Activated carbons were prepared from rice husk carbonized in the fluidized catalysts bed reactor. Using the different activating agents, samples with BET surface area in the range from 540 to 3060 m2/g were achieved. Using sodium or potassium carbonates results in the BET surface area up to 1400 m2/g. Hydroxides of sodium or potassium yield the samples with the higher BET surface area (up to 3060 m2/g). Textural peculiarities of the carbons were studied by the adsorption of nitrogen at 77 K and of carbon dioxide at 273 K. As active materials for supercapacitors, the porous carbon samples were examined by cyclic voltammetry and chronopotentiometry in galvanostatic mode in 1 M H2SO4 as the electrolyte using home-made three-electrode electrochemical glass cell. Gravimetric capacitance of the carbons is linearly proportional to the BET surface area and reaches 230 and 196 F/g at discharge current density of 0.2 and 1 A/g, respectively, for the samples with the highest surface area.
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Introduction
Among various devices for electric energy storage, supercapacitors take an intermediate position between batteries and conventional capacitors. They possess unique energetic characteristics, showing higher power density than batteries and higher energy density than capacitors. In addition, supercapacitors demonstrate long life cycle, good reversibility and low maintenance cost [1–3]. All these benefits draw a lot of attention to research and development of the new active materials suitable for the supercapacitor construction.
The specific character of energy storage requires tailored textural characteristics of the practical materials used in supercapacitors: extended surface area and open porous structure, accessible for ions of the electrolyte. Carbons presented in variety forms and modifications help prospectively to improve existing supercapacitors thanks to physico-chemical properties: sufficient conductivity, good corrosion resistance, temperature stability, relatively low cost and possibility to vary textural properties [4]. Micro- [5–8] and mesoporous [9–12] carbon materials have been widely investigated as active electrode materials for the supercapacitors.
Now, economic reasons and environmental challenges make biomass attract significant attention as a source for production of the carbon materials. Woods, leaves, beer lees, rice husk and other biomass precursors have been reported as a raw material for such production [5, 9, 13–20].
Rice husk (RH) is a large-scale agricultural waste without any relevant commercial applications. High amount of amorphous silica makes rice husk conversion difficult. However, on the other hand, the presence of silica allows to consider RH as template-containing precursor for the preparation of porous carbons with textural characteristics depending on the template phase properties. In our previous publications [21–23], two methods of preparation of porous carbons, from RH carbonized in the fluidized catalyst bed reactor, have been described—with the use of alkalis and carbonates of Na and K.
When using carbonates of Na or K in powdered state, the developed method is close to be an analog of the template synthesis technique, but in this case no additional template material is needed, since it is already contained in RH. Here, porosity in the prepared porous carbons is being developed by the following scheme (Fig. 1):
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Formation of water-soluble silicates by high-temperature treatment;
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Washing out the C/silicate composites.
In the case of alkalis, SiO2 phase certainly contributes to the development of porosity, but there is also a significant reconstruction of carbon phase because of its interaction with alkalis. That is why a detection of the contribution of SiO2 phase in the porosity development is complicated enough.
Thereby, in the present study, series of the carbon materials has been prepared from the rice husk carbonized in the fluidized catalyst bed reactor—by Na and K carbonates and alkalis activation. Variation of activation conditions allowed preparing materials with different textural characteristics. Carbons were investigated as active electrode materials for the supercapacitors; influence of the textural parameters on electrochemical response and capacitive characteristics was discussed.
Experimental
Synthesis of carbons
Carbonization of rice husk in fluidized catalyst bed (FCB) reactor
Rice husk was received from Krasnodar region (Russia). As-received RH contains about 19 wt% of ash which is mainly silica. Before the carbonization process, as-received RH was milled to particles of about 1 mm size. RH carbonization was carried out in a tubular stainless steel reactor of 75 mm i.d., with 1000 mm height of catalyst bed of 3.5 l in volume. The reactor scheme is presented in Fig. 2.
The feedstock was fed to the reactor within air stream (molar ratio of O2 in air to carbon in RH was equal 2). The contact time of RH with the catalyst was estimated as 0.3–0.4 s. The temperature of the process was 465, 550, and 600 °C and controlled by external electroheaters; in the case of 600 °C, the process carried out in autothermal mode. A commercial CuCr2O4 + MgO/γ-Al2O3 catalyst (IC-12-73, Katalizator Co.) with 15 wt% of the active component was employed. Temperatures 465–600 °C have been found to be optimal for RH carbonization in the reactor in previous studies [21]. Increasing the carbonization temperature leads to increase of ash content in the obtained composites (Table 1) and to an increase of size of SiO2 phase particles [24] that can affect to texture characteristics of obtaining porous carbons.
The obtaining carbonized RH is carbon–silica nanocomposite (C/SiO2) materials with homogenously distributed carbon and silica phases. More detailed studies of carbonized RH and influence of the carbonization conditions in FCB reactor on the C/SiO2 properties are reported in [21]. Some characteristics of C/SiO2 composites utilized for further carbon materials preparation are shown in Table 1.
Carbonate and alkali activation of carbonized RH
Porous carbons were obtained from the carbonized RH (C/SiO2 composites) by two activating methods—with employing of carbonates and hydroxides of K and Na. For preparation of the carbons, a static stainless steel reactor of 8.5 l of volume and of productivity by the carbons 50–200 g per 1 run has been used.
In the case of carbonates’ utilization, C/SiO2 composites were thoroughly mixed with powdered K2CO3 + Na2CO3 equimolar mixture (to reduce T melt of the carbonate agent) or individual K2CO3 up to getting a homogenous mechanical mixture. Molar ratio of the carbonates to SiO2 of carbonized RH was varied from 1:1 to 3:1. The mixture was heated up to 900, 950 and 1000 °C with holding activation temperature for 0.5–3 h; the heating rate was 3 °C min−1.
In the case of alkali activation, C/SiO2 composites were mixed with scaly either KOH or NaOH (without additional water). Ratios of KOH and NaOH to C/SiO2 precursor were 4:1 and 3:1 by weight, respectively. The mixture of precursor and alkalis was dried at 320 °C for 4 h to remove traces of water from alkalis and C/SiO2 pores. After the drying, in the case of KOH, the mixture was heated up to 750 °C with following switching off the heater without holding at activating temperature; in the case of NaOH, the mixture was heated up to 800 °C with holding for 1 h. Heating rate was also 3 °C min−1. There were two approaches of KOH activation; the second differed from the first one by using a mechanical stainless still agitator built-in into the reactor through the reactor head to intensify the activation process.
After the both type of the activation, the obtained products were washed from water-soluble silicates and other Na and K compounds step by step: (1) by deionized water until the pH was neutral; (2) by 3 M HCl solution (3) by deionized water until the pH was neutral. The washed materials were dried overnight at 120 °C. In Table 2, conditions of the carbons synthesis and designation of the samples are summarized.
More detailed information on the preparation of C/SiO2 composites from RH and their alkali and carbonate activation is represented in [21–23].
Characterization of carbons
Textural characteristics of the prepared samples were obtained from the isotherms of nitrogen adsorption measured at 77 K by means of an automatic volumetric device ASAP 2400 (Micrometritics, USA). Isotherms of adsorption of carbon dioxide at 273.15 K were measured by means of Autosorb-6B-Kr adsorption analyzer (Quantachrome Instruments, USA). Before measurement, all samples were degassed by evacuation at 1.5 Pa and heating at 350 °C during 10 h. The samples were pre-treated at 423 K under residual pressure of ca. 10 mTorr. The BET surface area, A BET, was calculated from the adsorption isotherms under relative pressures P/P 0 (P 0 is the saturation pressure) of 0.05–0.2, correspondingly. Total mesopore and micropore volume were also calculated from pore size distribution obtained using non-local density functional theory (NLDFT). Mesopore size distribution was calculated from isotherms of nitrogen adsorption using NLDFT N2-carbon kernel based on slit-like pore model for pore size less than 2 nm and on cylinder-like pore model for larger pore. Micropore size distribution was calculated using NLDFT CO2-carbon kernel based on slit-like pore model at 273 K. All calculations were carried out using the software supplied with the instrument.
Preparation of the electrodes and electrochemical measurements
For the working electrode preparation, mixture of the porous carbon sample, carbon black and polytetrafluoroethylene (PTFE) in ratio 80:10:10 in water with a few drops of isopropanol was treated in ultrasonic bath during 20 min. PTFE was used as binder and carbon black as conductive additive. Then, the obtained mixture was dried in an oven at 130 °C during 5 h. Working electrodes in the form of 1 cm diameter pellets (ca. 15 mg) were obtained by pressing the mixture. The experiments were performed in a three-electrode cell in 1 M H2SO4 as an electrolyte. Counter electrode was platinized platinum and carbon electrode for the high-surface area samples; Hg/HgSO4 electrode was used as reference electrode. All potential values in the article are reported versus reversible hydrogen electrode (RHE). Electrochemical measurements were performed using a potentiostat/galvanostat Autolab PGSTAT 30. Electrochemical characteristics of the carbon materials were examined by cyclic voltammetry with 1 mV/s scan rate and chronopotentiometry at current densities from 0.2 A/g to 2 A/g.
Results and discussion
Textural characteristics of the carbons
Carbon materials were synthesized by the activation of carbonized rice husk at the different activation condition. Their textural characteristics are shown in Table 3.
Combination of the preparation conditions allowed to obtain series of the carbon with textural characteristics varied in the wide range. Higher activation temperature (900–1000 °C) and carbonates as activated agents lead to materials with A BET = 540–1400 m2/g. Decrease in the temperature to 750 – 800 °C and utilization of the alkalis allow to obtain samples with more developed porosity and significantly higher BET surface area (C2230–C3060) close to the highest possible for the porous carbons [22].
Under the carbonate activation process, the porosity of carbonized RH is developed mainly due to “leaching out” of the template silica phase in the form of water-soluble silicates and interaction of carbon phase with CO2 which is formed as a product of SiO2 and carbonates interaction. Besides that, carbon phase is able to interact with carbonates themselves with microporosity developing, especially in the case of molar ratios of carbonates to SiO2 more than 1:1 [23]. In whole, carbonate activation leads to obtaining carbons with A BET = 800–1400 m2g−1, possessing porosity shifted to mesopore area [23]. In the case of alkalis, porosity development in the carbons is due to interaction of alkalis both with SiO2 and carbon phases, but the carbon phase seems to undergo significant reconstruction because of interaction of alkalis with carbon via oxygen-containing surface functional groups. Previous studies have shown no or enough low porosity development under activation of graphite or carbon nanofibers by KOH, in comparison with activation of the carbonized RH [22].
Isotherms of nitrogen adsorption on carbonized rice husk with A BET = 540–1400 m2g−1 (Fig. 3a) show H4-type hysteresis which is characteristic for microporous materials with wide mesopore size distribution without well-defined or tailored pore size. Pore size distribution calculated using NLDFT (Fig. 4, Series 1) applied to nitrogen and carbon dioxide isotherms on all samples is rather similar to each other with micropore fraction in total pore volume 20–30 %. The pore size distribution demonstrates no plateau up to pore size of 40 nm. The main texture characteristic, which really changes in the series, is the total pore volume or the porosity. Total micropore volume calculated from CO2 adsorption is quite close to such volume calculated from N2 adsorption. The only appreciable exception in the series is the sample C890, which shows more micropore volume calculated from CO2 adsorption. This fact could be explained by well-known phenomenon activated adsorption in this material at cryogenic temperature [25].
Isotherms of nitrogen adsorption on samples obtained by alkalis activation (Fig. 3b) show a plateau without hysteresis loop at the relative pressure more than 0.4. Such behavior could indicate the existence of narrow size distribution of either micro- or mesopore. This fact is well illustrated by pore size distribution (Fig. 4, Series 2). As in the case of samples with lower ABET, the micropore size distribution taken from CO2 adsorption agrees with pore size distribution calculated from N2 adsorption. The exception is the sample C3060 that shows much more micropore volume calculated from CO2 adsorption, which could be explained by activated nitrogen adsorption on this sample at cryogenic temperature [25]. Pore size distribution on the series demonstrates a visible plateau for pore size more than 4 nm. The total micropore volume in the series is near to constant, whereas the mesopore volume increases in the row C2232 < C2700 < C3060.
Electrochemical properties of the carbon materials
Cyclic voltammograms of the electrodes recorded at 1 mV/s are presented in Fig. 5a. The magnitude of the observed current is increased with increasing the carbon surface area, which indicates the increase of the capacitance. CVs are characterized by the symmetric, close to rectangular shape indicating good ion diffusion into the bulk of the electrodes. However, some deviation from the rectangular shape is observed for the sample with the highest surface area, C3060. It is most likely connected with increased self-resistance of the material typical for the high-surface area carbons. Pair of the weak reversible peak (around 0.6 V) on the CV curves of the all samples is associated with quinone/hydroquinone couples (QHC) on the surface of the carbon [26]. Intensity of the current related to those peaks is minor which supposes negligible contribution to the overall capacitance.
Capacitance of the samples has been determined by the chronopotentiometry method (CPM) in the potential range from 0.05 to 0.95 V vs RHE. Utilization of CPM allows to determine dependence of the capacitance from the charge/discharge rate by varying current densities. Charge and discharge current density was varied from 0.2 A/g to 2 A/g. The charge/discharge curves at 0.2 A/g for the C890, C2230 and C3060 are presented in Fig. 5b. The curves for the rest of the samples are not shown due to the similarity in the behavior and differ only time of the charge/discharge processes.
All charge and discharge curves are started with initial IR drop usually associated partially with equivalent series resistance (ESR) and individual pore resistance specific for the porous materials [27, 28]. Drop value is on the same level for the all samples. The shape of the curves is symmetrical and close to linear with an insignificant deviation from linearity due to the presence of some amount of QHC, which is more pronounced for the samples C2700 (not shown) and C3060. Such behavior characterizes samples as an electric double layer capacitor with a negligible contribution of the pseudocapacitance. C3060 possesses the longest times of the charge and discharge indicating high capacitive performance. Coulombic efficiency lies in range 98–99 %.
Based on the data obtained by the chronopotentiometry method, the capacitance has been calculated using the following equation from the discharge curve:
where C (F)—capacitance, i (A)—discharge current, t (s)—discharge time, E (V)—potential window, x—either mass (g) or specific surface area (m2) of the electrode.
Values of gravimetric (C g) and surface (C s) capacitance obtained at the chosen discharge current density and performance rating C 2/C 0.2 are listed in Table 4. The dependence of the relative capacitance on the current density is shown in Fig. 6a.
As expected, sample with the highest surface area, C3060, possesses the highest gravimetric capacitance at all examined discharge current densities (0.2–2 A/g). Farther, with decreasing the specific surface area, the capacitance gradually decreases and reaches minimum for the sample with the smallest surface area, C540.
At the relatively slow charge/discharge rate, i.e., 0.2 A/g, each sample demonstrates the highest intrinsic to its value of capacitance. Progressive increase of the current density to the higher charge/discharge rate (2 A/g) leads to the decrease in the gravimetric capacitance. However, degree of decay is around 15 % for the all samples (Fig. 6a), which means a good rate performance. The good rate performance is provided by the relatively low micropore fraction (20–30 % independently of the surface area of the carbons, see Table 1) giving almost complete availability of the carbon surface for the electrolyte ions.
The dependence of the gravimetric capacitance from the surface area of the studied carbons is depicted in Fig. 6b. Capacitance change is almost linear with the specific surface area. However, correlation line does not intercept zero point, which does not have realistic explanation. Slope of the correlation line is 0.068 F/g which is less than the calculated Cs of any presented samples at that discharge current density (see Table 4). However, taking into account textural features of the carbons, samples can be divided into two groups in compliance with their pore structure. Such separation gives more reasonable results. Inside each group, correlation line intercepts zero point within experimental error and slope corresponds to the average values of the surface capacitance (see Table 4; Fig. 6b). Such observation is correct through the all examined current density range. Samples in series C540–C1400 possess higher average surface capacitance compared to the samples with higher surface area (C2230–C3060), 0.088 F/m2 and 0.075 F/m2 at 0.2 A/g, respectively. Higher surface capacitance of the samples in the sequence C540–C1400 can be explained by wider pore size distribution resulting in more surface accessibility. Changes in the pore structure and porosity increase for samples C2230, C2700 and C3060 lead to restriction of surface availability for electrolyte ions and consequently to decrease in value of the surface capacitance.
The dependence of the capacitance from the surface area is varied by way of preparation, origin of precursors and electrolyte species, textural characteristics and surface functionality of carbon materials. In some cases, dependence either does not observe at all or observe in a limited range of the surface area values. Thus, studies of the activated carbons [29–32] and activated carbon nanofibers [33] showed that after some critical value (in most of cases around 1500 m2/g) capacitance becomes independent of the surface area. Tendency to saturation supports by the idea that only limited available for the electrolyte surface takes part in the formation of the electric double layer. On the contrary, no correlation of capacitance and surface area was found on plasma-treated carbon nanofibers [34] and various activated carbons [35, 36]. Absence of the dependency is explained by the different factors governing double layer formation, main of which is presence of the oxygen-content groups and specific porous structure.
In the presented study, increase in the gravimetric capacitance with surface area is absolutely clear. Particularly, it should be emphasized that the linearity is kept up to high values of the surface area (~3000 m2/g). Linear dependence points out that the surface area is a determinative factor providing good capacitive performance. Utilization of the rice husk as the template-containing precursor allowed to prepare carbon materials with textural properties suitable for application as electrode materials in the supercapacitors.
Conclusions
In summary, activated carbons have been successfully produced from the rice husk carbonized in the fluidized catalyst bed reactor. Variation of the preparation conditions allowed to obtain carbon materials with surface area varied in wide range, from 540 to 3060 m2/g and, which should be emphasized especially, with close values of the micropore fraction (20–30 %). Linear dependence of the gravimetric capacitance from BET surface area was found, suggesting the surface area as crucial factors for the formation of the electric double layer and obtaining appropriate capacitive performance. Surface capacitance poorly depends on the surface area which is a characterized material surface as available for the electrolyte ions with insignificant diffusion limitation. Thus, utilization of the RH as template-containing precursor allows to prepare materials with textural characteristics attractive for the application in the supercapacitors.
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This work was supported by Russian Academy of Science, Project No. V.46.4.4.
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Lebedeva, M.V., Yeletsky, P.M., Ayupov, A.B. et al. Micro–mesoporous carbons from rice husk as active materials for supercapacitors. Mater Renew Sustain Energy 4, 20 (2015). https://doi.org/10.1007/s40243-015-0061-x
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DOI: https://doi.org/10.1007/s40243-015-0061-x