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Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation

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Chemical Research in Chinese Universities Aims and scope

Abstract

The rational design of efficient heterogeneous catalysts for Friedel-Crafts acylation reactions is highly desirable for meeting the need for the industrial production of various aromatic ketone compounds and biomass-derived chemicals. Herein, we reported that graphitic carbon wrapped FeCo bimetallic nanoparticles confined in nitrogen-doped carbon nanotubes, which were prepared by pyrolysis of FeCo-based Prussian blue analogue and melamine via a two-stage programmed heating procedure, exhibited excellent catalytic activity and recyclability for the acylation of aromatic compounds with acyl chlorides. The oxidized bimetallic species embedded in the external graphitic carbon shell should be the main active sites for the acylation reaction. The graphitic carbon shell and the carbon nanotube could provide effective protection on the active metal species against leaching through multiple interactions, leading to the formation of a highly active and durable heterogeneous catalyst for the acylation reaction.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22172058).

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Authors and Affiliations

  1. Department of Physical Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Zhenyu Lei, Honglei Sun, Zhehan Dong, Shuaishuai Sun, Chongyao Bi, Junling Zhan, Lin Wu & Mingjun Jia

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  1. Zhenyu Lei
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  2. Honglei Sun
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  3. Zhehan Dong
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  4. Shuaishuai Sun
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Correspondence to Mingjun Jia.

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40242_2024_4020_MOESM1_ESM.pdf

Supporting Information: Prussian blue analogue derived N-doped graphitic carbon wrapped iron-cobalt nanoparticles as recyclable heterogeneous catalysts for Friedel-Crafts acylation

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Lei, Z., Sun, H., Dong, Z. et al. Prussian Blue Analogue Derived N-Doped Graphitic Carbon Wrapped Iron-Cobalt Nanoparticles as Recyclable Heterogeneous Catalysts for Friedel-Crafts Acylation. Chem. Res. Chin. Univ. (2024). https://doi.org/10.1007/s40242-024-4020-x

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