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Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

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Abstract

Reductive amination of aldehydes/ketones with aqueous NH3 and hydrogenation of nitriles to primary amines with Co catalysts were reported. Co@NC-700 exhibited remarkable activity and high selectivity for the reductive amination of aldehydes/ketones with aqueous NH3 and the hydrogenation of nitriles to primary amines. Several primary amines can be obtained with good to excellent yields via the reductive amination of aldehydes/ketones and the hydrogenation of nitriles. The nitrogen-doped carbon(C)-supported Co@NC-700 metal catalyst was prepared via the pyrolysis of bioMOF Co/adenine in activated C. Co@NC-700 can be reused five times without evident loss of activity.

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Authors and Affiliations

  1. State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China

    Junmei Liu, Wanwan Guo, Hao Sun, Ruyue Li, Zhipeng Feng, Xuyang Zhou & Jun Huang

Authors
  1. Junmei Liu
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  2. Wanwan Guo
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  3. Hao Sun
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  4. Ruyue Li
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  5. Zhipeng Feng
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  6. Xuyang Zhou
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  7. Jun Huang
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Corresponding author

Correspondence to Jun Huang.

Additional information

Supported by the National Natural Science Foundation of China(No.21676140) and the Fund of the State Key Laboratory of Materials-oriented Chemical Engineering, China(No.ZK201711).

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Liu, J., Guo, W., Sun, H. et al. Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts. Chem. Res. Chin. Univ. 35, 457–462 (2019). https://doi.org/10.1007/s40242-019-8390-4

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  • DOI: https://doi.org/10.1007/s40242-019-8390-4

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