Skip to main content
SpringerLink
Log in

Amphiphilic ABC triblock terpolymer templating for mesoporous silica

  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

Self-assembled triblock terpolymers have attracted intense attention in recent years because of their abundant variety of assembly mesostructure. We reported the synthesis of mesoporous silica materials with the amphiphilic ABC triblock terpolymer polyethylene-poly(ethylene oxide)-polycaprolactone(PE-PEO-PCL) as a template and tetraethoxysilane(TEOS) as a silica source. Increasing the hydrophilic head group(PEO) led to the decrease of packing parameter g, which gave rise to the mesophase transformation from a cylindrical two-dimensional hexagonal P6mm structure to a cage-type face centered cubic closed-packing mesostructure. This new templating route provided a new insight into the template factor governed inorganic-organic self-assembly mesophases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lei B., Li B., Zhang H., Lu S., Zheng Z., Li W., Wang Y., Adv. Funct. Mater., 2006, 16, 1883

    Article  CAS  Google Scholar 

  2. Lei J., Wang L., Zhang J., Chem. Commun., 2010, 46, 8445

    Article  CAS  Google Scholar 

  3. Zhang X. A., Jia H. Y., Wang X. F., Zhang H. L., Yin H. W., Chin. Sci. Bull., 2009, 54, 3023

    Article  CAS  Google Scholar 

  4. Yu W. H., Zhou C. H., Tong D. S., Fang M., Zhang B., Chem. Res. Chinese Universities, 2010, 26(4), 622

    CAS  Google Scholar 

  5. Hu Y. Y., He J. P., Wang T., Guo Y. X., Xue H. R., Li G. X., Acta Chim. Sin., 2012, 70, 822

    Article  CAS  Google Scholar 

  6. Sun B., Guo Y., Xu L., Huang Z. H., Wu P., Che S., Acta Chim. Sin., 2012, 70, 2419

    Article  CAS  Google Scholar 

  7. He H. Y., Li W. L., Xie Z. G., Jing X. B., Huang Y. B., Chem. Res. Chinese Universities, 2014, 30(2), 310

    Article  CAS  Google Scholar 

  8. Fan J., Yu C., Gao F., Lei J., Tian B. Z., Wang L. M., Luo Q., Tu B., Zhou W. Z., Zhao D. Y., Angew. Chem. Int. Ed., 2003, 42, 3146

    Article  CAS  Google Scholar 

  9. Sun J. M., Zhang H., Tian R. J., Ma D., Bao X. H., Sun D. S., Zhou H. F., Chem. Commun., 2006, (12), 1322

    Google Scholar 

  10. Li X. L., Zuo W. W., Luo M., Shi Z. S., Cui Z. C., Zhu S., Chem. Res. Chinese Universities, 2013, 29(6), 1214

    Article  CAS  Google Scholar 

  11. Zhang J. B., Yang Y. X., Tian M. J., Deng C. J., Cao L., Yuan H. M., Acta Chim. Sin., 2013, 71, 602

    Article  CAS  Google Scholar 

  12. Gu J. L., Shi J. L., You G. J., Xiong L. M., Qian S. X., Hua Z. L., Chen H. R., Adv. Mater., 2005, 17, 557

    Article  CAS  Google Scholar 

  13. Zhang W. K., Hu C. L., Huang Y. Y., Zhang M. Q., Liang H., Chen X. D., Acta Chim. Sin., 2012, 70, 2425

    Article  CAS  Google Scholar 

  14. Gerbaldi C., Meligrana G., Bodoardo S., Tuel A., Penazzi N., J. Power Sources, 2007, 174, 501

    Article  CAS  Google Scholar 

  15. Wang G., Liu H., Horvat J., Wane B., Qiao S., Park J., Ahn H., Chem. Eur. J., 2010, 16, 11020

    Article  CAS  Google Scholar 

  16. Cameron N. S., Corbierre M. K., Eisenberg A., Can. J. Chem., 1999, 77, 1311

    Article  CAS  Google Scholar 

  17. Gong Y., Huang H., Hu Z., Chen Y., Chen D., Wang Z., He T., Macromolecules, 2006, 39, 3369

    Article  CAS  Google Scholar 

  18. Zhang Q. L., Xu T., Butterfield D., Misner M. J., Ryu D. Y., Emrick T., Russell T. P., Nano. Lett., 2005, 5, 357

    Article  CAS  Google Scholar 

  19. Hur K., Francescato Y., Giannini V., Maier S. A., Hennig R. G., Wiesner U., Angew. Chem. Int. Ed., 2011, 50, 11985

    Article  CAS  Google Scholar 

  20. Shefelbine T. A., Vigild M. E., Matsen M. W., Hajduk D. A, Hillmyer M. A., Cussler E. L., Bates F. S., J. Am. Chem. Soc., 1999, 121, 8457

    Article  CAS  Google Scholar 

  21. Zhao D. Y., Feng J. L., Huo Q. S., Melosh N., Fredrickson G. H., Chmelka B. F., Stucky G. D., Science, 1998, 279, 548

    Article  CAS  Google Scholar 

  22. Deng Y. H., Yu T., Wan Y., Shi Y. F., Meng Y., Gu D., Zhang L. J., Huang Y., Liu C., Wu X. J., Zhao D. Y., J. Am. Chem. Soc., 2007, 129, 1690

    Article  CAS  Google Scholar 

  23. Yu K., Hurd A. J., Eisenberg A., Brinker C. J., Langmuir, 2001, 17, 7961

    Article  CAS  Google Scholar 

  24. Wei J., Yue Q., Sun Z. K., Deng Y. H., Zhao D. Y., Angew. Chem. Int. Ed., 2012, 51, 6149

    Article  CAS  Google Scholar 

  25. Wei J., Wang H., Deng Y. H., Sun Z. K., Shi L., Tu B., Luqman M., Zhao D. Y., J. Am. Chem. Soc., 2011, 133, 20369

    Article  CAS  Google Scholar 

  26. Li J. G., Chang Y. H., Lin Y. S., Kuo S. W., RSC Advances, 2012, 2, 12973

    Article  CAS  Google Scholar 

  27. Stefik M., Wang S. T., Hovden R., Sai H., Tate M. W., Muller D. A., Steiner U., Gruner S. M., Wiesner U., J. Mater. Chem., 2012, 22, 1078

    Article  CAS  Google Scholar 

  28. Li J. G., Lin R. B., Kuo S. W., RSC Advances, 2013, 3, 17411

    Article  CAS  Google Scholar 

  29. Woodcock L.V., Nature, 1997, 385, 141

    Article  CAS  Google Scholar 

  30. Huo Q. S., Margolese D. I., Stucky G. D., Chem. Mater., 1996, 8, 1147

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai, 200240, P. R. China

    Huan Wang, Yuan Yao, Lu Han & Shun’ai Che

Authors
  1. Huan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuan Yao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lu Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shun’ai Che
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shun’ai Che.

Additional information

Supported by the National Basic Research Program of China(No.2013CB934101), the National Natural Science Foundation of China(Nos.21201120, 21101106), the Youth Natural Science Foundation of Shanghai City, China(No.12ZR1445100), the “Chenguang” Program of the Shanghai Educational Development Foundation, China(No.12CG10) and the Fund from Evonik Industries.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, H., Yao, Y., Han, L. et al. Amphiphilic ABC triblock terpolymer templating for mesoporous silica. Chem. Res. Chin. Univ. 30, 863–867 (2014). https://doi.org/10.1007/s40242-014-4122-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-014-4122-y

Keywords

Search

Navigation