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Synthesis, structures, fluorescence and magnetism of two lanthanide metal-organic frameworks with CaF2 topology based on silicon-centered tetrahedral ligand

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Abstract

Two 3D multifunctional lanthanide metal-organic frameworks(MOFs), Pr(HTCPS)(H2O)·2DMF·C2H5OH·5H2O(JUC-93) and Pr3(TCPS)2(NO3)(H2O)4(DMA)2·2DMA·C2H5OH·3H2O(JUC-94)[H4TCPS=tetrakis(4-carboxyphenyl)silane, DMF=N,N′-dimethylformamide, DMA=N,N′-dimethylacetamide and JUC=Jilin University China] were synthesized by the self-assembly of a rigid silicon-centered tetrahedral carboxylate ligand H4TCPS and Pr(III) ions in different solvothermal reactions. X-Ray crystallography revealed that they exhibited a rare CaF2 topology framework, constructed from the 4-connected tetrahedral TCPS unit with the 8-connected dinuclear praseodymium cluster unit and trinuclear praseodymium cluster unit, respectively. In addition, the luminescent and magnetic properties of the two compounds were investigated.

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Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, P. R. China

    Yang-xue Li, Ming Xue, Lin Huang, Si-ru Chen & Shi-lun Qiu

Authors
  1. Yang-xue Li
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  2. Ming Xue
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  3. Lin Huang
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  4. Si-ru Chen
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  5. Shi-lun Qiu
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Corresponding authors

Correspondence to Ming Xue or Shi-lun Qiu.

Additional information

Supported by the National Basic Research Program of China(Nos.2011CB808703, 2012CB821700) and the National Natural Science Foundation of China(Nos.91022030, 21101072).

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Li, Yx., Xue, M., Huang, L. et al. Synthesis, structures, fluorescence and magnetism of two lanthanide metal-organic frameworks with CaF2 topology based on silicon-centered tetrahedral ligand. Chem. Res. Chin. Univ. 29, 611–616 (2013). https://doi.org/10.1007/s40242-013-2473-4

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  • DOI: https://doi.org/10.1007/s40242-013-2473-4

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