Abstract
Prickly carbonated hydroxyapatite(CHAp) spheres were obtained via a facile template-free self-assembly method with Na2HPO4 and self-made cubic CaCO3 as reactants. X-ray diffraction results of the product revealed CHAp with high crystallinity could be successfully prepared in a short reaction time. A nucleation mechanism was proposed according to the results of characterizing the resultant powders and analyzing the growth process. It shows that the self-made CaCO3 particles play an important role in the template-free synthesis of prickly spheres.
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Veiderma M., Tõnsuaadu K., Knubovets R., Peld M., J. Organomet. Chem., 2005, 690, 2638
Zhang P., Hong Z., Yu T., Chen X., Jing X., Biomaterials, 2009, 30, 58
Izquierdo-Barba I., Arcos D., Sakamoto Y., Terasaki O., López-Noriega A., Vallet-Regí M., Chem. Mater., 2008, 20, 3191
Fleet M. E., Liu X., J. Solid State Chem., 2008, 181, 2494
Arcos D., Rodriguez-Carvajal J., Vallet-Regi M., Chem. Mater., 2004, 16, 2300
Kannan S., Ferreira J. M.F., Chem.Mater., 2006, 18, 198
Kannan S., Lemos A. F., Ferreira J. M. F., Chem. Mater., 2006, 18, 2181
Kumar R., Prakash K. H., Cheang P., Khor K. A., Langmuir, 2004, 20, 5196
Wang Z. X., Hou Y., Han W., Chem. Res. Chinese Universities, 2011, 27(1), 94
Zhang D. L, Fu H. Y., Zhao X. Y., Zhao H. W., Chen H., Liu Y. M., Li X. J., Chem. J. Chinese Universities, 2012, 33(8), 1835
Zhang J. Z., Li D. D., Liu G. F., Wu Q., Wang J. C., Chem. J. Chinese Universities, 2012, 33(2), 219
Batton J., Kadakshama A. J., Nzihou A., Singh P., Aubry N., J. Hazardous Mater. A, 2007, 139, 461
Wang K. W., Zhu Y. J., Chen X. Y., Zhai W. Y., Wang Q., Chen F., Chang J., Duan Y. R., Chem. Asian J., 2010, 5(12), 2477
Luo P., Nieh T. G., Biomaterials, 1996, 17, 1959
Mori K., Hara T., Mizugaki T., Ebitani K., Kaneda K., J. Am. Chem. Soc., 2004, 126, 10657
Choudary B. M., Sridhar C., Kantam M. L., Venkanna G. T., Sreedhar B., J. Am. Chem. Soc., 2005, 127, 9948
He Q., Huang Z., Liu Y., Chen W., Xu T., Mater. Lett., 2007, 61, 141
Seoa D. S., Lee J. K., J. Cryst. Growth, 2008, 310, 2162
Chen H., Sun K., Tang Z., Law R. V., Mansfield J. F., Czajka-Jakubowska A., Clarkson B. H., Cryst. Growth Des., 2006, 6, 1504
Zhang H. G., Zhu Q., Wang Y., Chem. Mater., 2005, 17, 5824
Sarig S., Kahana F., J. Cryst. Growth, 2002, 237, 55
Ma M. G., Zhu Y. J., Chang J., J. Phys. Chem. B, 2006, 110, 14226
Liu J., Li K., Wang H., Zhu M., Yan H., Chem. Phys. Lett., 2004, 396, 429
Xu Y., Jiang J., Lu Y., Sun R., Song J., Ren L., Yu S., Cryst. Growth Des., 2008, 8, 3822
Wang C., Liu Y., Bala H., Pan Y., Zhao J., Zhao X., Wang Z., Colloids Surfaces A, 2007, 297, 179
Borum L., Wilson O. C., Biomaterials, 2003, 24, 3681
Smigelskas A. D., Kirkendall E. O., Trans. AIME, 1947, 171, 130
Yang J., Qi L., Lu C., Ma J., Cheng H., Angew. Chem. Int. Ed., 2005, 44, 598
Rodriguez-Lorenzo L. M., Vallet-Regi M., Chem. Mater., 2000, 12, 2460
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Supported by the Jilin Provincial Science and Technology Development Funds, China(No.20100334) and the Jilin Provincial Education Department’s “12th Five-Year” Scientific and Technological Research Projects, China[No.126(2013)].
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Liu, Y., Luo, Yg., Zhao, Ln. et al. Facile template-free synthesis of carbonated hydroxyapatite spheres in aqueous solution. Chem. Res. Chin. Univ. 29, 404–407 (2013). https://doi.org/10.1007/s40242-013-2455-6
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DOI: https://doi.org/10.1007/s40242-013-2455-6