Abstract
The degradation of hydrogenated nitrile-butadiene rubber(HNBR) soaped in aqueous solutions of H2S and HCl was investigated. The samples unexposed and exposed to different solutions were characterized by 13C nuclear magnetic resonance, X-ray photoelectron and infrared spectroscopies. In contrast to those of unexposed samples and samples soaped in HCl solution, the mechanical properties of samples exposed to H2S solution significantly deteriorated, in which the new groups of C(=O)-NH2, C-S-C and C=S emerged. The mechanism of C=S and C-S-C formation was speculated, except for that of the formation of group C(=O)-NH2, which was widely discussed in acidic condition such as HCl solution. The formation of C-S-C was due to radical reaction initiated by mercapto radical and that of C=S was due to nucleophilic reaction initiated by mercapto cations. This finding is helpful to understanding the seal failure of HNBR in working environment containing H2S.
Similar content being viewed by others
References
Severe G., White J. L., J. Appl. Polym. Sci., 2005, 95, 2
Zhao W., Yu L., Zhong X., Zhang Y., Sun J., J. Appl. Polym. Sci., 1994, 54, 1199
Giurginca M., Zaharescu T., Polymer, 2000, 41, 7583
Gatos K. G., Sawanis N. S., Apostolov A. A., Thomann R., Karger-Kocsis J., Macromol. Mater. Eng., 2004, 289, 1079
Gatos K. G., Százdi L., Pukánszky B., Karger-Kocsis J., Macromol. Rapid Commun., 2005, 26, 915
Cadambi R. M., Ghassemieh E., J. Elastom. Plast., 2012, 44, 353
Guan Y., Zhang L. X., Zhang L. Q., Lu Y. L., Polym. Degrad. Stabil., 2011, 96, 808
Choudhury A., Bhowmick A. K., Soddemann M., Polym. Degrad. Stabil., 2010, 95, 2555
Choudhury A., Bhowmick A. K., Ong C., J. Appl. Polym. Sci., 2010, 116, 1428
Chen S., Yu H., Ren W., Zhang Y., Thermochim. Acta, 2009, 491, 103
Lovy J. J., Vaclav H. H., Collect. Czech. Chem. Commun., 1984, 49, 506
Va S., J. Biomater. Appl., 1989, 3, 552
Ermakov I. V., Rebrov A. I., Litmanovich A. D., Platé N. A., Macromol. Chem. Phys., 2000, 201, 1415
Litmanovich A. D., Platé N. A., Macromol. Chem. Phys., 2000, 201, 2176
Kudryavtsev Y. V., Krentsel L. B., Bondarenko G. N., Litmanovich A. D., Platé N. A., Schapowalow S., Sackmann G., Macromol. Chem. Phys., 2000, 201, 1419
Krentsel L. B., Kudryavtsev Y. V., Rebrov A. I., Litmanovich A. D., Plate N. A., Macromolecules, 2001, 34, 5607
Vega-Cantu Y., Hauge R., Norman L., Billups W. E., J. Appl. Polym. Sci., 2003, 89, 1250
Kochi T., Noda S., Yoshimura K., Nozaki K., J. Am. Chem. Soc., 2007, 129, 8948
Ning S., Yang S., Wei X., Wang W., Zhang L., Yue D., J. Appl. Polym. Sci., 2012, 123, 1040
Schulz G. S., Comin E., Souza R. F., J. Appl. Polym. Sci., 2012, 123, 3605
Ouyang Q., Cheng L., Wang H. J., Li K. X., Polym. Degrad. Stabil., 2008, 93, 1415
Perraud S., Vallat M. F., David M. O., Kuczynski J., Polym. Degrad. Stabil., 2010, 95, 1495
Shang Y. M., Li J., Song Z. G., Li Y. Z., Huang H. M., Chem. Res. Chinese Universities, 2007, 23(4), 430
Liu C. H., Gao C., Yan D. Y., Chem. Res. Chinese Universities, 2005, 21(3), 345
Ren J., Huang J. X., Li Y., Zhou Y. Y., Chem. Res. Chinese Universities, 2004, 20(2), 142
Bhattacharjee S., Bhowmick A. K., Avasthi B. N., Polym. Degrad. Stabil., 1991, 31, 71
William S., Chem. Rev., 1983, 89, 263
Kasturi C. R., Canadian J. Chem., 1964, 42, 36
Bondar V. S., Purtov K. V., Malikova N. P., Frank L. A., Illarionov B. A., Biochemistry (Moscow), 2001, 66, 1014
Howard A. E., Kollman P. A., J. Am. Chem. Soc., 1988, 110, 7195
Zhang G. J., Meng H., Ji S. L., Desalination, 2009, 242, 313
Author information
Authors and Affiliations
Corresponding author
Additional information
Supporter by the National Natural Science Foundation of China (No.51003121) and the Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China(No. 707010).
Rights and permissions
About this article
Cite this article
Cong, Cb., Cui, Cc., Meng, Xy. et al. Degradation of hydrogenated nitrile-butadiene rubber in aqueous solutions of H2S or HCl. Chem. Res. Chin. Univ. 29, 806–810 (2013). https://doi.org/10.1007/s40242-013-2401-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-013-2401-7