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Corrosion Behaviors of Nitride Coatings on Titanium Alloy in NaCl-Induced Hot Corrosion

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

TiN and TiAlN coatings were deposited by arc ion plating on titanium alloys to study their hot corrosion resistance when they were exposed to NaCl at 600 °C. The microstructure and corrosion behaviors of nitride coatings were studied using scanning electron microscope, X-ray diffraction, electro-probe microanalyzer and X-ray photoelectron spectroscopy. The results showed that nitride coatings with the different compositions and the ones with the same composition but different thicknesses presented different hot corrosion resistance. TiN and thin TiAlN coatings showed poor corrosion resistance. Serious internal oxidation attacked the alloy substrate. Their corrosion products were mainly consisted of non-protective TiO2 and sodium salt. By contrast, the thick TiAlN coating presented outstanding corrosion resistance. Besides sodium salt, the corrosion products were composed of protective Al2O3. The increasing thickness of TiAlN significantly enhanced the hot corrosion resistance. The corrosion mechanisms of alloy, TiN and TiAlN coatings were discussed in detail.

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Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (Nos. 51901071, 51871229 and 51701223); the Program for Innovative Research Team (in Science and Technology) in University of Henan Province (No. 20IRTSTHN016); the High-Level Talents Introduction Project of Henan Institute of Science and Technology (No. 203010618003); the Science and Technology Research Project of Henan Province (No. 202102310288); the Landmark Innovation Project of Henan Institute of Science and Technology; the Young Key Teachers Projects in Henan Higher Education Institutions (No. 2018GGJS113).

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Authors and Affiliations

  1. School of Mechanical and Electrical Engineering, Henan Institute of Science and Technology, Xinxiang, 453003, China

    Mingming Zhang, Yipeng Feng, Yahui Wang, Yongfeng Li & Jianxiu Su

  2. Corrosion and Protection Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Shenyang, 110016, China

    Mingming Zhang, Yunsong Niu, Li Xin & Shenglong Zhu

  3. Corrosion and Protection Division, Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang, 110819, China

    Fuhui Wang

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  1. Mingming Zhang
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  2. Yipeng Feng
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  5. Li Xin
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Correspondence to Yunsong Niu or Yongfeng Li.

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Zhang, M., Feng, Y., Wang, Y. et al. Corrosion Behaviors of Nitride Coatings on Titanium Alloy in NaCl-Induced Hot Corrosion. Acta Metall. Sin. (Engl. Lett.) 34, 1434–1446 (2021). https://doi.org/10.1007/s40195-021-01264-8

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  • DOI: https://doi.org/10.1007/s40195-021-01264-8

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