Abstract
The Al–2.5C master alloy is prepared to investigate the effect of the Al4C3 particle size distribution on the refining efficiency of the AZ31 alloy. The results indicate that the Al4C3 particles are potent nucleation substrates for primary α-Mg grains. With 1.0 wt% master alloy addition, the grain size is reduced from 204 to 70 μm. The grain refining efficiency of the Al4C3 particles on the AZ31 alloy is calculated to be 0.04%–0.75%. Such low refining efficiency is mainly attributed to the size distribution of the Al4C3 particles. The particle sizes are in the range from 0.18 to 7.08 μm, and their distribution is well fitted by a log-normal function. The optimum particle size range for significant grain refinement is proposed to be around 5.0–7.08 μm in the present conditions.
Similar content being viewed by others
References
Y. Ali, D. Qiu, B. Jiang, F.S. Pan, M.X. Zhang, J. Alloys Compd. 619, 639 (2015)
Y. Yan, W.P. Deng, Z.F. Gao, J. Zhu, Z.J. Wang, X.W. Li, Acta Metall. Sin. (Engl. Lett.) 29, 163 (2016)
D.H. Hou, S.M. Liang, R.S. Chen, C. Dong, E.H. Han, Acta Metall. Sin. (Engl. Lett.) 28, 115 (2015)
A.A. Luo, Int. Mater. Rev. 49, 13 (2004)
J.B. Lin, X.Y. Wang, W.J. Ren, X.X. Yang, Q.D. Wang, J. Mater. Sci. Technol. 32, 783 (2016)
J. Du, M.H. Wang, M.C. Zhou, W.F. Li, J. Alloys Compd. 592, 313 (2014)
L. Wang, Y.M. Kim, J.H. Lee, B.S. You, Mater. Sci. Eng., A 528, 1485 (2011)
Y.M. Kim, L. Wang, B.S. You, J. Alloys Compd. 490, 695 (2010)
G. Han, X.F. Liu, H.M. Ding, J. Alloys Compd. 467, 202 (2009)
M. Qian, P. Cao, Scr. Mater. 52, 415 (2005)
L. Lu, A.K. Dahle, D.H. StJohn, Scr. Mater. 53, 517 (2005)
Q.L. Jin, J.P. Eom, S.G. Lim, W.W. Park, B.S. You, Scr. Mater. 49, 1129 (2003)
T.J. Chen, X.D. Jiang, Y. Ma, Y.D. Li, Y. Hao, J. Alloys Compd. 496, 218 (2010)
L. Lu, A.K. Dahle, D.H. StJohn, Scr. Mater. 54, 2197 (2006)
Y.C. Pan, X.F. Liu, H. Yang, J. Mater. Sci. Technol. 21, 822 (2005)
X.T. Liu, H. Hao, J. Alloys Compd. 623, 266 (2015)
S.F. Liu, Y. Chen, H. Han, J. Alloys Compd. 624, 266 (2015)
T.E. Quested, A.L. Greer, Acta Mater. 53, 2683 (2005)
A. Tronche, A.L. Greer, Philos. Mag. Lett. 81, 321 (2001)
A.L. Greer, A.M. Bunn, A. Tronche, P.V. Evans, D.J. Bristow, Acta Mater. 48, 2823 (2000)
T.E. Quested, A.L. Greer, Acta Mater. 52, 3859 (2004)
M. Sun, M.A. Easton, D.H. StJohn, G.H. Wu, T.B. Abbott, W.J. Ding, Adv. Eng. Mater. 15, 373 (2013)
E.E. Underwood, E.A. Starke, American Society for Testing and Materials, 1979, pp. 633–682
K. Li, Z.G. Sun, F. Wang, N.G. Zhou, X.W. Hu, Appl. Surf. Sci. 270, 584 (2013)
S. Nimityongskul, M. Jones, H. Choi, R. Lakes, S. Kou, X.C. Li, Mater. Sci. Eng. A 527, 2104 (2010)
A.R. Kennedy, D.P. Weston, M.I. Jones, C. Enel, Scr. Mater. 42, 1187 (2000)
T.E. Quested, A.L. Greer, P.S. Cooper, Mater. Sci. Forum 396–402, 53 (2002)
W.C. Yang, L. Liu, J. Zhang, S.X. Ji, Z.Y. Fan, Mater. Lett. 160, 263 (2015)
T.J. Chen, R.Q. Wang, H.J. Huang, Y. Ma, Y. Hao, Trans. Nonferrous Met. Soc. China 22, 1533 (2012)
E. Wang, T. Gao, J.F. Nie, X.F. Liu, J. Alloys Compd. 594, 7 (2014)
D.H. StJohn, M. Qian, M.A. Easton, P. Cao, Acta Mater. 59, 4907 (2011)
M. Qian, D.H. StJohn, M.T. Frost, Scr. Mater. 50, 1115 (2004)
D. Qiu, M.X. Zhang, J. Alloys Compd. 488, 260 (2009)
Acknowledgements
The work was supported by the National Key Research and Development Program of China (No. 2016YFB0701204) and the project (DUT15JJ (G) 01) supported by the Fundamental Research Funds for the Central Universities.
Author information
Authors and Affiliations
Corresponding author
Additional information
Available online at http://link.springer.com/journal/40195
Rights and permissions
About this article
Cite this article
Zhao, YZ., Liu, XT. & Hao, H. Effect of Al4C3 Particle Size Distribution in a Al–2.5C Master Alloy on the Refining Efficiency of the AZ31 Alloy. Acta Metall. Sin. (Engl. Lett.) 30, 505–512 (2017). https://doi.org/10.1007/s40195-017-0556-9
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-017-0556-9