The specific dynamic magnetic response and magnetic relaxation phenomena in magnetite-based glass-ceramics by controlled crystallization of Fe-rich borosilicate glasses with 25 wt% Fe2O3, in the presence of two types of nucleating agents, Cr2O3 and P2O5, were investigated. The magnetic response is complex and shows contributions arising from two subsystems: a system with collective characteristics, superspin-glass like, and another one with single particle characteristics (superparamagnetic) with dipolar interaction. The nucleating agents have strong influence on the characteristic temperatures and anisotropy energy.
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This work was supported by a grant of the Romanian National Authority for Scientific Research and Innovation, CNCS/CCCDI-UEFISCDI, project number PN-III-P2-2.1-PED-2016-1741 (contract 163PED/2017), ROMBRICKS, Core Program PN 10/2016 at NIMP and by the Office of Naval Research at USNA.
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Sandu, V., Cimpoiasu, E., Kuncser, A. et al. Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses. J Adv Ceram 6, 251–261 (2017). https://doi.org/10.1007/s40145-017-0236-2