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One-dimensional rare-earth tungstate nanostructure encapsulated reduced graphene oxide electrocatalyst-based electrochemical sensor for the detection of organophosphorus pesticide

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Abstract

The use of agricultural pesticides in modern agriculture has permitted enormous and reliable production. The organophosphorus pesticide fenitrothion (FT) is widely used in agricultural regions and has been related to detrimental effects on human health. We constructed an electrochemical sensor that detects fenitrothion (FT) using one-dimensional (1D) Pr2(WO4)3 nanorods (PWO) incorporated reduced graphene oxide (RGO) electrocatalyst that was synthesized hydrothermally. The PWO nanorods are finely embedded on the RGO nanosheet, according to powder XRD, FESEM, EDS, HRTEM, XPS, and micro-Raman studies. The PWO/RGO electrochemical behavior towards FT was studied by the different electrochemical characterization approaches [CV, DPV, AMP(i–t)]. Our proposed PWO/RGO sensor exhibited a linear range of 0.01–313 µM and an LOD of 0.0054 µM in AMP(i–t). The estimation of FT in different water samples proves the usefulness of the PWO/RGO sensor.

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Acknowledgements

The work was supported by the Ministry of Science and Technology, Taiwan under Contract no. MOST 111-2113-M-027-002. This work was supported by the projects from NTUT-NJUST-110-01 and NSFC51872141, National Taipei University of Technology, and Nanjing University of Science and Technology.

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Authors and Affiliations

  1. Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No. 1, Section 3, Chung−Hsiao East Road, Taipei, 106, Taiwan, ROC

    Ruspika Sundaresan, Vinitha Mariyappan, Tse-Wei Chen, Shen-Ming Chen & Muthumariappan Akilarasan

  2. Research and Development Center for Smart Textile Technology, National Taipei University of Technology, Taipei, 106, Taiwan, ROC

    Tse-Wei Chen

  3. Department of Materials, Imperial College London, London, SW72AZ, UK

    Tse-Wei Chen

  4. Key Laboratory of Education Ministry for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Nanjing, 210094, China

    Xiaoheng Liu

  5. Well Fore Special Wire Corporation, 10, Tzu-Chiang 7Rd., Chung-Li Industrial Park, Taoyuan, Taiwan

    Jaysan Yu

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  1. Ruspika Sundaresan
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Sundaresan, R., Mariyappan, V., Chen, TW. et al. One-dimensional rare-earth tungstate nanostructure encapsulated reduced graphene oxide electrocatalyst-based electrochemical sensor for the detection of organophosphorus pesticide. J Nanostruct Chem (2023). https://doi.org/10.1007/s40097-023-00524-6

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