Abstract
Graphene nanoplatelets are a novel class of carbon nanostructures. They possess an ultra high surface area, and thus have great potentials for the use as sorbent materials. We herein demonstrate the use of graphene nanoplatelets as an adsorbent material for solid-phase extraction. Surface compositions of graphene nanoplatelets were examined by X-ray photoelectron spectroscopy. Scanning electron and transmission electron microscopies were performed to elucidate the morphology of graphene nanoplatelets. Three chlorophenols, 3-chlorophenol, 4-chlorophenol, and 2,4-dichlorophenols were selected as model analytes and extracted on a graphene nanoplatelets-packed solid-phase extraction cartridge, followed by elution with alkaline methanol. The extracted chlorophenols were identified and quantified by UV-vis spectrophotometer. Under the optimized experimental conditions, good linearity (R2 >0.9969), recovery (95–103%), precision (<12%), and accuracy (<±9%) were achieved. The advantages of graphene nanoplatelets as solid phase extraction adsorbent, such as good reusability and no impact of sorbent drying, have been detailed. The present study proposes a useful method for water sample pretreatment and reveals the potential of graphene nanoplatelets as an excellent sorbent material in analytical processes.
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References
Ahlborg UG and Thunberg TM (1980) Chlorinated phenols: occurrence, toxicity, metabolism, and environmental impact. Crit Rev Toxicol 7, 1–35.
Allen MJ, Tung VC and Kaner RB (2010) Honeycomb carbon: a review of graphene. Chem Rev 110, 132–145.
Bianchi F, Careri M, Mucchino C, and Musci M (2002) Improved determination of chlorophenols in water by solid-phase microextraction followed by benzoylation and gas chromatography with electron capture detection. Chromatographia 55, 595–600.
Chen J, Zou J, Zeng J, and Song X (2010) Preparation and evaluation of graphene-coated solid-phase microextraction fiber. Anal Chim Acta 678, 44–49.
Choi W, Lahiri I, Seelaboyina R, and Kang YS (2010) Synthesis of graphene and its applications: a review. Crit Rev Solid State Mater Sci 35, 52–71.
Dong XL, Cheng JS, Li JH, and Wang YS (2010) Graphene as a novel matrix for the analysis of small molecules by MALDI-TOF MS. Anal Chem 82, 6208–6214.
Dreyer DR, Park S, Bielawski CW, and Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39, 228–240.
Geim AK (2009) Graphene: Status and Prospects. Science 324, 1530–1534.
Haghi ZE (2011) Extraction and determination of three chlorophenols by hollow fiber liquid phase microextraction-spectrophotometric analysis, and evaluation procedures using mean centering of ratio spectra method. A J Anal Chem 2, 1–8.
Huang KJ, Yu S, Li J, Wu ZW, and Wei CY (2012) Extraction of neurotransmitters from rat brain using graphene as a solid-phase sorbent, and their fluorescent detection by HPLC. Microchim Acta 176, 327–335.
Jimeez-Soto JM, Cardenas S, and Valcarcel M (2009) Evaluation of carbon nanocones/disks as sorbent material for solid-phase extraction. J Chromogr A 1216, 5626–5633.
Jung MW, Park HM, Rhee JS, Baek DJ, and Paeng KJ (1997) The characterization of synthetic active carbons as a sorbent for solid phase extraction. Anal Sci 13, 347–350.
Kim JY, In MK, Paeng KJ, and Chung BC (2005) Simultaneous determination of carisoprodol and meprobamate in human hair using solid-phase extraction and gas chromatography/mass spectrometry of the trimethylsilyl derivatives. Rapid Commun Mass Spectrom 19, 3056–3062.
Kotov NA (2006) Materials science: carbon sheet solutions. Nature 442, 254–255.
Lezamiz J and Jönsson JA (2007) Development of a simple hollow fibre supported liquid membrane extraction method to extract and preconcentrate dinitrophenols in environmental samples at ng L (−1) level by liquid chromatography. J Chromatogr A 1152, 226–233.
Liu Q, Shi JB, Sun JT, Wang T, Zeng LX, and Jiang GB (2011) Graphene and graphene oxide sheets supported on silica as versatile and highperformance adsorbents for solid-phase extraction. Angew Chem Int Ed 50, 5913–5917.
Liu Q, Shi JB, Zeng LX, Wang T, Cai YQ, and Jiang GB (2011) Evaluation of graphene as an advantageous adsorbent for solid-phase extraction with chlorophenols as model analytes. J Chromatogr A 1218, 197–204.
Luo YB, Yuan BF, Yu QW, and Feng YQ (2012) Substrateless graphene fiber: a sorbent for solid-phase microextraction. J Chromatogr A 1268, 9–15.
Mathialagan T and Viraraghavan T (2008) Biosorption of chlorophenols: A Review. Int J Environ Pollut 34, 164–194.
Ning B, Meihua H, Hongyu Z, Haibo Q, Yuan T, and Hanqi Z (2013) Determination of 6-thioguanine based on localized surface plasmon resonance of gold nanoparticle. Spectrochim Acta A 107, 24–30.
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV et al. (2004) Electric field effect in atomically thin carbon films. Science 306, 666–669.
Partoens B and Peeters FM (2006) From graphene to graphite: Electronic structure around the K point. Phys Rev B 74, 1–11.
Pumera M (2009) Electrochemistry of graphene: New horizons for sensing and energy storage. Chem Rev 9, 211–233.
Ribeiro A, Neves MH, Almeida MF, Alves A, and Santos L (2002) Direct determination of chlorophenols in land-fill leachates by solid-phase micro-extraction-gas chromatography-mass spectrometry. J Chromatogr A 975, 267–274.
Stoller MD, Park SJ, Zhu YW, An JH, and Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8, 3498–3502.
Thurman EM and Mills MS (1998) In Solid-phase Extraction: Principles and Practice (1st ed). John Wiley and Sons, inc., USA.
Wang W, Ma X, Wu Q, Wang C, Zang X, and Wang Z (2012) The use of graphene-based magnetic nanoparticles as adsorbent for the extraction of triazole fungicides from environmental water. J Sep Sci 35, 2266–2272.
Wegman RCC and Hofster AWM (1979) Chlorophenols in Surface Waters of the Netherlands. Water Res 13, 651–657.
Yadav SK and Cho JW (2013) Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites. Appl surf Sci 266, 360–367.
Yadav SK, Mahapatra SS, Cho JW, and Lee JY (2010) Functionalization of multiwalled carbon nanotubes with poly (styrene-b-(ethylene-co-butylene)-b-styrene) by click coupling. J Phys Chem 114, 11395–11400.
Yadav SK, Yoo HJ, and Cho JW (2013) Click coupled graphene for fabrication of high-performance polymer nanocomposites. J Polym Sci B 51, 39–47.
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Sadanala, K.C., Chung, B.C. Graphene nanoplatelets as a solid phase extraction sorbent for analysis of chlorophenols in water. J Korean Soc Appl Biol Chem 56, 673–678 (2013). https://doi.org/10.1007/s13765-013-3170-1
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DOI: https://doi.org/10.1007/s13765-013-3170-1