Abstract
Renewable energy sources draw attention day by day and studies in this field are increasing. However, in addition to producing energy, the efficient use of the energy produced is of greater importance. Thermoelectric materials come into play at this stage, but the production of materials at the desired level in terms of efficiency is still a problem. In this study, CaMnO3 structure with perovskite structure, which allows the production of many high-tech materials with its variable structure, was produced with acetate starting materials. Specific phase formation by X-ray diffraction analysis of the obtained material, Differential thermal analysis and thermogravimetric analysis endothermic, exothermic, and mass change in the material with temperature, Fourier Transform Infrared Spectroscopy between Ca and Mn bonding, scanning electron microscopy and transmission electron microscopy) single-phase CaMnO3 investigations, Laser flash analysis and Electrical Resistance Measurement Systems (SEM ULvac) analyzes were used to determine the thermoelectric properties. The CaMnO3 structure was obtained as a single phase without the formation of secondary phases with the initial precursors without using different dopants.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Chakroune N, Viau G, Ammar S et al (2005) Synthesis, characterization and magnetic properties of disk-shaped particles of a cobalt alkoxide: CoII(C2H4O2). New J Chem 29:355–361. https://doi.org/10.1039/B411117F
Chang L, Li J, Le Z et al (2021) Perovskite-type CaMnO3 anode material for highly efficient and stable lithium ion storage. J Colloid Interface Sci 584:698–705. https://doi.org/10.1016/j.jcis.2020.04.014
Dwi Yudanto S, Ari Adi W, Imaduddin A et al (2020) Microstructure study of calcium manganese oxide (CaMnO3) as perovskite materials. J Phys Conf Ser 1535:012024. https://doi.org/10.1088/1742-6596/1535/1/012024
Ferreira NM, Neves NR, Ferro MC et al (2019) Growth rate effects on the thermoelectric performance of CaMnO3-based ceramics. J Eur Ceram Soc 39:4184–4188. https://doi.org/10.1016/j.jeurceramsoc.2019.06.011
Galasso F (2012) Perovskite type compounds and high Tc superconductors. JOM 1987 396(39):8–10. https://doi.org/10.1007/BF03258050
Huynh M, Bediako DK, Nocera DG (2014) A functionally stable manganese oxide oxygen evolution catalyst in acid. J Am Chem Soc 136:6002–6010. https://doi.org/10.1021/JA413147E/SUPPL_FILE/JA413147E_SI_001.PDF
Hwang J, Rao RR, Giordano L et al (2017) Perovskites in catalysis and electrocatalysis. Science 358:751–756. https://doi.org/10.1126/SCIENCE.AAM7092
Kabir R, Zhang T, Wang D et al (2014) Improvement in the thermoelectric properties of CaMnO3 perovskites by W doping. J Mater Sci 49:7522–7528. https://doi.org/10.1007/S10853-014-8459-X/FIGURES/9
Karunadasa KSP, Manoratne CH, Pitawala HMTGA, Rajapakse RMG (2019) Thermal decomposition of calcium carbonate (calcite polymorph) as examined by in-situ high-temperature X-ray powder diffraction. J Phys Chem Solids 134:21–28. https://doi.org/10.1016/j.jpcs.2019.05.023
Kim CM, Kim DH, Hong HY, Park K (2020) Thermoelectric properties of La3+ and Ce3+ co-doped CaMnO3 prepared by tape casting. J Eur Ceram Soc 40:735–741. https://doi.org/10.1016/j.jeurceramsoc.2019.08.021
Lan J, Lin Y, Mei A et al (2009) High-temperature electric properties of polycrystalline La-doped CaMnO3 ceramics. J Mater Sci Technol 25:535–538
Liu Y, Zhu D, Chai X, Qing Y (2022) Influence of synergistic effect of Mn valence state and oxygen vacancy concentration on microwave absorbing properties of CaMnO3. Ceram Int 48:9882–9889. https://doi.org/10.1016/j.ceramint.2021.12.191
Macan J, Brleković F, Kralj S et al (2020) Soft chemistry synthesis of CaMnO3 powders and films. Ceram Int 46:18200–18207. https://doi.org/10.1016/j.ceramint.2020.04.142
Mary SB, Francis M, Sathe VG et al (2019) Enhanced thermoelectric property of nanostructured CaMnO3 by sol-gel hydrothermal method. Phys B Condens Matter 575:411707. https://doi.org/10.1016/j.physb.2019.411707
Megaw HD (1946) Crystal structure of double oxides of the perovskite type. Proc Phys Soc 58:133. https://doi.org/10.1088/0959-5309/58/2/301
Mouyane M, Itaalit B, Bernard J et al (2014) Flash combustion synthesis of electron doped-CaMnO3 thermoelectric oxides. Powder Technol 264:71–77. https://doi.org/10.1016/j.powtec.2014.05.022
Nakhowong R (2016) Preparation and characterization of calcium manganese oxide (CaMnO3) nanofibers by electrospinning. Mater Lett 163:222–225. https://doi.org/10.1016/j.matlet.2015.10.081
Namhongsa W, Seetawan T (2022) High electrical power designing the horizontal shaped of bulk Ca3Co4O9/CaMnO3. Phys B Condens Matter 636:413865. https://doi.org/10.1016/j.physb.2022.413865
Nandan KR, Kumar AR (2016) Electrical properties of Ca0.925Ce0.075Mn1−xFexO3 (x = 0.1–0.3) prepared by sol–gel technique. J Mater Sci Mater Electron 27:13179–13191. https://doi.org/10.1007/s10854-016-5464-7
Norman C, Azough F, Freer R (2016) Thermoelectric oxides. In: Nandhakumar I, White NM, Beeby S (eds) Thermoelectric materials and devices. The Royal Society of Chemistry, pp 60–82. https://doi.org/10.1039/9781782624042-00060
Pandey K, Singh D, Gupta SK et al (2018) Improving electron transport in the hybrid perovskite solar cells using CaMnO3-based buffer layer. Nano Energy 45:287–297. https://doi.org/10.1016/j.nanoen.2018.01.009
Park JW, Kwak DH, Yoon SH, Choi SC (2009) Thermoelectric properties of Bi, Nb co-substituted CaMnO3 at high temperature. J Alloys Compd 487:550–555. https://doi.org/10.1016/j.jallcom.2009.08.012
Paszkowicz W, Piętosa J, Woodley SM et al (2010) Lattice parameters and orthorhombic distortion of CaMnO3. Powder Diffr 25:46–59. https://doi.org/10.1154/1.3314256
Popescu MA, Isopescu R, Matei C, et al (2014) Thermal decomposition of calcium carbonate polymorphs precipitated in the presence of ammonia and alkylamines. Adv Powder Technol 25(2):500–507. https://doi.org/10.1016/j.apt.2013.08.003
Seetawan T (2014) Theoretical analysis of the substitutable metal on the thermoelectric performance. Integr Ferroelectr 155:9–14. https://doi.org/10.1080/10584587.2014.905070
Taguchi H, Kugi T, Kato M, Hirota K (2010) Fabrication of (Ca1−xLax)MnO3 ceramics with a high relative density and their power factor. J Am Ceram Soc 93:3009–3011. https://doi.org/10.1111/j.1551-2916.2010.03987.x
Terasaki I, Sasago Y, Uchinokura K (1997) Large thermoelectric power in NaCo2O4 single crystals. Phys Rev B 56:R12685. https://doi.org/10.1103/PhysRevB.56.R12685
Thiel P, Eilertsen J, Populoh S et al (2013) Influence of tungsten substitution and oxygen deficiency on the thermoelectric properties of CaMnO3−δ. J Appl Phys 114:243707. https://doi.org/10.1063/1.4854475
Thongsri P, Seetawan T (2013) Decreased thermal conductivity of CaMnO3 by added-CNTs. Adv Mater Res 770:327–330. https://doi.org/10.4028/www.scientific.net/AMR.770.327
Torres SDO, Thomazini D, Balthazar GP, Gelfuso MV (2020) Microstructural influence on thermoelectric properties of CaMnO3 ceramics. Mater Res. https://doi.org/10.1590/1980-5373-mr-2020-0169
Ullah R, Dutta J (2008) Photocatalytic degradation of organic dyes with manganese-doped ZnO nanoparticles. J Hazard Mater 156:194–200. https://doi.org/10.1016/j.jhazmat.2007.12.033
Wang T, Qian X, Yue D et al (2020) CaMnO3 perovskite nanocrystals for efficient peroxydisulfate activation. Chem Eng J 398:125638. https://doi.org/10.1016/j.cej.2020.125638
Xu G (2004) High-temperature transport properties of Nb and Ta substituted CaMnO3 system. Solid State Ion 171:147–151. https://doi.org/10.1016/S0167-2738(03)00108-5
Yudanto SD, Ari Adi W, Imaduddin A (2018) Characterization and studies on AC conductivity of CaMnO3 material. J Phys Conf Ser 1091:012023. https://doi.org/10.1088/1742-6596/1091/1/012023
Zhan B, Lan J, Liu Y et al (2014) High temperature thermoelectric properties of Dy-doped CaMnO3 ceramics. J Mater Sci Technol 30:821–825. https://doi.org/10.1016/j.jmst.2014.01.002
Zhang L, Liu GH, Li YB et al (2008) Simple chemical solution deposition of Ca3Co4O9 films directly on Si substrates. Mater Lett 62:1322–1324. https://doi.org/10.1016/J.MATLET.2007.08.037
Zhu Y-H, Su W-B, Liu J et al (2015) Effects of Dy and Yb co-doping on thermoelectric properties of CaMnO3 ceramics. Ceram Int 41:1535–1539. https://doi.org/10.1016/j.ceramint.2014.09.089
Acknowledgments
This manuscript is produced from PhD Thesis titled “Production of thermoelectric films by ultrasonic spray pyrolysis method” studied by Fuat Çelik in 2021.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no conflicts of interest.
Additional information
Editorial responsibility: Samareh Mirkia.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Çelik, F., Coşkun, N.D., Uz, V. et al. Acetate based CaMnO3 thermoelectric material synthesis: effects on efficiency, phase formation, and microstructural change. Int. J. Environ. Sci. Technol. 20, 13083–13090 (2023). https://doi.org/10.1007/s13762-023-05080-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-023-05080-8