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Sustainability evaluation of H2 production from sheep tallow by combining Emergy and environmental life cycle assessment

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Abstract

In the aim to reach low or net zero emissions energy systems by 2050, the transition toward more sustainable energy carriers seems crucial. H2 is gradually gaining attention as a promising alternative solution for future energy supply. The main purpose of this study is to investigate the sustainability of H2 generated from sheep tallow. To this end, a combination of life cycle assessment and Emergy analysis was applied. Different impact categories, following ReCiPe method, cumulative energy demand were calculated for the evaluation of the system environmental performances. Emergy comprehensively evaluated H2 production sustainability, through a set of indicators such as transformity, environmental loading ratio, percentage of renewability, Emergy yield ratio, Emergy investment ratio and Emergy sustainability index. The life cycle assessment results show that the thermal energy is the main contributor to the selected environmental impact categories. The net energy ratio of the system is approximately 2.5. Therefore, the H2 system presents a net energy gain. Emergy indices indicate that H2 transformity is higher than that of many other energy carriers. Also, the environmental loading ratio calculated is 17.26, indicating that the activities of the process increase the pressure on the environment. The environmental sustainability index is estimated to be 0.06 which shows that the investigated system is unsustainable from an emergetic point of view.

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Availability of data

The data that support finding of this study are available in the supplementary material attached file.

Abbreviations

%R :

Percentage of renewability

CED:

Cumulative energy demand

COP:

Conference of Parties

COPROX:

CO preferential oxidation reactor

E :

Energy of the product

EIR:

Emergy investment ratio

ELR:

Environmental loading ratio

ESI:

Emergy sustainability index

EYR:

Emergy yield ratio

F :

Flows from human activity

FDP:

Fossil depletion potential

FEP:

Fresh water ecotoxicity potential

FU:

Functional unit

GHG:

Greenhouse gas

GWP:

Global worming potential

HTP:

Human toxicity potential

HTS:

High-temperature shift reactor

I :

Local inputs

LCA:

Life cycle assessment

LCI:

Life cycle inventory

LCIA:

Life cycle impact assessment

LHV:

Low heating value

LTS:

Low-temperature shift reactor

M :

Materials

MEP:

Marine ecotoxicity potential

N :

Non-renewable

NER:

Net energy ratio

NRE:

Non-renewable energy

ODP:

Ozone depletion potential

Q :

Heat transferred

R :

Renewable

S :

Services

SB:

System boundaries

sej:

Solar emjoules

SG:

Synthesis gas

SR:

Steam reforming

ST:

Sheep tallow

TA:

Terrestrial acidification

TEP:

Terrestrial ecotoxicity potential

WDP:

Water depletion potential

WGS:

Water gas shift

Y :

Emergy inflows to the process

τ :

Transformity

η :

Thermal efficiency

α :

Renewability ratio

R :

Renewable

N :

Non-renewable

References

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Funding

Authors did not receive any funding support from any organization for the submitted work.

Author information

Authors and Affiliations

Authors

Contributions

Nahla El Faleh was involved in the conceptualization, methodology, software, validation, analysis and/or interpretation of data and writing the original draft. Khaoula Ben Hnich contributed to the conceptualization, methodology, software, validation, analysis and/or interpretation of data and writing the original draft. Zouhour Khila helped in the methodology, validation, analysis and/or interpretation of data, review & editing and supervision. Noureddine Hajjaji contributed to the methodology, validation, analysis and/or interpretation of data, review & editing and supervision.

Corresponding author

Correspondence to K. Ben Hnich.

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Conflict of interest

The authors declare that they have no conflicts of interest.

Consent to participate for publication

Informed consent was obtained from all individual participants included in the study.

Additional information

Editorial responsibility: M. Shabani.

Appendices

Appendix A

See Tables

Table 4 Aspen Plus™ models

4 and

Table 5 Equipment specifications and operating conditions

5.

Appendix B

See Table

Table 6 Simulation results summary

6.

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El Faleh, N., Ben Hnich, K., Khila, Z. et al. Sustainability evaluation of H2 production from sheep tallow by combining Emergy and environmental life cycle assessment. Int. J. Environ. Sci. Technol. 20, 4057–4072 (2023). https://doi.org/10.1007/s13762-022-04271-z

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  • DOI: https://doi.org/10.1007/s13762-022-04271-z

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