Abstract
In this research work, the synthesis of well-ordered mesoporous structure KIT-6 silica-supported vanadyl hydrogen phosphate hemihydrate (VHP/KIT-6) catalysts possessing varying surface area was carried out, followed by being utilized in the dehydration of sucrose to 5-hydroxymethylfurfural (5-HMF) as a solid acid catalyst. The fabrication of two different VHP/KIT-6 catalysts was conducted using the impregnation approach through V2O5 reduction in alcoholic media. Then, the catalytic behavior presented by the prepared VHP/KIT-6 samples was compared with unsupported VHP and unsupported vanadyl pyrophosphate (VPP), which was prepared through the calcination of VHP precursor at 400 °C for 24 h. The prepared catalysts were characterized by different analyses, including ICP-OES, BET, XRD, NH3-TPD analysis, FT-IR spectroscopy, as well as SEM and TEM techniques. Furthermore, important parameters, including the catalyst type and weight, sucrose amount, time, temperature, and the type of solvent on sucrose dehydration, were also studied. It was observed that the highest catalytic activity in the dehydration reaction (5-HMF yield: 67%, sucrose conversion: > 94%) could be provided by the catalyst possessing the highest surface area. Moreover, the catalyst reusability was examined for consecutive four times, based on which no considerable change in the catalytic activity was observed.
Similar content being viewed by others
References
L.T. Mika, E. Csefalvay, A. Nemeth, Chem. Rev. 118, 505–613 (2017)
A.N. Chermahini, M. Assar, J. Iran. Chem. Soc. 16, 2045–2053 (2019)
Z. Babaei, A.N. Chermahini, M. Dinari, M. Saraji, A. Shahvar, Sustain. Energ. Fuels 3, 1024–1032 (2019)
A. Maleki, A.A. Jafari, S. Yousefi, Carbohydr. Polym. 175, 409–416 (2017)
A. Maleki, H. Movahed, P. Ravaghi, Carbohydr. Polym. 156, 259–267 (2017)
A. Maleki, V. Eskandarpour, J. Iran. Chem. Soc. 16, 1459–1472 (2019)
J.J. Bozell, G.R. Petersen, Green Chem. 12, 539–554 (2010)
U.M. Shapla, M. Solayman, N. Alam, M.I. Khalil, S.H. Gan, Chem. Cent. J. 12, 35–53 (2018)
M. Murkovic, M.A. Bornik, Mol. Nutr. Food Res. 51, 390–394 (2007)
Z. Li, Y. Yuan, Y. Yao, X. Wei, T. Yue, J. Meng, Food Control 102, 56–68 (2019)
A.F. Sousa, C. Vilela, A.C. Fonseca, M. Matos, C.S. Freire, G.J.M. Gruter, J.F. Coelho, A.J. Silvestre, Polym. Chem. 6, 5961–5983 (2015)
A. Jain, S.C. Jonnalagadda, K.V. Ramanujachary, A. Mugweru, Catal. Commun. 58, 179–182 (2015)
Z. Zhang, G.W. Huber, Chem. Soc. Rev. 47, 1351–1390 (2018)
F.J. Santiago-Medina, A. Pizzi, S. Abdalla, J. Renew. Mater. 5, 1–13 (2017). https://doi.org/10.7569/JRM.2017.634166
Z. Yuan, Y. Zhang, C. Xu, RSC adv. 4, 31829–31835 (2014)
Z. Zhao, S. Sun, D. Wu, M. Zhang, C. Huang, K. Umemura, Q. Yong, Polymers 11, 1909–1924 (2019)
S.M. Basha, J. Agr. Food Chem. 40, 780–783 (1992)
A. Jain, A.M. Shore, S.C. Jonnalagadda, K.V. Ramanujachary, A. Mugweru, Appl. Catal. A Gen. 489, 72–76 (2015)
S. Marullo, C. Rizzo, A. Meli, F. D’Anna, A.C.S. Sustain, Chem. Eng. 7, 5818–5826 (2019)
X. Li, Y. Wang, X. Xie, C. Huang, S. Yang, RSC adv. 9, 9041–9048 (2019)
T. Deng, X. Cui, Y. Qi, Y. Wang, X. Hou, Y. Zhu, ChemComm 48, 5494–5496 (2012)
V. Choudhary, S.H. Mushrif, C. Ho, A. Anderko, V. Nikolakis, N.S. Marinkovic, A.I. Frenkel, S.I. Sandler, D.G. Vlachos, J. Am. Chem. Soc. 135, 3997–4006 (2013)
J.Y.G. Chan, Y. Zhang, Chemsuschem 2, 731–734 (2009)
W. Kunz, K. Häckl, Chem. Phys. Lett. 661, 6–12 (2016)
M. Rezaei, A.N. Chermahini, H.A. Dabbagh, Chem. Eng. J. 314, 515–525 (2017)
M. Rezaei, A.N. Chermahini, H.A. Dabbagh, J. Environ. Chem. Eng. 5, 3529–3539 (2017)
A. Moslemi, A.N. Chermahini, J.N. Sarpiri, S. Rezaei, M. Barati, J. Taiwan Inst. Chem. E. 97, 237–246 (2019)
K. Parida, G.C. Behera, Catal. Lett. 140, 197–204 (2010)
F. Wang, J.L. Dubois, W. Ueda, Appl. Catal. A Gen. 376, 25–32 (2010)
N.P. Rajan, G.S. Rao, V. Pavankumar, K.V. Chary, Catal Sci. Technol. 4, 81–92 (2014)
C. Tian, X. Zhu, S.H. Chai, Z. Wu, A. Binder, S. Brown, L. Li, H. Luo, Y. Guo, S. Dai, Chemsuschem 7, 1703–1709 (2014)
C. Carlini, P. Patrono, A.M.R. Galletti, G. Sbrana, Appl. Catal. A Gen. 275, 111–118 (2004)
G.C. Behera, K. Parida, Catal Sci. Technol. 3, 3278–3285 (2013)
J.N. Sarpiri, A.N. Chermahini, M. Saraji, A. Shahvar, Renew. Energy 164, 11–22 (2020)
I. Sádaba, S. Lima, A.A. Valente, M.L. Granados, Carbohydr. Res. 346, 2785–2791 (2011)
F. Wang, J.L. Dubois, W. Ueda, J. Catal. 268, 260–267 (2009)
Y. Kamiya, H. Nishiyama, M. Yashiro, A. Satsuma, T. Hattori, J. Jpn. Pet. Inst. 46, 62–68 (2003)
X. Feng, Y. Yao, Q. Su, L. Zhao, W. Jiang, W. Ji, C.T. Au, Appl. Catal. B- Environ. 164, 31–39 (2015)
E. Doustkhah, J. Lin, S. Rostamnia, C. Len, R. Luque, X. Luo, Y. Bando, K.C.W. Wu, J. Kim, Y. Yamauchi, Chem. Eur. J. 25, 1614–1635 (2019)
S. Rostamnia, E. Doustkhah, RSC Adv. 4, 28238–28248 (2014)
B. Karimi, M. Vafaeezadeh, ChemComm 48, 3327–3329 (2012)
A. Maleki, Z. Hajizadeh, R. Firouzi-Haji, Microporous Mesoporous Mater. 259, 46–53 (2018)
A. Maleki, A.A. Jafari, S. Yousefi, J. Iran. Chem. Soc. 14, 1801–1813 (2017)
Z. Mohammadbagheri, A.N. Chermahini, J. Ind. Eng. Chem. 62, 401–408 (2018)
M.M. Tabrizi, A.N. Chermahini, Z. Mohammadbagheri, J. Environ. Chem. Eng. 7, 103420–103426 (2019)
B. Karimi, S. Abedi, J.H. Clark, V. Budarin, Angew. Chem. Int. Ed. 45, 4776–4779 (2006)
L. Qian, Y. Ren, T. Liu, D. Pan, H. Wang, G. Chen, Chem. Eng. J. 213, 186–194 (2012)
B. Dou, Q. Hu, J. Li, S. Qiao, Z. Hao, J. Hazard. Mater. 186, 1615–1624 (2011)
A. Boulaoued, I. Fechete, B. Donnio, M. Bernard, P. Turek, F. Garin, Microporous Mesoporous Mater. 155, 131–142 (2012)
L. Kumaresan, A. Prabhu, M. Palanichamy, V. Murugesan, J. Taiwan Inst. Chem. E. 41, 670–675 (2010)
M. Falahati, L. Ma’mani, A.A. Saboury, A. Shafiee, A. Foroumadi, A.R. Badiei, Biochim. Biophys. Acta 1814, 1195–1202 (2011)
G. Karthikeyan, A. Pandurangan, J. Mol. Catal. A Chem. 58, 361–362 (2012)
F. Kleitz, S.H. Choi, R. Ryoo, Chem Comm, 2136–2137 (2003)
W. Ji, L. Xu, X. Wang, Z. Hu, Q. Yan, Y. Chen, Catal. Today 74, 101–110 (2002)
B. Hu, H. Liu, K. Tao, C. Xiong, S. Zhou, J. Phys. Chem. C 117, 26385–26395 (2013)
N. Mizuno, H. Hatayama, M. Misono, Chem. Mater. 9, 2697–2698 (1997)
D.B. Asay, S.H. Kim, J. Phys. Chem. B 109, 16760–16763 (2005)
Z. Luan, M. Hartmann, D. Zhao, W. Zhou, L. Kevan, Chem. Mater. 11, 1621–1627 (1999)
T. Okuhara, N. Ryumon, N. Yamamoto, N. Hiyoshi, Stud. Surf. Sci. Catal. 145, 271–274 (2003)
G. Dong, L. Zhang, J. Mater. Chem. 22, 1160–1166 (2012)
C.J. Kiely, A. Burrows, S. Sajip, G.J. Hutchings, M.T. Sananes, A. Tuel, J.C. Volta, J. Catal. 162, 31–47 (1996)
H. Jadhav, C.M. Pedersen, T. Sølling, M. Bols, Chemsuschem 4, 1049–1051 (2011)
H. Zhao, J.E. Holladay, H. Brown, Z.C. Zhang, Science 316, 1597–1600 (2007)
Y.J. Pagan-Torres, T. Wang, J.M.R. Gallo, B.H. Shanks, J.A. Dumesic, Acs Catal. 2, 930–934 (2012)
F. Salak Asghari, H. Yoshida, Ind. Eng. Chem. Res. 45, 2163–2173 (2006)
A.S. Amarasekara, L.D. Williams, C.C. Ebede, Carbohydr. Res. 343, 3021–3024 (2008)
F. Delbecq, C. Len, Molecules 23, 1973–1989 (2018)
B. Guo, L. Ye, G. Tang, L. Zhang, B. Yue, S.C.E. Tsang, H. He, Chin. J. Chem. 35, 1529–1539 (2017)
J. Pérez-Maqueda, I. Arenas-Ligioiz, Ó. López, J.G. Fernández-Bolaños, Chem. Eng. Sci. 109, 244–250 (2014)
P.V. Rathod, R.B. Mujmule, W.J. Chung, A.R. Jadhav, H. Kim, Catal. Lett. 149, 672–678 (2019)
B. Zheng, Z. Fang, J. Cheng, Y. Jiang, Z. Naturforsch, B 65, 168–172 (2010)
Acknowledgments
The authors would like to thank the financial supports from the Isfahan University of Technology for this work (Research Council Grant).
Author information
Authors and Affiliations
Corresponding author
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Najafi Sarpiri, J., Najafi Chermahini, A., Saraji, M. et al. Application of vanadyl hydrogen phosphate/KIT-6 composites as a catalyst for dehydration of sucrose. J IRAN CHEM SOC 18, 2291–2302 (2021). https://doi.org/10.1007/s13738-021-02191-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13738-021-02191-2