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The immobilized Ni(II) species on thiourea functionalized copper ferrite: a reusable nanocatalyst for synthesis of biscoumarins under solvent-free conditions

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Abstract

In this study, nanoparticles of CuFe2O4@SiO2@PTMS@Tu@Ni(II) as the reusable magnetic catalyst were prepared. Synthesis of the Ni(II)–CuFe2O4 system was carried out through a five-step procedure including the preparation of CuFe2O4 as the prime magnetic core, layering of silica, 3-chloropropyltrimethoxysilane and thiourea and finally the immobilization of Ni(OAc)2·4H2O. The prepared nanocomposite system was then characterized using FT-IR, SEM, EDX, XRD, VSM, ICP-OES and TGA/DSC analyses. Catalytic activity of CuFe2O4@SiO2@PTMS@Tu@Ni(II) was further studied toward synthesis of biscoumarin materials by a domino Knoevenagel–Michael reaction of 4-hydroxycoumarin with aromatic and heterocyclic aldehydes under solvent-free conditions (70 °C) within 15–30 min. The applied nanocomposite system was easily and magnetically separated from the reaction mixture and reused for six consecutive cycles without the significant loss of its catalytic activity.

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Acknowledgment

The authors gratefully appreciated the financial support of this work by the research council of Urmia University.

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  1. Faculty of Chemistry, Urmia University, Urmia, 5756151818, Iran

    Behzad Zeynizadeh, Morteza Hasanpour Galehban & Zahra Shokri

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  1. Behzad Zeynizadeh
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  2. Morteza Hasanpour Galehban
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Zeynizadeh, B., Hasanpour Galehban, M. & Shokri, Z. The immobilized Ni(II) species on thiourea functionalized copper ferrite: a reusable nanocatalyst for synthesis of biscoumarins under solvent-free conditions. J IRAN CHEM SOC 17, 1493–1505 (2020). https://doi.org/10.1007/s13738-020-01878-2

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