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NH3(CH2)5NH3BiCl5: an efficient and recyclable catalyst for the synthesis of benzoxazole, benzimidazole and benzothiazole heterocycles

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Abstract

In this work, the condensation of aromatic aldehydes with different two-substituted aniline catalyzed by NH3(CH2)5NH3BiCl5 as heterogeneous and recyclable catalyst was reported. It was demonstrated that NH3(CH2)5NH3BiCl5 can act as an efficient and active catalyst and is reusable for six runs without a significant loss of their catalytic activity. Simple preparation of the catalyst, high catalytic activity and good reusability are noteworthy advantages of this catalytic system in the synthesis of benzoxazole, benzimidazole and benzothiazole heterocycles at room temperature under solvent-free conditions.

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Authors and Affiliations

  1. Laboratoire de Chimie Organique, Organométallique et Théorique, Faculté des Sciences, Université Ibn Tofaïl, BP 133, 14000, Kenitra, Morocco

    Zakaria Benzekri, Sara Sibous, Houda Serrar, Said Boukhris & Abdelaziz Souizi

  2. Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Ibn Tofail, BP 133, 14000, Kenitra, Morocco

    Ali Ouasri & Ali Rhandour

  3. Centre Régional des Métiers de l’Education et de la Formation, Madinat Al Irfane, Souissi, BP 6210, Rabat, Morocco

    Ali Ouasri

Authors
  1. Zakaria Benzekri
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  2. Sara Sibous
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  3. Houda Serrar
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  4. Ali Ouasri
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  5. Said Boukhris
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  6. Ali Rhandour
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  7. Abdelaziz Souizi
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Correspondence to Said Boukhris.

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Benzekri, Z., Sibous, S., Serrar, H. et al. NH3(CH2)5NH3BiCl5: an efficient and recyclable catalyst for the synthesis of benzoxazole, benzimidazole and benzothiazole heterocycles. J IRAN CHEM SOC 15, 2781–2787 (2018). https://doi.org/10.1007/s13738-018-1465-1

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  • DOI: https://doi.org/10.1007/s13738-018-1465-1

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