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Irreversible replacement of sodium with thallium in sodium coordination polymer nanostructures by solid-state mechanochemical cation exchange process

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Abstract

Solid-state conversion of NaI coordination polymer nanostructure, synthesized by sonochemical procedure, to TlI coordination polymer has been observed upon liquid-assisted mechanochemical reaction of [Na2TP] n (1) (H2TP = terephthalic acid), with TlNO3. During this conversion, ion exchange process of Na(I) with Tl(I) was occurred and [Tl2TP] n (2) was synthesized. The X-ray diffraction (XRD) pattern of 2 after mechanochemical reaction of it with NaNO3 indicated that this transformation is irreversible. Compounds 1 and 2 were characterized by IR spectroscopy, X-ray powder diffraction (XRD), elemental analysis, thermogravimetric and differential thermal analyses and scanning electron microscopy.

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References

  1. M. Mohammadi, A. Morsali, Mat. Letter. 63, 2349 (2009)

    Article  CAS  Google Scholar 

  2. F. Yuan, L. Zhang, H.M. Hu, Ch. Bai, G. Xue, J. Mol. Struct. 1128, 385 (2017)

    Article  CAS  Google Scholar 

  3. W. Chen, F. Liu, D. Xu, K. Matsumoto, S. Kishi, M. Kato, Inorg. Chem. 45, 5552 (2006)

    Article  CAS  Google Scholar 

  4. K. Liu, H. You, G. Jia, Y. Zheng, Y. Huang, Y. Song, M. Yang, L. Zhang, H. Zhang, Cryst. Growth Des. 10, 790 (2010)

    Article  CAS  Google Scholar 

  5. O.K. Farha, I. Eryazici, N. Cheon Jeong, B.G. Hauser, ChE Wilmer, A.A. Sarjeant, R.Q. Snurr, S.T. Nguyen, A.O. Yazaydin, J.T. Hupp, J. Am. Chem. Soc. 134, 15016 (2012)

    Article  CAS  Google Scholar 

  6. W. Pei, Zh Han, J. Xie, Y. Zou, X.M. Ren, J. Chem. Crystallogr. 42, 1007 (2012)

    Article  CAS  Google Scholar 

  7. M. Zhao, Sh Chen, Y. Huang, Y. Dan, J. Mol. Struct. 1128, 123 (2017)

    Article  CAS  Google Scholar 

  8. K. Akhbari, S. Beheshti, A. Morsali, V.-T. Yilmaz, O. Büyükgüngӧr, J. Mol. Struct. 1074, 279 (2014)

    Article  CAS  Google Scholar 

  9. A.-Y. Robin, K.-M. Fromm, Coord. Chem. Rev. 250, 2127 (2006)

    Article  CAS  Google Scholar 

  10. D. Marcano, N. Gerasimchuk, V. Nemykin, S. Silchenko, Cryst. Growth Des. 12, 2877 (2012)

    Article  CAS  Google Scholar 

  11. K. Akhbari, A. Morsali, Inorg. Chem. Commun. 55, 11 (2015)

    Article  CAS  Google Scholar 

  12. K. Akhbari, A. Morsali, CrystEngComm 14, 1618 (2012)

    Article  CAS  Google Scholar 

  13. K. Akhbari, A. Morsali, Coord. Chem. Rev. 254, 1977 (2010)

    Article  CAS  Google Scholar 

  14. A. Askarinejad, A. Morsali, Inorg. Chem. Commun. 9, 143 (2009)

    Article  Google Scholar 

  15. L. Aboutorabi, A. Morsali, Ultrason. Sonochem. 32, 31 (2016)

    Article  CAS  Google Scholar 

  16. K. Akhbari, A. Morsali, CrystEngComm 15, 8915 (2013)

    Article  CAS  Google Scholar 

  17. G.K. Kole, J.J. Vittal, Chem. Soc. Rev. 42, 1755 (2013)

    Article  CAS  Google Scholar 

  18. M. Moeinian, A. Akhbari, S. Kawata, R. Ishikawata, RSC Adv. 6, 82447 (2016)

    Article  CAS  Google Scholar 

  19. L. Aboutorabi, A. Morsali, Coord. Chem. Rev. 310, 116 (2016)

    Article  CAS  Google Scholar 

  20. V. Cabras, M. Pilloni, A. Scano, R. Lai, M.C. Aragoni, S.J. Coles, G. Ennas, Eur. J. Inorg. Chem. 2017, 1908 (2017)

    Article  CAS  Google Scholar 

  21. M. Moeinian, A. Akhbari, J. Boonmak, S. Youngme, Polyhedron 118, 6 (2016)

    Article  CAS  Google Scholar 

  22. V. Safarifard, A. Morsali, Inorg. Chim. Acta 405, 203 (2013)

    Article  CAS  Google Scholar 

  23. V. Štrukil, L. Fábián, D.G. Reid, M.J. Duer, G.J. Jackson, M. Eckert-Maksič, T. Friščič, Chem. Commun. 46, 9191 (2010)

    Article  Google Scholar 

  24. J.A. Kaduk, Acta Cryst. 56, 474 (2000)

    Article  Google Scholar 

  25. F. Macrae, P.R. Edgington, P. McCabe, E. Pidcock, G.P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Cryst. 39, 453 (2006)

    Article  CAS  Google Scholar 

  26. S.H. Dale, M.R.J. Elsegood, Acta Crystallogr. Sect. C. 59, 475 (2003)

    Article  Google Scholar 

  27. N.N. Greenwood, A. Earnshaw, (Pergamon Press, Oxford, 1986), p. 235

  28. R. Foster, Paul Elek, (eds) (Scientific Books Ltd., London, 1973)

  29. M.C. Aragoni, M. Arca, F. Demartin, F.A. Devillanova, F. Isaia, A. Garau, V. Lippolis, F. Jalali, U. Papke, M. Shamsipur, L. Tei, A. Yari, G. Verani, Inorg. Chem. 41, 6623 (2002)

    Article  CAS  Google Scholar 

  30. V. Russell, M.L. Scudder, I.G. Dance, J. Chem. Soc., Dalton Trans. 6, 789 (2001)

    Article  Google Scholar 

  31. C. Janiak, J. Chem. Soc., Dalton Trans. 21, 3885 (2000)

    Article  Google Scholar 

  32. C. Seward, J. Chan, D. Song, S.-N. Wang, Inorg. Chem. 42, 1112 (2003)

    Article  CAS  Google Scholar 

  33. A. Bondi, J. Phys. Chem. 68, 441 (1964)

    Article  CAS  Google Scholar 

  34. E. Mirzadeh, K. Akhbari, J. White, Appl. Organomet. Chem. e4313 (2018). https://doi.org/10.1002/aoc.4313

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Acknowledgements

The authors would like to acknowledge the financial support of University of Tehran for this research under Grant Number 01/1/389845.

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Correspondence to Kamran Akhbari.

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Akhbari, K., Karami, S., Phuruangrat, A. et al. Irreversible replacement of sodium with thallium in sodium coordination polymer nanostructures by solid-state mechanochemical cation exchange process. J IRAN CHEM SOC 15, 1327–1335 (2018). https://doi.org/10.1007/s13738-018-1331-1

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  • DOI: https://doi.org/10.1007/s13738-018-1331-1

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