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Ultrasonic assistance syntheses of new nano-sized lead(II) coordination polymers: motifs for PbO preparation

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Abstract

Nanoparticles of two new coordination polymers, [Pb(5,5′-dm-2,2′-bpy)Cl2] n (1) and [Pb(5,5′-dm-2,2′-bpy)Br2] n (2), {5,5′-dm-2,2′-bpy = 5,5′-dimethyl-2,2′-bipyridine}, have been synthesized by ultrasonic assistance at different concentrations and characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Metal oxide nanoparticles were prepared from thermal decomposition of compounds 1 and 2 at 600 °C under air atmosphere. Scanning electron microscopy images of the residue which are obtained from calcination of compounds 1, 2 show the formation of lead(II) oxide nanoparticles with an average diameter of about 80 and 90 nm for compounds 1 and 2, respectively.

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Acknowledgements

Support of this investigation by Tarbiat Modares University and Payame Noor University are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P. O. Box 14155-4838, Tehran, Islamic Republic of Iran

    Lida Hashemi & Ali Morsali

  2. Department of Chemistry, Payame Noor University, P. O. Box 19395-3697, Tehran, Iran

    Farzin Marandi

  3. Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, 04103, Leipzig, Germany

    Harald Krautscheid

Authors
  1. Lida Hashemi
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  2. Farzin Marandi
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  3. Ali Morsali
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  4. Harald Krautscheid
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Correspondence to Farzin Marandi or Ali Morsali.

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Hashemi, L., Marandi, F., Morsali, A. et al. Ultrasonic assistance syntheses of new nano-sized lead(II) coordination polymers: motifs for PbO preparation. J IRAN CHEM SOC 14, 1271–1279 (2017). https://doi.org/10.1007/s13738-017-1078-0

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  • DOI: https://doi.org/10.1007/s13738-017-1078-0

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