Skip to main content
SpringerLink
Log in

Mn(II) and VO(IV) Schiff base complexes encapsulated in nanocavities of zeolite-Y: catalytic activity toward oxidation of alkenes and reduction of aldehydes

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

Oxovanadium(IV) and manganese(II) complexes of two Schiff base ligands, bis(2,4-dihydroxyacetophenone)-1,2-propandiimine (H2L1) and bis(2,4-dihydroxyacetophenone)-ethylenediimine (H2L2) were synthesized and characterized. The encapsulation of these complexes in the nanocavities of zeolite-Y was achieved by a flexible ligand method. The prepared heterogeneous catalysts have been characterized by FTIR, NMR and atomic absorption spectroscopy, X-ray diffraction patterns, scanning electron microscopy and BET. The catalytic activities of the encapsulated complexes were studied in the oxidation of alkenes with H2O2 and the reduction of aldehydes with NaBH4. In most cases, the manganese (II) complexes (MnL1-Y, MnL2-Y) showed better activity than the oxovanadium (IV) complexes (VOL1-Y, VOL2-Y) in both oxidation of alkenes and reduction of aldehydes. The catalytic activity of the recovered catalysts was compared with the fresh ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. D.J. Xuereb, R. Raja, Catal. Sci. Technol. 1, 517 (2011)

    Article  CAS  Google Scholar 

  2. M.L. Cano, A. Corma, V. Fornes, H. García, M.A. Miranda, C. Baerlocher, C. Lengauer, J. Am. Chem. Soc. 118, 11006 (1996)

    Article  CAS  Google Scholar 

  3. R.J. Corrêa, G.C. Salomao, M.H.N. Olsen, L.C. Filho, V. Drago, C. Fernandes, O.A.C. Antunes, Appl. Catal. A 336, 35 (2008)

    Article  Google Scholar 

  4. J. Poltowicz, K. Pamin, E. Tabor, J. Haber, A. Adamski, Z. Sojka, Appl. Catal. A 299, 235 (2006)

    Article  CAS  Google Scholar 

  5. S. Rayati, F. Salehi, J. Iran. Chem. Soc. 12, 309 (2015)

    Article  CAS  Google Scholar 

  6. G. Reddy, S. Balasubramanian, K. Chennakesavulu, J. Mater. Chem. A. 2, 15598 (2014)

    Article  Google Scholar 

  7. M. Salavati-Niasari, M. Shakouri-Arani, F. Davar, Microporous Mesoporous Mater. 116, 77 (2008)

    Article  CAS  Google Scholar 

  8. C.K. Modi, B.G. Gade, J.A. Chudasama, D.K. Parmar, H.D. Nakum, A.L. Patel, Acta Part A Mol. Biomol. Spectrosc. 140, 174 (2015)

    Article  CAS  Google Scholar 

  9. G.J. Kim, D.W. Park, Y.S. Tak, Catal. Lett. 65, 127 (2000)

    Article  CAS  Google Scholar 

  10. T. Yamada, T. Nagata, K.D. Sugi, K. Yorozu, T. Ikeno, Y. Ohtsuka, D. Miyazaki, T. Mukaiyama, Chem. Eur. J. 9, 4485 (2003)

    Article  CAS  Google Scholar 

  11. G.J. Kim, J.H. Shin, Catal. Lett. 63, 205 (1999)

    Article  CAS  Google Scholar 

  12. W. Kahlen, H.H. Wagner, W.F. Holderich, Catal. Lett. 54, 85 (1998)

    Article  CAS  Google Scholar 

  13. W. Kahlen, A. Johnson, W.F. Holderich, Stud. Surf. Sci. Catal. 108, 469 (1997)

    Article  CAS  Google Scholar 

  14. S. Rayati, P. Abdolalian, C. R. Chimie. 16, 814 (2013)

    Article  CAS  Google Scholar 

  15. M. Navidi, B. Movassagh, S. Rayati, Appl. Catal. A Gen. 452, 24 (2013)

    Article  CAS  Google Scholar 

  16. S. Rayati, N. Rafiee, A. Wojtczak, Inorg. Chimica Acta 368, 27 (2012)

    Article  Google Scholar 

  17. C.K. Modi, D.H. Jani, J. Therm. Anal. Calorim. 102, 1001 (2010)

    Article  CAS  Google Scholar 

  18. S.M. Emam, F.A.E. Saied, S.A.E. Enein, H.A.E. Shater, Spectrochim. Acta Part A 72, 291 (2009)

    Article  Google Scholar 

  19. W.H. Quayle, J.H. Lunsford, Inorg. Chem. 21, 97 (1982)

    Article  CAS  Google Scholar 

  20. W.H. Quayle, G. Peeters, G.L. DeRoy, E.F. Vansant, J.H. Lunsford, Inorg. Chem. 21, 2226 (1982)

    Article  CAS  Google Scholar 

  21. H.S. Abbo, S.J.J. Titinchi, Top. Catal. 53, 254 (2010)

    Article  CAS  Google Scholar 

  22. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985)

    Article  CAS  Google Scholar 

  23. K.J. Balkus Jr., A.G. Gabrielov, J. Incl. Phenom. Mol. Recognit. Chem. 21, 159 (1995)

    CAS  Google Scholar 

  24. A. Corma, P. Esteve, A. Martinez, J. Catal. 161, 11 (1996)

    Article  CAS  Google Scholar 

  25. R.A. Sheldon, J.K. Kochi, Metal-Catalyzed Oxidation of Organic Compounds (Academic Press, New York, 1981)

  26. A. Ghaemi, S. Rayati, S. Zakavi, N. Safari, Appl. Catal. A Gen. 353, 154 (2009)

    Article  CAS  Google Scholar 

  27. S. Rayati, S. Zakavi, V. Noroozi, S.H. Motlagh, Catal. Commun. 10, 221 (2008)

    Article  CAS  Google Scholar 

  28. S. Rayati, S. Zakavi, S.H. Motlagh, V. Noroozi, M. Razmjoo, A. Wojtczak, A. Kozakiewicz, Polyhedron 27, 2285 (2008)

    Article  CAS  Google Scholar 

  29. A.D. Adler, F.R. Longo, F. Kampas, J. Kim, J. Inorg. Nucl. Chem. 32, 2443 (1970)

    Article  CAS  Google Scholar 

  30. K. Tong, K. Wong, T. Chan, Org. Lett. 5, 3423 (2003)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work has been supported by the Iran National Science Foundation (INSF) (Grant No. 88001216).

Author information

Authors and Affiliations

  1. Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, 15418, Iran

    Saeed Rayati, Saeedeh Shokoohi & Elaheh Bohloulbandi

Authors
  1. Saeed Rayati
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Saeedeh Shokoohi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Elaheh Bohloulbandi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Saeed Rayati.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rayati, S., Shokoohi, S. & Bohloulbandi, E. Mn(II) and VO(IV) Schiff base complexes encapsulated in nanocavities of zeolite-Y: catalytic activity toward oxidation of alkenes and reduction of aldehydes. J IRAN CHEM SOC 13, 1983–1991 (2016). https://doi.org/10.1007/s13738-016-0915-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-016-0915-x

Keywords

Search

Navigation