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Synthesis, characterization and colour determination using CIELAB colour space of stilbene dyes

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Abstract

The synthesis of six new symmetrical disazo direct dyes containing 4,4′-diaminostilbene-2,2′-disulphonic acid as middle component and N-(2-chlorophenyl)-2-hydroxybenzamide, N-(3-chlorophenyl)-2-hydroxybenzamide, N-(4-chlorophenyl)-2-hydroxybenzamide, N-(2-bromophenyl)-2-hydroxybenzamide, N-(3-bromophenyl)-2-hydroxybenzamide, N-(4-bromophenyl)-2-hydroxybenzamide as coupling components is presented. The synthesized dyes were analyzed by thin layer chromatography, electronic spectra and HPLC technique. Their structures were elucidated by FT/IR and 13C-NMR spectroscopy. The CIELAB (1976) colour space was used in all the colour measurements for the six disazo stilbene dyes under the CIE recommended illuminants: D65 (natural day light), A (tungsten light), F2 (fluorescent light) and the standard 10° observer, respectively. The colour differences: ΔEab* and ΔECMC were calculated against one standard. The results reveal a good colouring power of the new azo-stilbene dyes.

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Acknowledgments

This work was supported by Program 2 of Institute of Chemistry Timişoara of Romanian Academy (Research Project 2.3).

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Authors and Affiliations

  1. Institute of Chemistry Timişoara of Romanian Academy, B-dul Mihai Viteazul 24, 300223, Timişoara, Romania

    Maria Elena Grad, Simona Gabriela Muntean & Gheorghe Ilia

  2. Faculty of Pharmacy, University of Medicine and Pharmacy “V. Babeş” Timişoara, Eftimie Murgu 2, 300041, Timişoara, Romania

    Georgeta Maria Simu

  3. Faculty of Chemistry-Biology and Geography, West University, Pestalozzi 16, 300115, Timişoara, Romania

    Gheorghe Ilia

Authors
  1. Maria Elena Grad
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  2. Georgeta Maria Simu
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  3. Simona Gabriela Muntean
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  4. Gheorghe Ilia
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Correspondence to Gheorghe Ilia.

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Grad, M.E., Simu, G.M., Muntean, S.G. et al. Synthesis, characterization and colour determination using CIELAB colour space of stilbene dyes. J IRAN CHEM SOC 10, 807–816 (2013). https://doi.org/10.1007/s13738-012-0216-y

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  • DOI: https://doi.org/10.1007/s13738-012-0216-y

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