Abstract
The specimens of austenitic stainless steels were machined to different strain rates (105 s−1, 1050 s−1, 1500 s−1, 2100 s−1). These specimens were subjected to low-temperature sensitization (LTS) heat treatment. The LTS treatment was carried out at 475℃ and 575℃ for 24 h. Further, oxalic acid, double-loop electrochemical potentiokinetic reactivation (DL-EPR) were carried out. As-machined specimens were subjected to surface roughness measurements, optical microscopy, electron backscattered diffraction (EBSD), and Fourier transform infrared spectroscopy (FTIR) imaging measurements. Machined specimen exhibited more difficulty in passivation than the as-received specimen. The complete surface statistics were extracted. The specimens machined at a strain rate of 2100 s−1 were exhibited a higher degree of sensitization (DoS) at LTS of 575℃ and 475℃ for 24 h, respectively, than other specimens. It was found that specimens machined at a higher strain rate produced smoother roughness. FTIR imaging was used to extract the signal intensity of chromium oxide (Cr2O3) peak. Detected Cr2O3 peak/signal was strong for the specimen that exhibited lower DoS as estimated from FTIR-imaging.
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References
N. Srinivasan, V. Kain, N. Birbilis, K.V. Mani Krishna, S. Shekhawat, I. Samajdar, Near boundary gradient zone and sensitization control in austenitic stainless steel. Corros. Sci. 100, 544–555 (2015)
S. Ghosh, V. Kain, Microstructural changes in AISI 304L stainless steel due to surface machining: effect on its susceptibility to chloride stress corrosion cracking. J. Nucl. Mater. 403, 62–67 (2010)
A.J. Sedriks, Corrosion of Stainless Steels, 2nd edn (A Wiley-Interscience Publication, New York, 1996)
A. Pardo, M.C. Merino, A.E. Coy, F. Viejo, R. Arrabal, E. Matykina, Pitting corrosion behaviour of austenitic stainless steels – combining effects of Mn and Mo additions. Corros. Sci. 50, 1796–1806 (2008)
C.O.A. Olsson, D. Landolt, Passive films on stainless steels—chemistry, structure and growth. Electrochim. Acta. 48, 1093–1104 (2003)
S. Ningshen, U. Kamachi Mudali, V.K. Mittal, H.S. Khatak, Semiconducting and passive film properties of nitrogen-containing type 316LN stainless steels, Corros. Sci. 49 (2007) 481–496.
T.L.S.L. Wijesinghe, D.J. Blackwood, Characterisation of passive films on 300 series stainless steels. Appl. Surf. Sci. 253, 1006–1009 (2006)
N.E. Hakiki, Comparative study of structural and semiconducting properties of passive films and thermally grown oxides on AISI 304 stainless steel. Corros. Sci. 53, 2688–2699 (2011)
L.V. Jinlong, L. Hongyun, Influence of tensile pre-strain and sensitization on passive films in AISI 304 austenitic stainless steel. Mater. Chem. Phys. 135, 973–978 (2012)
J. Gravier, V. Vignal, S. Bissey-Breton, Influence of residual stress, surface roughness and crystallographic texture induced by machining on the corrosion behaviour of copper in salt-fog atmosphere. Corros. Sci. 61, 162–170 (2012)
A. Turnbull, K. Mingard, J.D. Lord, B. Roebuck, D.R. Tice, K.J. Mottershead, N.D. Fairweather, A.K. Bradbury, Sensitivity of stress corrosion cracking of stainless steel to surface machining and grinding procedure. Corros. Sci. 53, 3398–3415 (2011)
P.S. Kumar, S.G. Acharyya, S.V.R. Rao, K. Kapoor, Distinguishing effect of buffing vs. grinding, milling and turning operations on the chloride induced SCC susceptibility of 304L austenitic stainless steel. Mater. Sci. Eng. A. 687, 193–199 (2017)
S. Wang, Y. Hu, K. Fang, W. Zhang, X. Wang, Effect of surface machining on the corrosion behaviour of 316 austenitic stainless steel in simulated PWR water. Corros. Sci. 126, 104–120 (2017). https://doi.org/10.1016/j.corsci.2017.06.019
Z. Wang, M. Rahman, High speed machining, in Compr. ed. by M.S.J. Hashmi (Mater. Process, Elsevier, Ireland, 2014), pp. 221–253
S. Ghosh, V. Kain, Effect of surface machining and cold working on the ambient temperature chloride stress corrosion cracking susceptibility of AISI 304L stainless steel. Mater. Sci. Eng. A. 527, 679–683 (2010)
M. Martin, S. Weber, C. Izawa, S. Wagner, A. Pundt, W. Theisen, Influence of machining-induced martensite on hydrogen-assisted fracture of AISI type 304 austenitic stainless steel. Int. J. Hydrogen Energy. 36, 11195–11206 (2011)
A. Maurotto, D. Tsivoulas, Y. Gu, M.G. Burke, Effects of machining abuse on the surface properties of AISI 316L stainless steel. Int. J. Press. Vessel. Pip. 151, 35–44 (2017)
L.R. Queiroga, G.F. Marcolino, M. Santos, G. Rodrigues, C. Eduardo dos Santos, P. Brito, Influence of machining parameters on surface roughness and susceptibility to hydrogen embrittlement of austenitic stainless steels. Int. J. Hydrogen Energy. 44, 29027–29033 (2019). https://doi.org/10.1016/j.ijhydene.2019.09.139
S.M. Alvarez, A. Bautista, F. Velasco, Influence of strain-induced martensite in the anodic dissolution of austenitic stainless steels in acid medium. Corros. Sci. 69, 130–138 (2013)
K.N. Lyon, T.J. Marrow, S.B. Lyon, Influence of milling on the development of stress corrosion cracks in austenitic stainless steel. J. Mater. Process. Technol. 218, 32–37 (2015)
W. Zhang, K. Fang, Y. Hu, S. Wang, X. Wang, Effect of machining-induced surface residual stress on initiation of stress corrosion cracking in 316 austenitic stainless steel. Corros. Sci. 108, 173–184 (2016)
J. Rajaguru, N. Arunachalam, Investigation on machining induced surface and subsurface modifications on the stress corrosion crack growth behaviour of super duplex stainless steel. Corros. Sci. 141, 230–242 (2018)
N. Srinivasan, B. Sunil Kumar, V. Kain, N. Birbilis, S.S. Joshi, P.V. Sivaprasad, G. Chai, A. Durgaprasad, S. Bhattacharya, I. Samajdar, Defining the Post-machined Sub-surface in Austenitic stainless steels. Metall. Mater. Trans. A. 49, 2281–2292 (2018)
G. Cios, T. Tokarski, A. Żywczak, R. Dziurka, M. Stępień, M. Gondek, B. Marciszko, K. Pawłowski, P.. Ba.ła Wieczerzak, The investigation of Strain-induced martensite reverse transformation in AISI 304 Austenitic stainless steel, metall. Mater. Trans. A Phys. Metall. Mater. Sci. 48, 4999–5008 (2017). https://doi.org/10.1007/s11661-017-4228-1
C. Celada-Casero, H. Kooiker, M. Groen, J. Post, D. San-Martin, In-situ investigation of strain-induced martensitic transformation kinetics in an austenitic stainless steel by inductive measurements. Metals (Basel). (2017). https://doi.org/10.3390/met7070271
L. Dong, X. Zhang, Y. Han, Q. Peng, P. Deng, S. Wang, Effect of surface treatments on microstructure and stress corrosion cracking behavior of 308L weld metal in a primary pressurized water reactor environment. Corros. Sci. 166, 108465 (2020). https://doi.org/10.1016/j.corsci.2020.108465
M.J. Povich, Low temperature sensitization of type 304 stainless steel. Corrosion. 34, 60–65 (1978)
C. Schmidt, R. Caligiuri, L. Eiselstein, S. Wing, D. Cubicciotti, Low temperature sensitization of type 304 stainless steel pipe weld heat affected zone. Metall. Mater. Trans. A. 18, 1483–1493 (1987)
N. Parvathavarthini, R.K. Dayal, S.K. Seshadri, J.B. Gnanamoorthy, Continuous cooling and low temperature sensitization of AISI Types 316 SS and 304 SS With different degrees of cold work. J. Nucl. Mater. 168, 83–96 (1989)
R. Singh, S.G. Chowdhury, G. Das, P.K. Singh, I. Chattoraj, Low temperature sensitization on the orthogonal surfaces of prior deformed AISI 304LN and aged at 673 K to 873 K (400°C to 600°C). Metall. Mater. Trans. A. 43, 986–1003 (2012)
L. Hongyun, Z. Yubo, L. Hongdou, L. Jinlong, M. Yue, Characterization of the oxide films formed on low temperature sensitized AISI 321 stainless steel with different strain levels in elevated temperature borate buffer solution. J. Alloys Compd. 696, 1235–1243 (2017). https://doi.org/10.1016/j.jallcom.2016.12.107
P. Muri, F.V.V. Sousa, K.S. Assis, A.C. Rocha, O.R. Mattos, I.C.P. Margarit-Mattos, Experimental procedures and sensitization diagnostics of aisi304 steel by double loop electrochemical potentiodynamic reactivation method. Electrochim. Acta. 124, 183–189 (2014). https://doi.org/10.1016/j.electacta.2013.11.044
R. Joham, N.K. Sharma, K. Mondal, S. Shekhar, Low temperature cross-rolling to modify grain boundary character distribution and its effect on sensitization of SS304. J. Mater. Process. Technol. 240, 324–331 (2017). https://doi.org/10.1016/j.jmatprotec.2016.10.014
R.S. Pawade, H.A. Sonawane, S.S. Joshi, An analytical model to predict specific shear energy in high-speed turning of Inconel 718. Int. J. Mach. Tools Manuf. 49, 979–990 (2009)
H.A. Sonawane, S.S. Joshi, Analytical modeling of chip geometry and cutting forces in helical ball end milling of superalloy Inconel 718. CIRP J. Manuf. Sci. Technol. 3, 204–217 (2010)
A.P. Majidi, M. Streicher A., , Potentiodynamic reactivation method for detecting sensitization in AISI 304 and 304L stainless steels. Corrosion. 40, 393–408 (1984)
N. Srinivasan, S.S. Kumaran, D. Venkateswarlu, Effects of in-grain misorientation developments in sensitization of 304 L austenitic stainless steels. Mater. Res. Express. 6, 016551 (2018). https://doi.org/10.1088/2053-1591/aae802
J.P. Davim, C. Maranhão, A study of plastic strain and plastic strain rate in machining of steel AISI 1045 using FEM analysis. Mater. Des. 30, 160–165 (2009)
E.S. Gadelmawla, M.M. Koura, T.M.A. Maksoud, I.M. Elewa, H.H. Soliman, Roughness parameters. J. Mater. Process. Technol. 123, 133–145 (2002). https://doi.org/10.1016/S0924-0136(02)00060-2
ASTM A262 practice test standard practices for detecting susceptibility to intergranular attack in austenitic stainless steels, ASTM Int. A262-10 (2010) 1–16.
S. Rahimi, T.J. Marrow, Effects of orientation, stress and exposure time on short intergranular stress corrosion crack behaviour in sensitised type 304 austenitic stainless steel. Fatigue Fract. Eng. Mater. Struct. 35, 359–373 (2012)
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Srinivasan, N. Studies of Low-Temperature Sensitization after Sub-Surface Damage Evolution in Austenitic Stainless Steel. Metallogr. Microstruct. Anal. 10, 236–245 (2021). https://doi.org/10.1007/s13632-021-00736-8
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DOI: https://doi.org/10.1007/s13632-021-00736-8