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Structural, Optical, and Electrical Investigation of Polyvinyl Alcohol Thin Film Doped with Gold Core and Silver Shell Nanoparticles

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Abstract

Gold core and silver shell (\({C}^{Au}{S}^{Ag}\)) nanoparticles (NPs) fabricated by an efficient synthetic route have been used to fabricate polyvinyl alcohol (PVA) nanocomposite (NC) thin films by solution casting technique. High-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and UV–visible absorption spectroscopy confirmed the core–shell structure of \({C}^{Au}{S}^{Ag}\) NPs. UV–visible spectroscopy data has been analyzed to obtain various linear as well as nonlinear optical parameters. The current–voltage characteristics have been examined to find out the exact conduction mechanism accountable for the movement of charge carriers in these NC films.

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References

  1. A. Nouailhat, An Introduction to Nanoscience and Nanotechnology (ISTE, London, UK, 2008)

  2. M. Zhiming, Wang, Toward Functional Nanomaterials (Springer, US, New York, NY, 2009)

    Google Scholar 

  3. A. Steinbrück, O. Stranik, A. Csaki, W. Fritzsche, Anal. Bioanal. Chem. 401, 1241 (2011)

    Article  Google Scholar 

  4. A. Steinbrück, A. Csáki, G. Festag, W. Fritzsche, Plasmonics 1, 79 (2006)

    Article  Google Scholar 

  5. H. Han, Y. Fang, Z. Li, H. Xu, Appl. Phys. Lett. 92, 023116 (2008)

    Article  ADS  Google Scholar 

  6. H. Nishi, S. Hiroya, T. Tatsuma, ACS Nano 9, 6214 (2015)

    Article  Google Scholar 

  7. A.J. Haes, S. Zou, G.C. Schatz, R.P. Van Duyne, J. Phys. Chem. B 108, 6961 (2004)

    Article  Google Scholar 

  8. R. Kumar, A. Sharma, R. Kumar, P.K. Sharma, Integr. Ferroelectr. 204, 150 (2020)

    Article  Google Scholar 

  9. A. Loiseau, L. Zhang, D. Hu, M. Salmain, Y. Mazouzi, R. Flack, B. Liedberg, S. Boujday, A.C.S. Appl, Mater. Interfaces 11, 46462 (2019)

    Article  Google Scholar 

  10. L. Yang, W. Yan, H. Wang, H. Zhuang, J. Zhang, RSC Adv. 7, 11355 (2017)

    Article  ADS  Google Scholar 

  11. J. Yang, J.Y. Lee, H.-P. Too, J. Phys. Chem. B 109, 19208 (2005)

    Article  Google Scholar 

  12. D. Mott, J. Lee, N.T.B. Thuy, Y. Aoki, P. Singh, S. Maenosono, Jpn. J. Appl. Phys. 50, 065004 (2011)

    Article  ADS  Google Scholar 

  13. Y. Feng, G. Wang, Y. Chang, Y. Cheng, B. Sun, L. Wang, C. Chen, H. Zhang, Nano Lett. 19, 4478 (2019)

    Article  ADS  Google Scholar 

  14. A.K. Samal, L. Polavarapu, S. Rodal-Cedeira, L.M. Liz-Marzán, J. Pérez-Juste, I. Pastoriza-Santos, Langmuir 29, 15076 (2013)

    Article  Google Scholar 

  15. M. Banerjee, S. Sharma, A. Chattopadhyay, S.S. Ghosh, Nanoscale 3, 5120 (2011)

    Article  ADS  Google Scholar 

  16. S. Pande, S.K. Ghosh, S. Praharaj, S. Panigrahi, S. Basu, S. Jana, A. Pal, T. Tsukuda, T. Pal, J. Phys. Chem. C 111, 10806 (2007)

    Article  Google Scholar 

  17. J. Zeng, Y. Cao, J. Chen, X. Wang, J. Yu, B. Yu, Z. Yan, X. Chen, Nanoscale 6, 9939 (2014)

    Article  ADS  Google Scholar 

  18. H.-L. Jiang, T. Akita, T. Ishida, M. Haruta, Q. Xu, J. Am. Chem. Soc. 133, 1304 (2011)

    Article  Google Scholar 

  19. Y. Zhao, X. Xie, J. Braz. Chem. Soc. 29, 232 (2017)

    Google Scholar 

  20. M.I. Baker, S.P. Walsh, Z. Schwartz, B.D. Boyan, J. Biomed. Mater. Res. Part B Appl. Biomater. 100B, 1451 (2012)

    Article  Google Scholar 

  21. S. Mahmud, S.S. Satter, A.K. Singh, M.M. Rahman, M.Y.A. Mollah, M.A.B.H. Susan, ACS Omega 4, 18061 (2019)

    Article  Google Scholar 

  22. T. Som, B. Karmakar, Nano Res. 2, 607 (2009)

    Article  Google Scholar 

  23. H.M. Chen, R.S. Liu, L.-Y. Jang, J.-F. Lee, S.F. Hu, Chem. Phys. Lett. 421, 118 (2006)

    Article  ADS  Google Scholar 

  24. I.J. Godfrey, A.J. Dent, I.P. Parkin, S. Maenosono, G. Sankar, J. Phys. Chem. C 121, 1957 (2017)

    Article  Google Scholar 

  25. S. Mallick, P. Sanpui, S.S. Ghosh, A. Chattopadhyay, A. Paul, RSC Adv. 5, 12268 (2015)

    Article  ADS  Google Scholar 

  26. R. Kumar, R. Kaushik, R. Kumar, D.A. Jose, P.K. Sharma, A. Sharma, Mater. Chem. Phys. 260, 124132 (2021)

    Article  Google Scholar 

  27. B.D. Cullity, Elements of X-Ray Diffraction (Addison-Wesley Publishing Company INC., USA, 1978)

    Google Scholar 

  28. G. Rajender, P.K. Giri, J. Alloys Compd. 676, 591 (2016)

    Article  Google Scholar 

  29. D. Nath, F. Singh, R. Das, Mater. Chem. Phys. 239, 122021 (2020)

    Article  Google Scholar 

  30. U. Kreibig, M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin Heidelberg, Berlin, Heidelberg, 1995)

    Book  Google Scholar 

  31. K.M. Mayer, J.H. Hafner, Chem. Rev. 111, 3828 (2011)

    Article  Google Scholar 

  32. G. Mie, Ann. Phys. 330, 377 (1908)

    Article  Google Scholar 

  33. S. Link, M.A. El-Sayed, J. Phys. Chem. B 103, 8410 (1999)

    Article  Google Scholar 

  34. N.F. Mott, E.A. Davis, Electronic Processes in Non-Crystalline Materials (Oxford University Press, USA, 1971)

    Google Scholar 

  35. Sonal, A. Sharma, and S. Aggarwal, Opt. Mater. (Amst). 84, 807 (2018)

  36. I. Saini, J. Rozra, N. Chandak, S. Aggarwal, P.K. Sharma, A. Sharma, Mater. Chem. Phys. 139, 802 (2013)

    Article  Google Scholar 

  37. Sonal, A. Sharma, and S. Aggarwal, J. Non. Cryst. Solids 485, 57 (2018)

  38. T.S. Soliman, S.A. Vshivkov, S.I. Elkalashy, Polym. Compos. 41, 3340 (2020)

    Article  Google Scholar 

  39. A.A. Ahmad, A.M. Alsaad, Q.M. Al-Bataineh, M.A. Al-Naafa, Appl. Phys. A 124, 458 (2018)

    Article  ADS  Google Scholar 

  40. K.H. Mahmoud, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 138, 434 (2015)

    Article  ADS  Google Scholar 

  41. T.S. Soliman, S.A. Vshivkov, S.I. Elkalashy, Opt. Mater. (Amst). 107, 110037 (2020)

    Article  Google Scholar 

  42. M. Aslam, M.A. Kalyar, Z.A. Raza, Appl. Phys. A 123, 424 (2017)

    Article  ADS  Google Scholar 

  43. C. Flytzanis, F. Hache, M. C. Klein, D. Ricard, and P. Roussignol, in Prog. Opt. 321–411 (1991)

  44. C.H. Yang, Z.M. Ao, Q.F. Li, J.J. Jiang, Opt. Commun. 338, 145 (2015)

    Article  ADS  Google Scholar 

  45. A. Gautam, S. Ram, Phys. Status Solidi 206, 1471 (2009)

    Article  ADS  Google Scholar 

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Acknowledgements

R K acknowledges the Council of Scientific & Industrial Research (CSIR), New Delhi, India, for a Senior Research Fellowship. The authors are thankful to AIIMS, New Delhi, for providing the HRTEM facility.

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Correspondence to Annu Sharma.

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Kumar, R., Kumar, R., Arya, A. et al. Structural, Optical, and Electrical Investigation of Polyvinyl Alcohol Thin Film Doped with Gold Core and Silver Shell Nanoparticles. Braz J Phys 52, 163 (2022). https://doi.org/10.1007/s13538-022-01170-z

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  • DOI: https://doi.org/10.1007/s13538-022-01170-z

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