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Experimental study of formaldehyde and BTEX adsorption onto activated carbon from lignocellulosic biomass

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Abstract

Formaldehyde and BTEX have been used for different industries and other activities. They release many ways that negatively affect the environment and human health due to inadequate ventilation and rapidly increasing oscillation conditions. The widely used technology, which activated carbon, is emerging new studies on air pollutants removal. This study was produced activated carbon for formaldehyde and BTEX removal from Aesculus hippocastanum L. biomass. It was used as organic waste that is abundant in nature. The carbonization was taken place at 600 °C and chemical activation by mixing with ZnCl2. The produced activated carbon has a surface area is 1858.42 m2/g. The adsorption capacity acquired from experimental data of VOCs were range from 638 to 1114 µg/g for AC-KN, respectively. The removal capacity of produced activated carbon was investigated in a batch reactor. Also, Freundlich and Langmuir’s isotherms were applied in the study. Accordingly, the experimental data were found compatible with both and a hybrid structure that the formaldehyde and BTEX adsorption by AC-KN was better fitted into the Freundlich model. Overall, the study showed that the produced AC-KN from the Aesculus hippocastanum L. biomass has a perfect potential in the removal of the formaldehyde and BTEX from indoor air.

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References

  1. ACGIH (2011) Threshold limit values for chemical substances and physical agents and biological exposure indices. American Conference of Governmental Industrial Hygienists, Cincinnati

  2. Aivalioti M, Papoulias P, Kousaiti A et al (2012) Adsorption of BTEX, MTBE and TAME on natural and modified diatomite. J Hazard Mater 207:117–127. https://doi.org/10.1016/j.jhazmat.2010.01.053

    Article  Google Scholar 

  3. Amiri MJ, Roohi R, Arshadi M et al (2020) 2, 4-D adsorption from agricultural subsurface drainage by canola stalk-derived activated carbon: insight into the adsorption kinetics models under batch and column conditions. Environ Sci Pollut Res 1–15.https://doi.org/10.1007/s11356-020-08211-7

  4. Awad R, Mamaghani AH, Boluk Y et al (2021) Synthesis and characterization of electrospun PAN-based activated carbon nanofibers reinforced with cellulose nanocrystals for adsorption of VOCs. Chem Eng J 410:128412. https://doi.org/10.1016/j.cej.2021.128412

    Article  Google Scholar 

  5. Bellat JP, Bezverkhyy I, Weber G, Royer S, Averlant R, Giraudon JM, Lamonier JF (2015) Capture of formaldehyde by adsorption on nanoporous materials. J Hazard Mater. https://doi.org/10.1016/j.jhazmat.2015.07.078

    Article  Google Scholar 

  6. Ceron-Breton JG, Bretón RMC, Kahl JD, Rico GS, Lozada SEC et al (2021) Concentrations, sources, and health risk associated with exposure to BTEX at ten sites located in an urban-industrial area in the Bajio Region, Mexico. Air Qual Atmos Health 14(5):741–761. https://doi.org/10.1007/s11869-021-00976-1

    Article  Google Scholar 

  7. Chen PW, Kuo TC, Liu ZS et al (2021) Assessment of the mutagenicity of two common indoor air pollutants, formaldehyde and toluene. Indoor Air. https://doi.org/10.1111/ina.12832

    Article  Google Scholar 

  8. Clinger JC, O’Shaughnessy PT (2019) Breakthrough analysis for filtering facepiece respirators impregnated with activated carbon. J Occup Environ Hyg 16(7):423–431. https://doi.org/10.1080/15459624.2019.1594838

    Article  Google Scholar 

  9. Destro F, Hur I, Wang V, Abdi M, Feng X, Wood E et al (2021) Mathematical modeling and digital design of an intensified filtration-washing-drying unit for pharmaceutical continuous manufacturing. Chem Eng Sci 244:116803. https://doi.org/10.1016/j.ces.2021.116803

    Article  Google Scholar 

  10. Dinh TV, Kim SY, Son YS, Choi IY, Park SR, Sunwoo Y et al (2015) Emission characteristics of VOCs emitted from consumer and commercial products and their ozone formation potential. Environ Sci Pollut Res 22(12):9345–9355. https://doi.org/10.1007/s11356-015-4092-8

    Article  Google Scholar 

  11. El-Hashemy MAES, Alotaibi NF (2021) Purification of benzene-laden air by static adsorption of benzene onto activated carbon prepared from Diplotaxisacris biomass. Biomass Convers Biorefinery 1–15.https://doi.org/10.1007/s13399-021-01462-5

  12. Fu C, Zhang L, Zhang K, Xiao B, Liu J, Luan Q, Liu J (2021) Effects of air-prepared atmosphere on the Pb2+ adsorption of sludge-based adsorbent. Biomass Convers Biorefinery 1–13.https://doi.org/10.1007/s13399-021-01706-4

  13. Gałko G, Rejdak M, Tercki D, Bogacka M et al (2021) Evaluation of the applicability of polymeric materials to BTEX and fine product transformation by catalytic and non-catalytic pyrolysis as a part of the closed loop material economy. J Anal Appl Pyrol 154:105017. https://doi.org/10.1016/j.jaap.2021.105017

    Article  Google Scholar 

  14. Giovanis E (2018) The relationship between teleworking, traffic and air pollution. Atmos Pollut Res. https://doi.org/10.1016/j.apr.2017.06.004

    Article  Google Scholar 

  15. Goldstein AH, Nazaroff WW, Weschler CJ et al (2020) How do indoor environments affect air pollution exposure? Environ Sci Technol 55(1):100–108. https://doi.org/10.1021/acs.est.0c05727

    Article  Google Scholar 

  16. González-García P (2018) Activated carbon from lignocellulosics precursors: a review of the synthesis methods, characterization techniques and applications.

  17. Guo M, Yu W, Zhang S, Wang H et al (2020) A numerical model predicting indoor volatile organic compound volatile organic compounds emissions from multiple building materials. Environ Sci Pollut Res 27(1):587–596. https://doi.org/10.1007/s11356-019-06890-5

    Article  Google Scholar 

  18. Haffner MJ, Oakes P, Demerdash A, Yammine KC, Watanabe K, Loukas M, Tubbs RS (2015) Formaldehyde exposure and its effects during pregnancy: recommendations for laboratory attendance based on available data. Clin Anat. https://doi.org/10.1002/ca.22623

    Article  Google Scholar 

  19. Hajizadeh Y, Mokhtari M, Faraji M, Mohammadi A, Nemati S, Ghanbari R, Abdolahnejad A, Fard RF, Nikoonahad A, Jafari N, Miri M (2018) Trends of BTEX in the central urban area of Iran: a preliminary study of photochemical ozone pollution and health risk assessment. Atmos Pollut Res. https://doi.org/10.1016/j.apr.2017.09.005

    Article  Google Scholar 

  20. Huang S, Wei W, Weschler LB, Salthammer T, Kan H, Bu Z, Zhang Y (2017) Indoor formaldehyde concentrations in urban China: preliminary study of some important influencing factors. Sci Total Environ. https://doi.org/10.1016/j.scitotenv.2017.02.187

    Article  Google Scholar 

  21. Isinkaralar O, Isinkaralar K, Ekizler A, Ilkdogan C (2017) Changes in the amounts of CO2 and particulate matter in Kastamonu Province depending on weather conditions and locations. J Chem Biol Phys Sci 7(3):643–650. https://doi.org/10.24214/jcbps.D.7.3.64350

    Article  Google Scholar 

  22. Isinkaralar K (2020) Removal of formaldehyde and BTEX in indoor air using activated carbon produced from horse chestnut (Aesculus hippocastanum L.) Shell. Ph.D. Thesis Hacettepe University, Institute of Science and Engineering, Department of Environmental Engineering. Ankara, Turkey

  23. Jaiswal KK, Dutta S, Banerjee I, Pohrmen CB et al (2021) Photosynthetic microalgae–based carbon sequestration and generation of biomass in biorefinery approach for renewable biofuels for a cleaner environment. Biomass Convers Biorefinery 1–19.https://doi.org/10.1007/s13399-021-01504-y

  24. Janhäll S (2015) Review on urban vegetation and particle air pollution–deposition and dispersion. Atmos Environ 105:130–137. https://doi.org/10.1016/j.atmosenv.2015.01.052

    Article  Google Scholar 

  25. Javed M, Zahoor M, Mazari SA, Qureshi SS, Sabzoi N, Jatoi AS, Mubarak NM (2021) An overview of effect of process parameters for removal of CO 2 using biomass-derived adsorbents. Biomass Convers Biorefinery 1–19.https://doi.org/10.1007/s13399-021-01548-0

  26. Karacocuk T, Sevik H, Isinkaralar K, Turkyilmaz A, Cetin M (2021) The change of Cr and Mn concentrations in selected plants in Samsun city center depending on traffic density. Landscape Ecol Eng. https://doi.org/10.1007/s11355-021-00483-6

    Article  Google Scholar 

  27. Karmakar D, Deb K et al (2021) Ecophysiological responses of tree species due to air pollution for biomonitoring of environmental health in urban area. Urban Climate 35:100741. https://doi.org/10.1016/j.uclim.2020.100741

    Article  Google Scholar 

  28. Kim MJ, Seo YK, Kim JH et al (2020) Impact of industrial activities on atmospheric volatile organic compounds in Sihwa-Banwol, the largest industrial area in South Korea. Environ Sci Pollut Res 27:28912–28930. https://doi.org/10.1007/s11356-020-09217-x

    Article  Google Scholar 

  29. Lara-Ibeas I, Megias-Sayago C, Louis B, Le Calvé S (2020) Adsorptive removal of gaseous formaldehyde at realistic concentrations. J Environ Chem Eng 8(4):103986. https://doi.org/10.1016/j.jece.2020.103986

    Article  Google Scholar 

  30. Li Z, Li Y, Zhu J (2021) Straw-based activated carbon: optimization of the preparation procedure and performance of volatile organic compounds adsorption. Materials 14(12):3284. https://doi.org/10.3390/ma14123284

    Article  Google Scholar 

  31. Liu X, Zhang Y, Wu R, Ye M, Zhao Y, Kang J, Ma P, Li J, Yang X (2018) Acute formaldehyde exposure induced early Alzheimer-like changes in mouse brain. Toxicol Mech Methods. https://doi.org/10.1080/15376516.2017.1368053

    Article  Google Scholar 

  32. Liu Y, Jia H, Li C et al (2019) Efficient removal of gaseous formaldehyde by amine-modified diatomite: a combined experimental and density functional theory study. Environ Sci Pollut Res 26:25130–25141. https://doi.org/10.1007/s11356-019-05758-y

    Article  Google Scholar 

  33. Mirzaei A, Leonardi SG, Neri G (2016) Detection of hazardous volatile organic compounds (VOCs) by metal oxide nanostructures-based gas sensors: a review. Ceram Int 42(14):15119–15141. https://doi.org/10.1016/j.ceramint.2016.06.145

    Article  Google Scholar 

  34. Mirzaie M, Talebizadeh AR, Hashemipour H (2021) Mathematical modeling and experimental study of VOC adsorption by Pistachio shell–based activated carbon. Environ Sci Pollut Res 28(3):3737–3747. https://doi.org/10.1007/s11356-020-10634-1

    Article  Google Scholar 

  35. Na CJ, Yoo MJ, Tsang DCW, Kim HW, Kim KH (2019) High-performance materials for effective sorptive removal of formaldehyde in air. J Hazard Mater 366:452–465. https://doi.org/10.1016/j.jhazmat.2018.12.011

    Article  Google Scholar 

  36. Nanda S, Mohammad J, Reddy SN, Kozinski JA, Dalai AK (2014) Pathways of lignocellulosic biomass conversion to renewable fuels. Biomass Convers Biorefinery 4(2):157–191. https://doi.org/10.1007/s13399-013-0097-z

    Article  Google Scholar 

  37. Nielsen GD, Larsen ST, Wolkoff P (2013) Recent trend in risk assessment of formaldehyde exposures from indoor air.

  38. Niu Z, Kong S, Zheng H, Yan Q, Liu J, Feng Y et al (2021) Temperature dependence of source profiles for volatile organic compounds from typical volatile emission sources. Sci Total Environ 751:141741. https://doi.org/10.1016/j.scitotenv.2020.141741

    Article  Google Scholar 

  39. Park SH, Lim HB, Hong HJ, Kim HS, Yoon DK, Lee HW et al (2021) Health risk assessment for multimedia exposure of formaldehyde emitted by chemical accident. Environ Sci Pollut Res 28(8):9712–9722. https://doi.org/10.1007/s11356-020-11403-w

    Article  Google Scholar 

  40. Paterson CA, Sharpe RA, Taylor T, Morrissey K (2021) Indoor PM2. 5, VOCs and asthma outcomes: a systematic review in adults and their home environments. Environ Res 111631. https://doi.org/10.1016/j.envres.2021.111631

  41. Penney D, Benignus V, Kephalopoulos S, Kotzias D, Kleinman M, Verrier A (2010) Guidelines for indoor air quality. WHO Guidelines 9:454. https://doi.org/10.1186/2041-1480-2-S2-I1

    Article  Google Scholar 

  42. Pivokonsky M, Kopecka I, Cermakova L, Fialova K, Novotna K, Cajthaml T et al (2021) Current knowledge in the field of algal organic matter adsorption onto activated carbon in drinking water treatment. Sci Total Environ 149455.https://doi.org/10.1016/j.scitotenv.2021.149455

  43. Ramadoss R, Subramaniam D (2019) Removal of divalent nickel from aqueous solution using blue-green marine algae: adsorption modeling and applicability of various isotherm models. Sep Sci Technol 54(6):943–961. https://doi.org/10.1080/01496395.2018.1526194

    Article  Google Scholar 

  44. Rehfuess E, World Health Organization (2006) Fuel for life: household energy and health. World Health Organization

  45. Restrepo SYG, Rocha MH, Lora EES, Venturini OJ, Cobas VRM, Maya DMY (2021) Design and operation of a gas cleaning system for biomass gasification in a two-stage air-blown downdraft gasifier to meet quality requirements of solid oxide fuel cells. Biomass Convers Biorefinery 1–27.https://doi.org/10.1007/s13399-021-01796-0

  46. Robert B, Nallathambi G (2021) Indoor formaldehyde removal by catalytic oxidation, adsorption and nanofibrous membranes: a review. Environ Chem Lett 1–29.https://doi.org/10.1007/s10311-020-01168-6

  47. Ryu DY, Shimohara T, Nakabayashi K, Miyawaki J, Park JI, Yoon SH (2019) Urea/nitric acid co-impregnated pitch-based activated carbon fiber for the effective removal of formaldehyde. J Ind Eng Chem 80:98–105. https://doi.org/10.1016/j.jiec.2019.07.036

    Article  Google Scholar 

  48. Saleem J, Shahid UB, Hijab M, Mackey H, McKay G (2019) Production and applications of activated carbons as adsorbents from olive stones. Biomass Convers Biorefinery 9(4):775–802. https://doi.org/10.1007/s13399-019-00473-7

    Article  Google Scholar 

  49. Savas DS, Sevik H, Isinkaralar K, Turkyilmaz A et al (2021) The potential of using Cedrus atlantica as a biomonitor in the concentrations of Cr and Mn. Environ Sci Pollut Res 1–8.https://doi.org/10.1007/s11356-021-14826-1

  50. Scherzinger M, Kaltschmitt M (2021) Thermal pre-treatment options to enhance anaerobic digestibility–a review. Renew Sustain Energy Rev 137:110627. https://doi.org/10.1016/j.rser.2020.110627

    Article  Google Scholar 

  51. Sevik H, Isinkaralar K, Isinkaralar O (2018) Indoor air quality in hospitals: the case of Kastamonu Turkey. J Chem Biol Phys Sci Sect D 9(1):067–073. https://doi.org/10.24214/jcbps.D.9.1.06773

    Article  Google Scholar 

  52. Sovacool BK, Griffiths S, Kim J, Bazilian M (2021) Climate change and industrial F-gases: a critical and systematic review of developments, sociotechnical systems and policy options for reducing synthetic greenhouse gas emissions. Renew Sustain Energy Rev 141:110759. https://doi.org/10.1016/j.rser.2021.110759

    Article  Google Scholar 

  53. Sun J, Shen Z, Zhang Y, Zhang Z, Zhang Q, Zhang T et al (2019) Urban VOC profiles, possible sources, and its role in ozone formation for a summer campaign over Xi’an, China. Environ Sci Pollut Res 26(27):27769–27782. https://doi.org/10.1007/s11356-019-05950-0

    Article  Google Scholar 

  54. Teimouri Z, Salem A, Salem S (2019) Regeneration of wastewater contaminated by cationic dye by nanoporous activated carbon produced from agriculture waste shells. Environ Sci Pollut Res 26(8):7718–7729. https://doi.org/10.1007/s11356-018-04094-x

    Article  Google Scholar 

  55. Tham YJ, Latif PA, Abdullah AM, Shamala-Devi A, Taufiq-Yap YH (2011) Performances of toluene removal by activated carbon derived from durian shell. Biores Technol 102(2):724–728. https://doi.org/10.1016/j.biortech.2010.08.068

    Article  Google Scholar 

  56. Turkyilmaz A, Cetin M, Sevik H, Isinkaralar K, Saleh EAA (2020) Variation of heavy metal accumulation in certain landscaping plants due to traffic density. Environ Dev Sustain 22(3):2385–2398. https://doi.org/10.1007/s10668-018-0296-7

    Article  Google Scholar 

  57. Turkyilmaz A, Sevik H, Isinkaralar K, Cetin M (2018) Using Acer platanoides annual rings to monitor the amount 520 of heavy metals accumulated in air. Environ Monit Assess 190:578. https://doi.org/10.1007/s10661-018-5216956-0

    Article  Google Scholar 

  58. Turkyilmaz A, Sevik H, Isinkaralar K, Cetin M (2019) Use of tree rings as a bioindicator to observe atmospheric heavy metal deposition. Environ Sci Pollut Res 26(5):5122–5130. https://doi.org/10.1007/s11356-018-3962-2

    Article  Google Scholar 

  59. UNION P (2008) Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe. Official Journal of the European Union

  60. USEPA (2020) —Measurement of Formaldehyde Emissions From Natural Gas-Fired Stationary Sources—Acetyl Acetone Derivitization Method Environmental Protection Agency. https://www.epa.gov/sites/default/files/2020-12/documents/method_323.pdf. Accessed 9/7/2020

  61. Wang H, Wang B, Li J, Zhu T (2019) Adsorption equilibrium and thermodynamics of acetaldehyde/acetone on activated carbon. Sep Purif Technol 209:535–541. https://doi.org/10.1016/j.seppur.2018.07.076

    Article  Google Scholar 

  62. WHO (2000) Air Quality Guidelines for Europe, 2nd edn, European Series, No. 91. WHO Regional Publications, Copenhagen

  63. Wu J, Ahn J, Lee J (2021) Characterization of gold deportment and thiosulfate extraction for a copper‑gold concentrate treated by pressure oxidation. Hydrometallurgy 105771.https://doi.org/10.1016/j.hydromet.2021.105771

  64. Xu X, Guo Y, Shi R, Chen H, Du Y, Liu B et al (2021) Natural honeycomb-like structure cork carbon with hierarchical micro-mesopores and N-containing functional groups for VOCs adsorption. Appl Surf Sci 565:150550. https://doi.org/10.1016/j.apsusc.2021.150550

    Article  Google Scholar 

  65. Yusoff MNAM, Zulkifli NWM, Sukiman NL, Chyuan OH, Hassan MH, Hasnul MH et al (2021) Sustainability of palm biodiesel in transportation: a review on biofuel standard, policy and international collaboration between Malaysia and Colombia. Bioenergy Res 14(1):43–60. https://doi.org/10.1007/s12155-020-10165-0

    Article  Google Scholar 

  66. Zhang G, Lei B, Chen S, Xie H, Zhou G (2021) Activated carbon adsorbents with micro-mesoporous structure derived from waste biomass by stepwise activation for toluene removal from air. J Environ Chem Eng 9(4):105387. https://doi.org/10.1016/j.jece.2021.105387

    Article  Google Scholar 

  67. Zhu L, Shen D, Luo KH (2020) A critical review on VOCs adsorption by different porous materials: species, mechanisms and modification methods. J Hazard Mater 389:122102. https://doi.org/10.1016/j.jhazmat.2020.122102

    Article  Google Scholar 

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Acknowledgements

This study is produced from the Ph.D. thesis titled “Removal of Formaldehyde and BTEX in Indoor Air Using Activated Carbon Produced from Horse Chestnut (Aesculus hippocastanum L.) Shell” conducted at Hacettepe University, Ankara, Türkiye, Graduate School of Science and Engineering, Department of Environmental Engineering.

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  1. Department of Environmental Engineering, Faculty of Engineering and Architecture, Kastamonu University, Kastamonu, Türkiye

    Kaan Isinkaralar & Aydin Turkyilmaz

  2. Department of Environmental Engineering, Faculty of Engineering, Hacettepe University, Ankara, Türkiye

    Gulen Gullu

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KI, raw material collection and/or processing analysis and/or interpretation; AT, materials and processing analysis; GG, conceptualization, methodology, and literature search.

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Isinkaralar, K., Gullu, G. & Turkyilmaz, A. Experimental study of formaldehyde and BTEX adsorption onto activated carbon from lignocellulosic biomass. Biomass Conv. Bioref. 13, 4279–4289 (2023). https://doi.org/10.1007/s13399-021-02287-y

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