Abstract
In this work, the high κ ZrxAl1−xOy films with a different Zr concentration have been deposited by atomic layer deposition, and the effect of Zr concentrations on the structure, chemical composition, surface morphology and dielectric properties of ZrxAl1−xOy films is analyzed by Atomic force microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and capacitance-frequency measurement. The effect of Zr concentrations of ZrxAl1-xOy gate insulator on the electrical property and stability under negative bias illumination stress (NBIS) or temperature stress (TS) of ZnSnO (ZTO) TFTs is firstly investigated. Under NBIS and TS, the much better stability of ZTO TFTs with ZrxAl1−xOy film as a gate insulator is due to the suppression of oxygen vacancy in ZTO channel layer and the decreased trap states originating from the Zr atom permeation at the ZTO/ZrxAl1−xOy interface. It provides a new strategy to fabricate the low consumption and high stability ZTO TFTs for application.
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Nomura, K., Ohta, H., Takagi, A., Kamiya, T., Hirano, M., Hosono, H.: Room-temperature fabrication of transparent flexible thin-film transistors using amorphous oxide semiconductors. Nature 432, 488 (2004)
Ryu, M.K., Yang, S., Park, S.H.K., Hwang, C.S., Jeong, J.K.: Impact of Sn/Zn ratio on the gate bias and temperature-induced instability of Zn-In-Sn-O thin film transistors. Appl. Phys. Lett. 95, 173508 (2009)
Rim, Y.S., Ahn, B.D., Park, J.S., Kim, H.J.: Manifestation of reversal conductivity on high pressurizing of solution-processed ZnSnO thin-film transistors at low temperature. J. Phys. D Appl. Phys. 47, 045502 (2014)
Sahoo, A.K., Wu, G.M.: Effects of argon flow rate on electrical properties of amorphous indium gallium zinc oxide thin-film transistors. Thin Solid Films 605, 129 (2016)
Lee, W.J., Chun, M.H., Cheong, K.S., Park, K.C., Park, C.O., Cao, G.: Characteristics of SiO2 film grown by atomic layer deposition as the gate insulator of low-temperature polysilicon thin-film transistors. Solid State Phenom. 124, 247 (2007)
Yang, W., Song, K., Jung, Y., Jeong, S., Moon, J.: Solution-deposited Zr-doped AlOx gate dielectrics enabling high-performance flexible transparent thin film transistors. J. Mater Chem. C 1, 4275 (2013)
Kim, Y.G., Avis, C., Hwang, H.R., Kim, T.W., Seol, Y.G., Jang, J.: Effect of strontium addition on stability of Zinc–Tin–Oxide thin-film transistors fabricated by solution process. J. Disp. Technol. 10, 939 (2014)
Huang, C.X., Li, J., Fu, Y.Z., Zhang, J.H., Jiang, X.Y., Zhang, Z.L.: Effect of hafnium doping on density of states in dual-target magnetron co-sputtering HfZnSnO thin film transistors. Appl. Phys. Lett. 107, 213504 (2015)
Huang, C.X., Li, J., Fu, Y.Z., Zhang, J.H., Jiang, X.Y., Zhang, Z.L., Yang, Q.H.: Characterization of dual-target co-sputtered novel Hf-doped ZnSnO semiconductors and the enhanced stability of its associated thin film transistors. J. Alloy. Compd. 681, 81 (2016)
Huang, C.X., Li, J., Fu, Y.Z., Zhang, J.H., Jiang, X.Y., Zhang, Z.L.: Suppression in the negative bias illumination instability of ZnSnO thin-film transistors using hafnium doping by dual-target magnetron cosputtering system. IEEE T. Electron. Dev. 63, 3552 (2016)
Han, D.S., Park, J.H., Kang, M.S., Choi, D.K., Park, J.W.: Highly stable hafnium–tin–zinc oxide thin film transistors with stacked bilayer active layers. Curr. Appl. Phys. 15, 94 (2015)
Kang, I., Park, C.H., Chong, E., Lee, S.Y.: Role of Si as carrier suppressor in amorphous Zn–Sn–O. Curr. Appl. Phys. 12, S12 (2012)
Choi, W.S., Jo, H., Kwon, M.S., Jung, B.J.: Control of electrical properties and gate bias stress stability in solution-processed a-IZO TFTs by Zr doping. Curr. Appl. Phys. 14, 1831 (2014)
Jeon, H.J., Maeng, W.J., Park, J.S.: Effect of Al concentration on the electrical characteristics of solution-processed Al doped ZnSnO thin film transistors. Ceram. Int. 40, 8769 (2014)
Banger, K.K., Peterson, R.L., Mori, K., Yamashita, Y., Leedham, T., Sirringhaus, H.: High performance, low temperature solution-processed barium and strontium doped oxide thin film transistors. Chem. Mater. 26, 1195 (2014)
Jeonga, K.S., Song, J., Lima, D., Lee, M.S., Kim, H., Cho, M.H.: Structural evolution and defect control of yttrium-doped ZrO2 films grown by a sol–gel method. Appl. Surf. Sci. 320, 128 (2014)
Huang, C.X., Li, J., Zhong, D.Y., Zhao, C.Y., Zhu, W.Q., Zhang, J.H., Jiang, X.Y., Zhang, Z.L.: Atomic layer deposition deposited high dielectric constant (κ) ZrAlOx gate insulator enabling high performance ZnSnO thin film transistors. Superlattices Microstruct. 109, 852 (2017)
Ha, T.J., Dodabalapur, A.: Photo stability of solution-processed low-voltage high mobility zinc-tin-oxide/ZrO2 thin-film transistors for transparent display applications. Appl. Phys. Lett. 102, 123506 (2013)
Wilk, G.D., Wallace, R.M., Anthony, J.M.: High-κ gate dielectrics: current status and materials properties considerations. J. Appl. Phys. 89, 5243 (2001)
Tewg, J.Y., Kuo, Y., Lu, J.: Suppression of crystallization of tantalum oxide thin film by doping with zirconium. J. Electrochem. Soc. 8, G27 (2005)
Puurunen, R.L.: Surface chemistry of atomic layer deposition: a case study for the trimethylaluminum/water process. J. Appl. Phys. 97, 121301 (2005)
Huang, C.X., Li, J., Zhong, D.Y., Zhao, C.Y., Zhang, J.H., Jiang, X.Y., Zhang, Z.L.: Realization of solution-processed semiconducting single-walled carbon nanotubes thin film transistors with atomic layer deposited ZrAlOx gate insulator. Appl. Phys. Lett. 110, 253510 (2017)
Zhang, J.H., Ding, X.W., Li, J., Zhang, H., Jiang, X.Y., Zhang, Z.L.: Performance enhancement in InZnO thin-film transistors with compounded ZrO2–Al2O3 nanolaminate as gate insulators. Ceram. Int. 42, 8115 (2016)
Lee, S., Choi, H., Shin, S., Park, J., Ham, G., Jung, H., Jeon, H.: Permeation barrier properties of an Al2O3/ZrO2 multilayer deposited by remote plasma atomic layer deposition. Curr. Appl. Phys. 14, 552 (2014)
Oh, J., Shin, S., Park, J., Ham, G., Jeon, H.: Characteristics of Al2O3/ZrO2 laminated films deposited by ozone-based atomic layer deposition for organic device encapsulation. Thin Solid Films 599, 119 (2016)
Abdullah, H., Norazia, M.N., Shaari, S., Nuawi, M.Z., Mohamed, N.S.: Dan, low-doping effects of nanostructure ZnO:Sn tin films annealed at different temperature in nitrogen ambient to be applied as an anti-reflecting coating. Am. J. Eng. Appl. Sci. 3, 171 (2010)
Kim, S.J., Yoon, D.H., Rim, Y.S., Kim, H.J.: Low-temperature solution-processed ZrO2 gate insulators for thin-film transistors using high-pressure annealing. Electrochem. Solid-State Lett. 14, E35 (2011)
Rim, Y.S., Kim, D.L., Jeong, W.H., Kim, H.J.: Effect of Zr addition on ZnSnO thin-film transistors using a solution process. Appl. Phys. Lett. 97, 233502 (2010)
Parthiban, S., Kwon, J.Y.: Role of dopants as a carrier suppressor and strong oxygen binder in amorphous indium-oxide-based field effect transistor. J. Mater. Res. 29, 1585 (2014)
Valletta, A., Mariucci, L., Fortunato, G.: Surface-scattering effects in polycrystalline silicon thin-film transistors. Appl. Phys. Lett. 82, 3119 (2003)
Volkel, A.R., Street, R.A., Knipp, D.: Carrier transport and density of state distributions in pentacene transistors. Phys. Rev. B 66, 195336 (2002)
Oh, H., Yoon, S.M., Ryu, M.K., Hwang, C.S., Yang, S., Park, S.H.K.: Photon-accelerated negative bias instability involving subgap states creation in amorphous In–Ga–Zn–O thin film transistor. Appl. Phys. Lett. 97, 183502 (2010)
Chowdhury, M.D.H., Migliorato, P., Jang, J.: Light induced instabilities in amorphous indium–gallium–zinc–oxide thin-film transistors. Appl. Phys. Lett. 97, 173506 (2010)
Jung, H.Y., Park, S.Y., Kim, J.I., Yang, H., Choa, R., Kim, D.H., Bae, J.U., Shin, W.S., Jeong, J.K.: Investigation of co-sputtered LiZnSnO thin film transistors. Thin Solid Films 522, 435 (2012)
Kim, U.K., Rha, S.H., Kim, J.H., Chung, Y.J., Jung, J., Hwang, E.S., Lee, J., Park, T.J., Choic, J.H., Hwang, C.S.: Study on the defects in metal–organic chemical vapor deposited zinc tin oxide thin films using negative bias illumination stability analysis. J. Mater. Chem. C 1, 6695 (2013)
Gavryushin, V., Raciukaitis, G., Juodzbalis, D., Kazlauskas, A., Kubertavicius, V.: Characterization of intrinsic and impurity deep levels in ZnSe and ZnO crystals by nonlinear spectroscopy. J. Cryst. Growth 138, 924 (1994)
Takechi, K., Nakata, M., Eguchi, T., Yamaguchi, H., Kaneko, S.: Temperature-dependent transfer characteristics of amorphous InGaZnO4 thin-film transistors. Jpn. J. Appl. Phys. 48, 011301 (2009)
Kim, J., Bang, S., Lee, S., Shin, S., Park, J., Seo, H., Jeon, H.: A study on H2 plasma treatment effect on a-IGZO thin film transistor. J. Mater. Res. 27, 2318 (2012)
Tai, Y.H., Chiu, H.L., Chou, L.S.: The deterioration of a-IGZO TFTs owing to the copper diffusion after the process of the source/drain metal formation. J. Electrochem. Soc. 159, 200 (2012)
Kim, G.H., Jeong, W.H., Ahn, B.D., Shin, H.S., Kim, H.J., Kim, H.J., Ryu, M.K., Park, K.B., Seon, J.B., Lee, S.Y.: Investigation of the effects of Mg incorporation into InZnO for high-performance and high-stability solution-processed thin film transistors. Appl. Phys. Lett. 96, 163506 (2010)
Janotti, A., Van de Walle, C.G.: Oxygen vacancies in ZnO. Appl. Phys. Lett. 87, 122102 (2005)
Kamiya, T., Nomura, K., Hosono, H.: Electronic structure of the amorphous oxide semiconductor a-InGaZnO4–x: Tauc–Lorentz optical model and origins of subgap states. Phys. Status Solidi A 206, 860 (2009)
Seo, H., Park, C.J., Cho, Y.J., Kim, Y.B., Choi, D.K.: Correlation of band edge native defect state evolution to bulk mobility changes in ZnO thin films. Appl. Phys. Lett. 96, 232101 (2010)
Acknowledgements
The authors would like to acknowledge the financial support given by the Natural Science Foundation of China (61774100, 61674101), Shanghai Science and Technology Commission (15JC1402000, 16010500500, 18JC1410402), the National Science Foundation for Distinguished Young Scholars of China (51725505), Science and Technology Commission of Shanghai Municipality Program (17DZ2281700) and the Shanghai Sailing Program (17YF1406300).
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Li, J., Zhou, YH., Zhong, DY. et al. Atomic Layer Deposited ZrxAl1−xOy Film as High κ Gate Insulator for High Performance ZnSnO Thin Film Transistor. Electron. Mater. Lett. 14, 669–677 (2018). https://doi.org/10.1007/s13391-018-0079-1
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DOI: https://doi.org/10.1007/s13391-018-0079-1